Christopher Carruthers
The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands
Carruthers, Christopher; Ronson, Tanya K.; Sumby, Christopher J.; Westcott, Aleema; Harding, Lindsay P.; Prior, Timothy J.; Rizkallah, Pierre; Hardie, Michaele J.
Authors
Tanya K. Ronson
Christopher J. Sumby
Aleema Westcott
Lindsay P. Harding
Dr Tim Prior T.Prior@hull.ac.uk
Senior Lecturer in Inorganic Chemistry
Pierre Rizkallah
Michaele J. Hardie
Abstract
A series of clathrate and metal complexes with cyclotriveratrylene-like molecular host ligands show a similar dimeric homomeric inclusion motif in which a ligand arm of one host is the intra-cavity guest of another and vice versa. This "hand-shake" motif is found in the trinuclear transition metal complex [Cu3Cl6(1)]center dot CH3CN center dot 1.5H(2)O which 1 is tris(4-[2,2',6',2 ''-terpyridyl]benzyl)cyclotriguaiacylene; in the self-included M4L4 tetrahedral metallo-supramolecular assembly [Ag-4(2)(4)]center dot(BF4)(4) in which 2 is tris-(2-quinolyl-methyl)cyclotriguaiacylene; in the 1D coordination chains [Ag(4)]center dot ReO4 center dot CH3CN and [Ag(5)]center dot SbF6 center dot 3DMF center dot H2O in which 4 is tris(1H-imidazol-1-yl)-cyclotriguaiacylene and 5 is tris{4-(2-pyridyl)benzyl}cyclotiguaiacylene; and in the acetone clathrate of tris{4-(2-pyridyl)benzyl-amino}cyclotriguaiacylene. Clathrates of ligands 2 and 5 do not show the same dimeric motif, although 2 has an extended homomeric inclusion motif that gives a hexagonal network.
Citation
Carruthers, C., Ronson, T. K., Sumby, C. J., Westcott, A., Harding, L. P., Prior, T. J., Rizkallah, P., & Hardie, M. J. (2008). The dimeric "hand-shake" motif in complexes and metallo-supramolecular assemblies of cyclotriveratrylene-based ligands. Chemistry: a European journal, 14(33), 10286-10296. https://doi.org/10.1002/chem.200801264
Journal Article Type | Article |
---|---|
Online Publication Date | Oct 1, 2008 |
Publication Date | Nov 17, 2008 |
Journal | CHEMISTRY-A EUROPEAN JOURNAL |
Print ISSN | 0947-6539 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 14 |
Issue | 33 |
Pages | 10286-10296 |
DOI | https://doi.org/10.1002/chem.200801264 |
Keywords | Coordination chains; Cyclotriveratrylene; Host-guest chemistry; Supramolecular chemistry; Tetrahedral assembly |
Public URL | https://hull-repository.worktribe.com/output/405221 |
Publisher URL | https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.200801264 |
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