Ionothermal synthesis and crystal structures of metal phosphate chains

Wragg, David S.; Le Ouay, Benjamin; Beale, Andrew M.; O'Brien, Matthew G.; Slawin, Alexandra M.Z.; Warren, John E.; Prior, Timothy J.; Morris, Russell E.

Abstract

We have prepared isostructural aluminium and gallium phosphate chains by ionothermal reactions in 1-ethyl-3-methylimidazolium bromide and 1-ethylpyridinium bromide under a variety of conditions. The chains can be prepared as pure phases or along with three dimensional framework phases. The chains are favoured at shorter heating times and the crystallinity can be improved by addition of transition metal acetates and amines which are not included in the final structure. The chain can be prepared with or without the presence of hydrofluoric acid.

Citation

Wragg, D. S., Le Ouay, B., Beale, A. M., O'Brien, M. G., Slawin, A. M., Warren, J. E., …Morris, R. E. (2010). Ionothermal synthesis and crystal structures of metal phosphate chains. Journal of Solid State Chemistry, 183(7), 1625-1631. https://doi.org/10.1016/j.jssc.2010.05.002

• Journal Article Type: Article
• Acceptance Date: May 2, 2010
• Online Publication Date: May 11, 2010
• Publication Date: 2010-07
• Journal: JOURNAL OF SOLID STATE CHEMISTRY
• Print ISSN: 0022-4596
• Electronic ISSN: 1095-726X
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 183
• Issue: 7
• Pages: 1625-1631
• DOI: https://doi.org/10.1016/j.jssc.2010.05.002
• Keywords: Ionothermal synthesis; X-ray diffraction; Crystal structure; Chain
• Public URL: https://hull-repository.worktribe.com/output/405209
• Publisher URL: https://www.sciencedirect.com/science/article/pii/S002245961000191X?via%3Dihub