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Intercalated brucite-type layered cobalt(II) hydroxysulfate

Prior, Timothy; Yotnoi, Bunlawee; Luachan, Sanchai; Prior, Timothy J.; Rujiwatra, Apinpus

Authors

Bunlawee Yotnoi

Sanchai Luachan

Apinpus Rujiwatra



Abstract

In an attempt to synthesize new cobalt(II) sulfate framework structures using 1,4-diazabicyclo[2.2.2]octane as a template, crystals of poly[0.35-[hexaaquacobalt(II)] [tri-μ-hydroxido-μ-sulfato-dicobalt(II)]], {[Co(H 2 O) 6 ] 0.35 [Co 2 (OH) 3 (SO 4 )]} n , were obtained as a mixture with [Co(H 2 O) 6 ]SO 4 crystals. The crystal structure can be described as being constructed from discrete brucite-type [Co 4 (OH) 6 (SO 4 ) 2 ] layers, each of which is built up from edge-shared [Co(OH) 6 ] and [Co(OH) 4 -(OSO 3 ) 2 ] octahedra, with partial intercalation by [Co(H 2 O) 6 ] 2+ ions. The absence of ca 30% of the [Co(H 2 O) 6 ] 2+ cations indicates partial oxidation of cobalt(II) to cobalt(III) within the layer.

Journal Article Type Article
Publication Date 2009-06
Print ISSN 2056-9890
Electronic ISSN 1600-5368
Publisher International Union of Crystallography
Peer Reviewed Peer Reviewed
Volume 65
Issue 7
Pages I52-U139
APA6 Citation Yotnoi, B., Luachan, S., Prior, T. J., & Rujiwatra, A. (2009). Intercalated brucite-type layered cobalt(II) hydroxysulfate. Acta Crystallographica Section E: Crystallographic Communications, 65(7), I52-U139. https://doi.org/10.1107/S160053680902251X
DOI https://doi.org/10.1107/S160053680902251X
Publisher URL http://scripts.iucr.org/cgi-bin/paper?S160053680902251X
Additional Information Journal: Acta Crystallographica Section E: Structure Reports Online; Content type: inorganic compounds; Peer reviewed: Yes; Review process: Single blind; Received: 27 May 2009; Accepted: 12 June 2009; Published online: 20 June 2009; Supplementary materials: This article has supporting information; Copyright: © 2009 Yotnoiet al.; Licence: Creative Commons Attribution (CC-BY)

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