Controlled formation of gold nanoparticles with tunable plasmonic properties in tellurite glass

Wei, Yunle; Zhao, Jiangbo; Fuhrmann, Sindy; Sajzew, Roman; Wondraczek, Lothar; Ebendorff-Heidepriem, Heike

Abstract

Silicate glasses with metallic nanoparticles (NPs) have been of intense interest in art, science and technology as the plasmonic properties of these NPs equip glass with light modulation capability. The so-called striking technique has enabled precise control of the in situ formation of metallic NPs in silicate glasses for applications from coloured glasses to photonic devices. Since tellurite glasses exhibit the unique combination of comparably easy fabrication, low phonon energy, wide transmission window and high solubility of luminescent rare earth ions, there has been a significant amount of work over the past two decades to adapt the striking technique to form gold or silver NPs in tellurite glasses. Despite this effort, the striking technique has remained insufficient for tellurite glasses to form metal NPs suitable for photonic applications. Here, we first uncover the challenges of the traditional striking technique to create gold NPs in tellurite glass. Then, we demonstrate precise control of the size and concentration of gold NPs in tellurite glass by developing new approaches to both steps of the striking technique: a controlled gold crucible corrosion technique to incorporate gold ions in tellurite glass and a glass powder reheating technique to subsequently transform the gold ions to gold NPs. Using the Mie theory, the size, size distribution and concentration of the gold NPs formed in tellurite glass are determined from the plasmonic properties of the NPs. This fundamental research provides guidance for designing and manipulating the plasmonic properties in tellurite glass for photonics research and applications.

Citation

Wei, Y., Zhao, J., Fuhrmann, S., Sajzew, R., Wondraczek, L., & Ebendorff-Heidepriem, H. (2023). Controlled formation of gold nanoparticles with tunable plasmonic properties in tellurite glass. Light: Science and Applications, 12(1), Article 293. https://doi.org/10.1038/s41377-023-01324-x

• Journal Article Type: Article
• Acceptance Date: Nov 2, 2023
• Online Publication Date: Dec 7, 2023
• Publication Date: Dec 1, 2023
• Deposit Date: Jan 19, 2024
• Publicly Available Date: Jan 23, 2024
• Journal: Light: Science and Applications
• Print ISSN: 2095-5545
• Electronic ISSN: 2047-7538
• Publisher: Nature Publishing Group
• Peer Reviewed: Peer Reviewed
• Volume: 12
• Issue: 1
• Article Number: 293
• DOI: https://doi.org/10.1038/s41377-023-01324-x
• Keywords: Nanoparticles; Nanophotonics and plasmonics
• Public URL: https://hull-repository.worktribe.com/output/4491064