Preparation and Characterization of Bis(μ-1,2-diaminoethane)cobalt(II) Hexavanadate: A Layered Polyoxovanadate Pillared by a Cobalt Coordination Complex

Yotnoi, Bunlawee; Limtrakul, Jumras; Prior, Timothy; Rujiwatra, Apinpus

Abstract

The first example of polyoxovanadate layered framework with a cobalt coordination complex as a pillaring unit, CoII(mu-C2N2H8)(2)[(V4V2O14)-V-IV-O-V], was readily synthesized under hydrothermal conditions. The structure can be solved and refined in monoclinic P2(1)/n with a = 9.143(3) angstrom, b = 6.5034(11) angstrom, c = 15.874(4) angstrom, beta = 101.90(2), V = 923.6(4) angstrom(3) and Z = 2. The crystal structure comprises two-dimensional (V4V2O14)-V-IV-O-V}(2-) layers extending parallel to [101], constructed from tetrahedral {(VO4)-O-V} and square pyramidal {(VO5)-O-IV} building units. Adjacent layers are linked through the octahedral {(CoO2)-O-II(mu-C2N2H8)(2)} pillars, within which the CoII resides on an inversion center. The structure displays N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonding between the ethylenediamine and vanadium oxide layers.

Citation

Yotnoi, B., Limtrakul, J., Prior, T., & Rujiwatra, A. (2009). Preparation and Characterization of Bis(μ-1,2-diaminoethane)cobalt(II) Hexavanadate: A Layered Polyoxovanadate Pillared by a Cobalt Coordination Complex. Journal of chemical crystallography, 39(7), 525-529. https://doi.org/10.1007/s10870-009-9529-9

• Journal Article Type: Article
• Acceptance Date: Feb 17, 2009
• Online Publication Date: Feb 26, 2009
• Publication Date: 2009-07
• Journal: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
• Print ISSN: 1074-1542
• Electronic ISSN: 1572-8854
• Publisher: Springer Verlag
• Peer Reviewed: Peer Reviewed
• Volume: 39
• Issue: 7
• Pages: 525-529
• DOI: https://doi.org/10.1007/s10870-009-9529-9
• Keywords: Spectroscopy; Structural Biology; Condensed Matter Physics
• Public URL: https://hull-repository.worktribe.com/output/391268