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Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer

Prior, Timothy; Lauchan, Sanchai; Prior, Timothy J.; Meansiri, Santi; Rujiwatra, Apinpus

Authors

Sanchai Lauchan

Santi Meansiri

Apinpus Rujiwatra

Abstract

A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and SO4 tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature.

Journal Article Type Article
Publication Date 2008-09
Journal JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Print ISSN 1574-1443
Electronic ISSN 1574-1451
Publisher Springer Verlag
Peer Reviewed Peer Reviewed
Volume 18
Issue 3
Pages 352-357
Institution Citation Lauchan, S., Prior, T. J., Meansiri, S., & Rujiwatra, A. (2008). Cobalt(ethylenediamine)sulfate: A pillared layered coordination polymer. Journal of inorganic and organometallic polymers and materials, 18(3), 352-357. https://doi.org/10.1007/s10904-008-9208-x
DOI https://doi.org/10.1007/s10904-008-9208-x
Keywords Materials Chemistry; Polymers and Plastics
Publisher URL https://link.springer.com/article/10.1007%2Fs10904-008-9208-x