Hao Zhang
Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties
Zhang, Hao; Zhu, Zhao Qiang; Zhou, Fu Hou; Redshaw, Carl; Chen, Kai; Xu, Jing
Authors
Zhao Qiang Zhu
Fu Hou Zhou
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Kai Chen
Jing Xu
Abstract
The solvothermal synthesis of three new 2D MOFs is reported. From the reaction of 3,5-di(1H-imidazol-
1-yl)pyridine (dip) and the metal salts Co(NO3)2$6H2O, Cd(NO3)2$4H2O or Zn(NO3)2$4H2O, the three
MOFs [Co(dip)2(SCN)2] (1), {[Cd(dip)2(H2O)2]$(NO3)2} (2), {[Zn(dip)2(H2O)2]$(ClO4)2} (3) were obtained.
For these 2D MOFs, all the metal ions adopt a six-coordinate octahedral geometry with axial coordination
sites occupied by SCN or water molecules. The SCN/water ligands were all mono-coordinate and led to
layered MOF structures. Furthermore, the fluorescence properties of 2 and 3 have been investigated.
Citation
Zhang, H., Zhu, Z. Q., Zhou, F. H., Redshaw, C., Chen, K., & Xu, J. (2020). Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties. Journal of molecular structure, 1207, Article 127818. https://doi.org/10.1016/j.molstruc.2020.127818
Journal Article Type | Article |
---|---|
Acceptance Date | Jan 28, 2020 |
Online Publication Date | Jan 31, 2020 |
Publication Date | May 5, 2020 |
Deposit Date | Feb 8, 2020 |
Publicly Available Date | Feb 1, 2021 |
Journal | Journal of Molecular Structure |
Print ISSN | 0022-2860 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 1207 |
Article Number | 127818 |
DOI | https://doi.org/10.1016/j.molstruc.2020.127818 |
Keywords | Inorganic Chemistry; Organic Chemistry; Analytical Chemistry; Spectroscopy |
Public URL | https://hull-repository.worktribe.com/output/3426554 |
Publisher URL | https://www.sciencedirect.com/science/article/abs/pii/S0022286020301423?via%3Dihub |
Additional Information | This article is maintained by: Elsevier; Article Title: Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties; Journal Title: Journal of Molecular Structure; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.molstruc.2020.127818; Content Type: article; Copyright: © 2020 Elsevier B.V. All rights reserved. |
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