All Outputs (26)

A fluorescent probe based on cucurbit[7]uril for the selective recognition of phenylalanine (2020)
Journal Article
Shan, P. H., Kan, J. L., Deng, X. Y., Redshaw, C., Bian, B., Fan, Y., …Xiao, X. (2020). A fluorescent probe based on cucurbit[7]uril for the selective recognition of phenylalanine. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 233, Article 118177. https://doi.org/10.1016/j.saa.2020.118177

© 2020 Elsevier B.V. Herein we describe a simple fluorescence quenching method for the selective recognition and determination of the amino acid phenylalanine (Phe). The use of 1H NMR spectroscopy revealed that the alkaloid palmatine (PAL) can encaps... Read More about A fluorescent probe based on cucurbit[7]uril for the selective recognition of phenylalanine.

Use of titanium complexes bearing diphenolate or calix[n]arene ligands in α-olefin polymerization and the ROP of cyclic esters (2020)
Journal Article
Santoro, O., & Redshaw, C. (2020). Use of titanium complexes bearing diphenolate or calix[n]arene ligands in α-olefin polymerization and the ROP of cyclic esters. Catalysts, 10(2), Article 210. https://doi.org/10.3390/catal10020210

In this review, we discuss the use of titanium complexes bearing either bridged diphenolate or calix[n]arene (n = 4, 6, 8) ligation, in the formation of plastics from α-olefins or via the ring opening polymerization (ROP) of cyclic esters. The synthe... Read More about Use of titanium complexes bearing diphenolate or calix[n]arene ligands in α-olefin polymerization and the ROP of cyclic esters.

Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties (2020)
Journal Article
Zhang, H., Zhu, Z. Q., Zhou, F. H., Redshaw, C., Chen, K., & Xu, J. (2020). Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties. Journal of molecular structure, 1207, Article 127818. https://doi.org/10.1016/j.molstruc.2020.127818

The solvothermal synthesis of three new 2D MOFs is reported. From the reaction of 3,5-di(1H-imidazol- 1-yl)pyridine (dip) and the metal salts Co(NO3)2$6H2O, Cd(NO3)2$4H2O or Zn(NO3)2$4H2O, the three MOFs [Co(dip)2(SCN)2] (1), {[Cd(dip)2(H2O)2]$(NO3... Read More about Two dimensional coordination polymers based on 3,5-di(1H-imidazol-1-yl)pyridine and their fluorescence properties.

Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies (2020)
Journal Article
Alshamrani, A. F., Prior, T. J., Burke, B. P., Roberts, D. P., Archibald, S. J., Higham, L. J., …Redshaw, C. (2020). Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies. Inorganic chemistry, 59(4), 2367-2378. https://doi.org/10.1021/acs.inorgchem.9b03239

Reaction of [ReOCl3(PPh3)2] or [ReO2I(PPh3)2] with 2,2′-diphenylglycine (dpgH2) in refluxing ethanol afforded the air-stable complex [ReO(dpgH)(dpg)(PPh3)] (1). Treatment of [ReO(OEt)I2(PPh3)2] with 1,2,3-triaza-7-phosphaadamantane (PTA) afforded the... Read More about Water-Soluble Rhenium Phosphine Complexes Incorporating the Ph2C(X) Motif (X = O–, NH–): Structural and Cytotoxicity Studies.

Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters (2020)
Journal Article
Sun, Z., Zhao, Y., Santoro, O., Elsegood, M. R., Bedwell, E. V., Zahra, K., …Redshaw, C. (2020). Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters. Catalysis science & technology, 10(6), 1619-1639. https://doi.org/10.1039/c9cy02571e

The known dichloride complexes [TiCl2L(O)2(OR)2] (type I: R = Me (1), n-Pr (2) and n-pentyl (3); L(OH)2(OR)2 = 1,3-dialkyloxy-p-tert-butylcalix[4]arene), together with the new complexes {[TiL(O)3(OR)]2(μ-Cl)2}·6MeCN (R = n-decyl (4·6MeCN)), and [Ti(N... Read More about Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters.

Studies on Lewis-Acid Induced Reactions of 8-Methoxy[2.2]metacyclophanes: A New Synthetic Route to Alkylated Pyrenes (2020)
Journal Article
Monarul Islam, M., Feng, X., Wang, C. Z., Rahman, S., Alodhayb, A., Georghiou, P. E., …Yamato, T. (2020). Studies on Lewis-Acid Induced Reactions of 8-Methoxy[2.2]metacyclophanes: A New Synthetic Route to Alkylated Pyrenes. ChemistrySelect, 5(4), 1269-1274. https://doi.org/10.1002/slct.201903048

Anti-8-methoxy[2.2]metacyclophanes (MCPs) 5 a–b were obtained via pyrolysis of the corresponding syn-thiatetraoxide cyclophanes 4 a–b. Coupling reactions of 4-tert-butyl-1-methoxy-2,6-bis(mercaptomethyl)benzenes 1 a–b and 1,5-bis(chloro-methyl)-2,4-d... Read More about Studies on Lewis-Acid Induced Reactions of 8-Methoxy[2.2]metacyclophanes: A New Synthetic Route to Alkylated Pyrenes.