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Highly selective recognition of Al3+ and I- ions using a bifunctional fluorescent probe

Li, Zhao; Zhao, Jiang-Lin; Wu, Yu-Tian; Mu, Lan; Zeng, Xi; Jin, Zongwen; Wei, Gang; Xie, Ning; Redshaw, Carl

Authors

Zongwen Jin

Zhao Li

Lan Mu

Gang Wei

Yu-Tian Wu

Ning Xie

Xi Zeng

Jiang-Lin Zhao

Abstract

A tripodal fluorescent probe L1 armed with rhodamine B and 1-naphthaleneisothiocyanates was prepared in high yield. A study of the recognition properties revealed that probe L1 exhibited high sensitivity and selectivity towards Al3⁺ through a “FRET” fluorescence response and colorimetric response with low detection limits of the order of 10-8 M. Meanwhile, probe L1 also possessed high recognition capability for I⁻ through fluorescent decay, which given there are comparatively few selective fluorescent probes for I⁻, is significant. Furthermore, the complexation mechanisms were fully investigated by spectral titrations, 1H NMR spectroscopic titrations and mass spectrometry. The utility of probe L1 as a biosensor in living cells (PC3 cells) towards Al3⁺ ions has also been demonstrated.

Journal Article Type Article
Publication Date Sep 28, 2017
Journal Organic and biomolecular chemistry
Print ISSN 1477-0520
Electronic ISSN 1477-0539
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 15
Issue 40
Pages 8627-8633
DOI https://doi.org/10.1039/C7OB02301D
Keywords Physical and Theoretical Chemistry; Organic Chemistry; Biochemistry
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2017/OB/C7OB02301D#!divAbstract
Additional Information : This document is Similarity Check deposited; : Supplementary Information; : Jiang-Lin Zhao (ORCID); : Xi Zeng (ORCID); : Zongwen Jin (ORCID); : Carl Redshaw (ORCID); : The Royal Society of Chemistry has an exclusive publication licence for this journal; : Single-blind; : Received 14 September 2017; Accepted 28 September 2017; Accepted Manuscript published 28 September 2017; Advance Article published 5 October 2017; Version of Record published 18 October 2017

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