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Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates

Settheeworrarit, Thapanon; Prior, Timothy J.; Meansiri, Santi; Limtrakul, Jumras; Rujiwatra, Apinpus

Authors

Thapanon Settheeworrarit

Santi Meansiri

Jumras Limtrakul

Apinpus Rujiwatra



Abstract

A series of four diaminoalkane templated vanadium oxide polymeric frameworks, [(V2O8V2O2)-O-IV-O-V](C2H10N2), [V (2O8V2V)-O-IV O-2](C3H12N2), [(V4O10V2V)-O-IV O-4](C4H14N2) and [(V4O102O4)-O-IV-O-V-O-V](C5H16N2), have been successfully prepared under hydrothermal conditions. The crystal structures are fully characterized revealing layered structures composed of common inorganic building units, namely {(VO5)-O-IV} square pyramids and {(VO4)-O-V} tetrahedra. The layer registries are different depending on the molecular structure of the diaminoalkanes, and can be accounted for by the organic-inorganic interface interactions. The analysis of hydrogen bonds indicates their important role in directing two- and three-dimensional structural architectures. The influences of different diaminoalkanes are also apparent in both thermogravimetric and complex magnetic behaviors, and are discussed in details.

Citation

Settheeworrarit, T., Prior, T. J., Meansiri, S., Limtrakul, J., & Rujiwatra, A. (2008). Crystal structures, thermogravimetric and magnetic properties of four organodiamine templated vanadium oxide frameworks: influences of diaminoalkane templates. Journal of inorganic and organometallic polymers and materials, 18(2), 253-263. https://doi.org/10.1007/s10904-007-9171-y

Journal Article Type Article
Online Publication Date Oct 27, 2007
Publication Date 2008-06
Journal JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Print ISSN 1574-1443
Electronic ISSN 1574-1451
Publisher Springer Verlag
Peer Reviewed Peer Reviewed
Volume 18
Issue 2
Pages 253-263
DOI https://doi.org/10.1007/s10904-007-9171-y
Keywords Materials Chemistry; Polymers and Plastics
Public URL https://hull-repository.worktribe.com/output/396192
Publisher URL https://link.springer.com/article/10.1007%2Fs10904-007-9171-y