Jian Hang Hu
Cucurbit[6]uril-based supramolecular frameworks formed through outer surface interactions and application for iodine adsorption
Hu, Jian Hang; Cen, Ran; Liu, Ming; Shan, Pei Hui; Prior, Timothy J.; Redshaw, Carl; Huang, Ying; Tao, Zhu; Xiao, Xin
Authors
Ran Cen
Ming Liu
Pei Hui Shan
Dr Tim Prior T.Prior@hull.ac.uk
Senior Lecturer in Inorganic Chemistry
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Emeritus Professor
Ying Huang
Zhu Tao
Xin Xiao
Abstract
The interaction between the outer surface of cucurbit[6]uril (Q[6]) and methyl triphenyl phosphorus iodide (MTPI) has been studied in the presence of [CdCl4]2-. The MTPI is connected to four neighboring Q[6]s through weak interactions such as C-H···π and C-H···O, whilst the [CdCl4]2- is connected with the portal carbonyl oxygen, glycoside urea methylene and a bridging methylene of a Q[6] molecule via ion–dipole interactions. These interactions were evident from a single crystal X-ray diffraction study of Q[6]-MTPI-[CdCl4]2-. Furthermore, this complex exhibits a porous structure, which can be described as a Q[6]-based supramolecular framework (QSF), and its ability to adsorb iodine was also investigated.
Citation
Hu, J. H., Cen, R., Liu, M., Shan, P. H., Prior, T. J., Redshaw, C., Huang, Y., Tao, Z., & Xiao, X. (2022). Cucurbit[6]uril-based supramolecular frameworks formed through outer surface interactions and application for iodine adsorption. Inorganic Chemistry Communications, 142, Article 109663. https://doi.org/10.1016/j.inoche.2022.109663
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 10, 2022 |
Online Publication Date | Jun 14, 2022 |
Publication Date | 2022-08 |
Deposit Date | Jul 6, 2022 |
Publicly Available Date | Jun 15, 2023 |
Journal | Inorganic Chemistry Communications |
Print ISSN | 1387-7003 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 142 |
Article Number | 109663 |
DOI | https://doi.org/10.1016/j.inoche.2022.109663 |
Keywords | Cucurbit[6]uril; Methyl triphenyl phosphorus iodide; Weak interactions; Q[n]-based supramolecular framework; Outer surface interactions |
Public URL | https://hull-repository.worktribe.com/output/4021747 |
Files
Accepted manuscript
(1.7 Mb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by-nc-nd/4.0/
Copyright Statement
© 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license: http://creativecommons.org/licenses/by-nc-nd/4.0/
You might also like
Co/Mn-based 2D coordination polymers: synthesis, structure and ring opening polymerization
(2023)
Journal Article
A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine
(2023)
Journal Article
Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine
(2023)
Journal Article
Downloadable Citations
About Repository@Hull
Administrator e-mail: repository@hull.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2025
Advanced Search