Crystal structure of (1,3-thiazole-2-carboxylato-κ N)(1,3-thiazole-2-carboxylic acid-κ N)silver(I)
Meundaeng, Natthaya; Rujiwatra, Apinpus; Prior, Timothy J.
Dr Tim Prior T.Prior@hull.ac.uk
Senior Lecturer in Inorganic Chemistry
© Meundaeng et al. 2019. The linear two-coordinate silver (I) complex [Ag(C 4 H 2 NO 2 S)(C 4 H 3 NO 2 S)] or [Ag(2-Htza)(2-tza)] is reported (2-Htza = 1,3-thiazole-2-carboxylic acid). The Ag I ion is coordinated by two heterocyclic N atoms from two ligands in a linear configuration, forming a discrete coordination complex. There is an O - H⋯O hydrogen bond between 2-tza - and 2tzaH of adjacent complexes. The hydrogen atom is shared between the two oxygen atoms. This interaction produces a hydrogen-bonded tape parallel to the  direction, which is augmented through intermolecular C - H⋯O hydrogen-bonding interactions between the bound thiazole groups. There is a further rather long Ag⋯O interaction [2.8401 (13) Å, compared with a mean of 2.54 (11) Å for 23 structures in the CSD] that assembles these tapes into columns, between which there are C - H⋯π interactions, leading to the formation of a three-dimensional supramolecular architecture.
Meundaeng, N., Rujiwatra, A., & Prior, T. J. (2019). Crystal structure of (1,3-thiazole-2-carboxylato-κ N)(1,3-thiazole-2-carboxylic acid-κ N)silver(I). Acta Crystallographica Section E: Crystallographic Communications, 75(2), 185-188. https://doi.org/10.1107/S2056989019000124
|Journal Article Type||Article|
|Acceptance Date||Jan 3, 2019|
|Online Publication Date||Jan 11, 2019|
|Deposit Date||Dec 11, 2020|
|Publicly Available Date||Jan 8, 2021|
|Journal||Acta Crystallographica Section E: Crystallographic Communications|
|Publisher||International Union of Crystallography|
|Peer Reviewed||Peer Reviewed|
|Keywords||Silver; 2-thiazolecarboxylic acid; Hydrogen bonding; Crystal structure.|
|Additional Information||Publication: Acta Crystallographica Section E: Crystallographic Communications; Content type: research communications; Article metrics: Available; Peer reviewed: Yes; Review process: Single blind; Received: 15 October 2018; Accepted: 3 January 2019; Published online: 11 January 2019; Supplementary materials: This article has supporting information; Copyright: © 2019 Meundaeng et al.; Licence: Creative Commons Attribution (CC-BY)|
This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.