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Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties

Zhang, Hao; Zhu, Zhao Qiang; Zhou, Fu-Hou; Redshaw, Carl; Chen, Kai; Xu, Jing

Authors

Hao Zhang

Zhao Qiang Zhu

Fu-Hou Zhou

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry

Kai Chen

Jing Xu



Abstract

The solvothermal synthesis of three new 2D MOFs is reported. From the reaction of 3,5-di(1H-imidazol-
1-yl)pyridine (dip) and the metal salts Co(NO3)2$6H2O, Cd(NO3)2$4H2O or Zn(NO3)2$4H2O, the three
MOFs [Co(dip)2(SCN)2] (1), {[Cd(dip)2(H2O)2]$(NO3)2} (2), {[Zn(dip)2(H2O)2]$(ClO4)2} (3) were obtained.
For these 2D MOFs, all the metal ions adopt a six-coordinate octahedral geometry with axial coordination
sites occupied by SCN or water molecules. The SCN/water ligands were all mono-coordinate and led to
layered MOF structures. Furthermore, the fluorescence properties of 2 and 3 have been investigated.

Journal Article Type Article
Publication Date May 5, 2020
Journal Journal of Molecular Structure
Print ISSN 0022-2860
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 1207
Article Number 127818
APA6 Citation Zhang, H., Zhu, Z. Q., Zhou, F., Redshaw, C., Chen, K., & Xu, J. (2020). Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties. Journal of molecular structure, 1207, https://doi.org/10.1016/j.molstruc.2020.127818
DOI https://doi.org/10.1016/j.molstruc.2020.127818
Keywords Inorganic Chemistry; Organic Chemistry; Analytical Chemistry; Spectroscopy
Additional Information This article is maintained by: Elsevier; Article Title: Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties; Journal Title: Journal of Molecular Structure; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.molstruc.2020.127818; Content Type: article; Copyright: © 2020 Elsevier B.V. All rights reserved.
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