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Mixed-metal one-dimensional sulfides-A class of materials with differences and similarities to oxides

Harrison, Mark R.; Francesconi, M. Grazia

Authors

Mark R. Harrison



Abstract

The higher degree of covalency in the metal-sulfide bond in sulfides compared to the metal-oxide bond in oxides often leads to the breakdown of the ionic model for the description of sulfides, making the two classes of materials rather dissimilar. This feature considers how one-dimensional ternary (or mixed-metal) sulfides can be considered a class of materials for which the ionic model is still valid. A selection of one-dimensional mixed-metal sulfides is described with the aim of highlighting some similarities and differences with oxides, especially oxides of the same stoichiometry. (C) 2010 Elsevier B.V. All rights reserved.

Journal Article Type Review
Publication Date Feb 28, 2011
Journal COORDINATION CHEMISTRY REVIEWS
Print ISSN 0010-8545
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 255
Issue 3-4
Pages 451 - 458
APA6 Citation Harrison, M. R., & Francesconi, M. G. (2011). Mixed-metal one-dimensional sulfides-A class of materials with differences and similarities to oxides. Coordination chemistry reviews, 255(3-4), 451 - 458. https://doi.org/10.1016/j.ccr.2010.10.008
DOI https://doi.org/10.1016/j.ccr.2010.10.008
Keywords Sulfides One-dimensional structures Transition metals ba-fe-s crystal-structure magnetic-properties linear antiferromagnetism framework structures chain structures chalcogenides iron transition mossbauer
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