Skip to main content

Research Repository

Advanced Search

Environmental behaviour of iron and steel slags in coastal settings

Riley, Alex L.; Cameron, James; Burke, Ian T; Onnis, Patrizia; Macdonald, John M; Gandy, Catherine J; Crane, Richard A; Byrne, Patrick; Comber, Sean; Jarvis, Adam P; Hudson-Edwards, Karen A; Mayes, William M.

Authors

Profile Image

Dr Alex Riley A.L.Riley@hull.ac.uk
Lecturer in Environmental Science

James Cameron

Ian T Burke

Patrizia Onnis

John M Macdonald

Catherine J Gandy

Richard A Crane

Patrick Byrne

Sean Comber

Adam P Jarvis

Karen A Hudson-Edwards



Abstract

Iron and steel slags have a long history of both disposal and beneficial use in the coastal zone. Despite the large volumes of slag deposited, comprehensive assessments of potential risks associated with metal(loid) leaching from iron and steel by-products are rare for coastal systems. This study provides a national-scale overview of the 14 known slag deposits in the coastal environment of Great Britain (those within 100 m of the mean high-water mark), comprising geochemical characterisation and leaching test data (using both low and high ionic strength waters) to assess potential leaching risks. The seaward facing length of slag deposits totalled at least 76 km, and are predominantly composed of blast furnace (iron-making) slags from the early to mid-20th Century. Some of these form tidal barriers and formal coastal defence structures, but larger deposits are associated with historical coastal disposal in many former areas of iron and steel production, notably the Cumbrian coast of England. Slag deposits are dominated by melilite phases (e.g. gehlenite), with evidence of secondary mineral formation (e.g. gypsum, calcite) indicative of weathering. Leaching tests typically show lower element (e.g. Ba, V, Cr, Fe) release under seawater leaching scenarios compared to deionised water, largely ascribable to the pH buffering provided by the former. Only Mn and Mo showed elevated leaching concentrations in seawater treatments, though at modest levels (<3 mg/L and 0.01 mg/L, respectively). No significant leaching of potentially ecotoxic elements such as Cr and V (mean leachate concentrations <0.006 mg/L for both) were apparent in seawater, which micro-X-Ray Absorption Near Edge Structure (μXANES) analysis show are both present in slags in low valence (and low toxicity) forms. Although there may be physical hazards posed by extensive erosion of deposits in high-energy coastlines, the data suggest seawater leaching of coastal iron and steel slags in the UK is likely to pose minimal environmental risk.

Citation

Riley, A. L., Cameron, J., Burke, I. T., Onnis, P., Macdonald, J. M., Gandy, C. J., Crane, R. A., Byrne, P., Comber, S., Jarvis, A. P., Hudson-Edwards, K. A., & Mayes, W. M. (2024). Environmental behaviour of iron and steel slags in coastal settings. Environmental science and pollution research, https://doi.org/10.1007/s11356-024-33897-4

Journal Article Type Article
Acceptance Date May 31, 2024
Online Publication Date Jun 14, 2024
Publication Date Jan 1, 2024
Deposit Date May 31, 2024
Publicly Available Date Jun 17, 2024
Journal Environmental Science and Pollution Research
Print ISSN 0944-1344
Publisher Springer Verlag
Peer Reviewed Peer Reviewed
DOI https://doi.org/10.1007/s11356-024-33897-4
Keywords Iron and steel slag; Legacy Waste; Leachate Formation; Coastal Pollution; Synchrotron; Waste Geochemistry
Public URL https://hull-repository.worktribe.com/output/4693457

Files

Published article (2.3 Mb)
PDF

Publisher Licence URL
http://creativecommons.org/licenses/by/4.0

Copyright Statement
© The Author(s) 2024.
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.





You might also like



Downloadable Citations