Aggregation-induced emission luminogen: A new perspective in the photo-degradation of organic pollutants

Hu, Zhen; Li, Ying; Kang, Miaomiao; Islam, Md. Monarul; Chen, Mengsi; Zhang, Jun; Xiao, Ye; Feng, Xing; Redshaw, Carl; Zhang, Menglong; Chen, Qing; Xie, Sheng; Lam, Jacky W.Y.; Tang, Ben Zhong

Abstract

Both the variety and uniqueness of organic semiconductors has contributed to the rapid development of environmental engineering applications and renewable fuel production, typified by the photodegradation of organic pollutants or water splitting. This paper presents a rare example of an aggregation-induced emission luminogen as a highly efficient photocatalyst for pollutant decomposition in an environmentally relevant application. Under irradiation, the tetraphenylethene-based AIEgen (TPE-Ca) exhibited high photo-degradation efficiency of up to 98.7% of Rhodamine B (RhB) in aqueous solution. The possible photocatalytic mechanism was studied by electron paramagnetic resonance and X-ray photoelectron spectroscopy spectra, electrochemistry, thermal imaging technology, ultra-performance liquid chromatography and high-definition mass spectrometry, as well as by density functional theory calculations. Among the many diverse AIEgens, this is the first AIEgen to be developed as a photocatalyst for the degradation of organic pollutants. This research will open up new avenues for AIEgens research, particularly for applications of environmental relevance. (Figure presented.).

Citation

Hu, Z., Li, Y., Kang, M., Islam, M. M., Chen, M., Zhang, J., …Tang, B. Z. (2020). Aggregation-induced emission luminogen: A new perspective in the photo-degradation of organic pollutants. Ecomat, 2(2), Article e12024. https://doi.org/10.1002/eom2.12024

• Journal Article Type: Article
• Acceptance Date: Apr 3, 2020
• Online Publication Date: Apr 27, 2020
• Publication Date: Jun 1, 2020
• Deposit Date: Apr 27, 2020
• Publicly Available Date: Apr 29, 2020
• Journal: EcoMat
• Print ISSN: 2567-3173
• Electronic ISSN: 2567-3173
• Peer Reviewed: Peer Reviewed
• Volume: 2
• Issue: 2
• Article Number: e12024
• DOI: https://doi.org/10.1002/eom2.12024
• Keywords: aggregation‐induced emission luminogen; photocatalysis mechanism; photodegradation; radical species
• Public URL: https://hull-repository.worktribe.com/output/3501597