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Bi2WO6/C-Dots/TiO2: A Novel Z-Scheme Photocatalyst for the Degradation of Fluoroquinolone Levofloxacin from Aqueous Medium

Elumalai, Sasikumar; Sharma, Shelja; Ibhadon, Alex O; Francesconi, M. Grazia; Mehta, Surinder Kumar; Kansal, Sushil Kumar; Umar, Ahmad; Baskoutas, Sotirios

Authors

Sasikumar Elumalai

Shelja Sharma

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Dr Alex Ibhadon A.O.Ibhadon@hull.ac.uk
Reader in Catalysis and Reactor Engineering

Surinder Kumar Mehta

Sushil Kumar Kansal sushilkk1@yahoo.co.ins.k.k.

Ahmad Umar ahmadumar786@gmail.com

Sotirios Baskoutas



Contributors

Abstract

Photocatalytic materials and semiconductors of appropriate structural and morphological architectures as well as energy band gaps are the materials needed for mitigating current environmental problems as these materials have the ability to exploit the full spectrum of solar light in a number of applications. Hence, constructing a Z-scheme heterojunction is an ideal approach to overcome the limitations of a single component or traditional heterogeneous catalysts for the competent removal of organic chemicals present in wastewater, to mention one of the areas of application. A Z-scheme catalyst possesses many attributes, including enhanced light harvesting capacity, strong redox ability and different oxidation and reduction positions. In the present work, a novel ternary z-scheme photocatalyst, i.e. Bi2WO6/C-dots/TiO2, has been prepared by a facile chemical wet technique. The prepared solar light driven z-scheme composite was characterized by many analytical and spectroscopic practices including powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), N2 adsorption-desorption isotherm, Fourier- transform infrared spectroscopy (FT-IR), photoluminescence (PL) and UV-vis diffuse reflectance spectroscopy (DRS). The photocatalytic activity of the Bi2WO6/C-dots/TiO2 composite was evaluated by studying the degradation of fluoroquinolone drug, levofloxacin under solar light irradiation. Almost complete (99%) decomposition of the levofloxacin drug was observed in 90 minutes of sunlight irradiation. The effect of catalyst loading, initial substrate concentration and pH of the reaction was also optimized. The photocatalytic activity of the prepared catalyst was also compared with that of bare Bi2WO6, TiO2 and TiO2/C-dots under optimized conditions. Scavenger radical trap studies and terephthalic acid (TPA) fluorescence technique were done to understand the role of the photoinduced active radical ions that are bring about the decomposition of levofloxacin. Based on these studies, the plausible degradation trail of levofloxacin was proposed and was further supported by LC-MS analysis.

Citation

Elumalai, S., Ibhadon, A. O., Sharma, S., Ibhadon, A. O., Francesconi, M. G., Mehta, S. K., …Baskoutas, S. (2020). Bi2WO6/C-Dots/TiO2: A Novel Z-Scheme Photocatalyst for the Degradation of Fluoroquinolone Levofloxacin from Aqueous Medium. Nanomaterials, 10(5), https://doi.org/10.3390/nano10050910

Journal Article Type Article
Acceptance Date Apr 20, 2020
Online Publication Date May 8, 2020
Publication Date 2020-05
Deposit Date Apr 25, 2020
Publicly Available Date May 11, 2020
Journal Nanomaterials
Print ISSN 2079-4991
Electronic ISSN 2079-4991
Publisher MDPI
Peer Reviewed Peer Reviewed
Volume 10
Issue 5
Article Number 910
DOI https://doi.org/10.3390/nano10050910
Keywords Bi2WO6/C-dots/TiO2; Z-scheme, photocatalysis; levofloxacin; LC-MS; degradation
Public URL https://hull-repository.worktribe.com/output/3499709
Publisher URL https://www.mdpi.com/2079-4991/10/5/910

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Copyright Statement
© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).





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