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Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates

Settheeworrarit, Thapanon; Prior, Timothy J.; Meansiri, Santi; Limtrakul, Jumras; Rujiwatra, Apinpus

Authors

Thapanon Settheeworrarit

Santi Meansiri

Jumras Limtrakul

Apinpus Rujiwatra



Abstract

A series of four diaminoalkane templated vanadium oxide polymeric frameworks, [(V2O8V2O2)-O-IV-O-V](C2H10N2), [V (2O8V2V)-O-IV O-2](C3H12N2), [(V4O10V2V)-O-IV O-4](C4H14N2) and [(V4O102O4)-O-IV-O-V-O-V](C5H16N2), have been successfully prepared under hydrothermal conditions. The crystal structures are fully characterized revealing layered structures composed of common inorganic building units, namely {(VO5)-O-IV} square pyramids and {(VO4)-O-V} tetrahedra. The layer registries are different depending on the molecular structure of the diaminoalkanes, and can be accounted for by the organic-inorganic interface interactions. The analysis of hydrogen bonds indicates their important role in directing two- and three-dimensional structural architectures. The influences of different diaminoalkanes are also apparent in both thermogravimetric and complex magnetic behaviors, and are discussed in details.

Journal Article Type Article
Publication Date 2008-06
Journal JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Print ISSN 1574-1443
Electronic ISSN 1574-1451
Publisher Springer Verlag
Peer Reviewed Peer Reviewed
Volume 18
Issue 2
Pages 253-263
APA6 Citation Settheeworrarit, T., Prior, T. J., Meansiri, S., Limtrakul, J., & Rujiwatra, A. (2008). Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates. Journal of inorganic and organometallic polymers and materials, 18(2), 253-263. https://doi.org/10.1007/s10904-007-9171-y
DOI https://doi.org/10.1007/s10904-007-9171-y
Keywords Materials Chemistry; Polymers and Plastics
Publisher URL https://link.springer.com/article/10.1007%2Fs10904-007-9171-y
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