Albert Farre
Amine catalysis for the organocatalytic diboration of challenging alkenes
Farre, Albert; Soares, Kaline; Briggs, Rachel A.; Balanta, Angelica; Benoit, David M.; Bonet, Amadeu
Authors
Kaline Soares
Rachel A. Briggs
Angelica Balanta
Dr David Benoit D.Benoit@hull.ac.uk
Senior Lecturer in Molecular Physics and Astrochemistry
Amadeu Bonet
Abstract
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The generation of in situ sp 2 –sp 3 diboron adducts has revolutionised the synthesis of organoboranes. Organocatalytic diboration reactions have represented a milestone in terms of unpredictable reactivity of these adducts. However, current methodologies have limitations in terms of substrate scope, selectivity and functional group tolerance. Here a new methodology based on the use of simple amines as catalyst is reported. This methodology provides a completely selective transformation overcoming current substrate scope and functional/protecting group limitations. Mechanistic studies have been included in this report.
Citation
Farre, A., Soares, K., Briggs, R. A., Balanta, A., Benoit, D. M., & Bonet, A. (2016). Amine catalysis for the organocatalytic diboration of challenging alkenes. Chemistry: a European journal, 22(49), 17552-17556. https://doi.org/10.1002/chem.201603979
Journal Article Type | Article |
---|---|
Acceptance Date | Sep 28, 2016 |
Online Publication Date | Oct 26, 2016 |
Publication Date | Dec 5, 2016 |
Deposit Date | Sep 30, 2016 |
Publicly Available Date | Oct 26, 2016 |
Journal | Chemistry: a European journal |
Print ISSN | 0947-6539 |
Electronic ISSN | 1521-3765 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 22 |
Issue | 49 |
Pages | 17552-17556 |
DOI | https://doi.org/10.1002/chem.201603979 |
Keywords | Organoboron, Organocatalysis, Lewis base, Amines, Density functional calculations |
Public URL | https://hull-repository.worktribe.com/output/443716 |
Publisher URL | http://onlinelibrary.wiley.com/doi/10.1002/chem.201603979/full |
Additional Information | Authors' accepted manuscript of article published in: Chemistry: a European journal, 2016, v.22, issue 49. |
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