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Robust measurement of flexoelectro-optic switching with different surface alignments (2019)
Journal Article
Sandford O’Neill, J. J., Fells, J. A. J., Welch, C., Mehl, G., Yip, W. C., Wilkinson, T. D., …Morris, S. M. (2019). Robust measurement of flexoelectro-optic switching with different surface alignments. Journal of applied physics, 125(9), doi:10.1063/1.5086241

The alignment of chiral nematic liquid crystals in the so-called uniform lying helix geometry allows for the observation and exploitation of the flexoelectro-optic effect. However, high-quality uniform lying helix alignment is difficult to achieve re... Read More

1H NMR study of molecular order and dynamics in CBC9CB Liquid Crystal (2019)
Journal Article
Aluculesei, A., Cachitas, H., Carvalho, J., Vaca Chavez, F., Figueirinhas, J. L., Sebastião, P. J., …Mehl, G. H. (2019). 1H NMR study of molecular order and dynamics in CBC9CB Liquid Crystal. Physical chemistry chemical physics : PCCP, doi:10.1039/c8cp06868b

Molecular order and dynamics of the CB-C9-CB liquid crystalline dimer exhibiting the nematic (N) and the twist bend nematic (Ntb) phases were investigated by proton NMR spectroscopy, using fields of 0.78T and 7.04T, and relaxometry. The first relaxom... Read More

Proton and Deuterium NMR study of the CBC9CB Dimer System (2019)
Journal Article
Carvalho, J., Cruz, C., Figueirinhas, J. L., Tamba, M., Kohlmeier, A., & Mehl, G. H. (in press). Proton and Deuterium NMR study of the CBC9CB Dimer System. Journal of Physical Chemistry B, doi:10.1021/acs.jpcb.8b11526

Using proton and deuterium NMR spectroscopy , this work provides a description of the molecular order of the mesogenic grops in both the Ntb and the classical nematic phase (N), of the liquid crystal dimer CB-C9CB. The proton NMR data were collected... Read More

The induction of the Ntb phase in mixtures (2018)
Journal Article
Ramou, E., Welch, C., Hussey, J., Ahmed, Z., Karahaliou, P. K., & Mehl, G. H. (2018). The induction of the Ntb phase in mixtures. Liquid crystals, 45(13-15), 1929-1935. doi:10.1080/02678292.2018.1524523

We report the induction of the Ntb phase over a wide temperature and concentration range in a binary system. This was achieved by addition of a flexible dopant without LC properties to a flexible dimer exhibiting only a nematic LC phase. The Ntb phas... Read More

Dynamic calorimetry and XRD studies of the nematic and twist-bend nematic phase transitions in a series of dimers with increasing spacer length (2018)
Journal Article
Stevenson, W. D., Zou, H., Zeng, X., Welch, C., Ungar, G., & Mehl, G. H. (2018). Dynamic calorimetry and XRD studies of the nematic and twist-bend nematic phase transitions in a series of dimers with increasing spacer length. Physical chemistry chemical physics : PCCP, 25268-25274. doi:10.1039/c8cp05744c

A modulated and conventional DSC study of the transitions between the twist-bend nematic (Ntb), regular nematic (N) and isotropic liquid (Iso) phases was performed on a series of difluoroterphenyl-based dimers with (CH2)n spacers; n = 5, 7, 9, 11. Th... Read More

Lyotropic ‘hairy’ TiO2 nanorods (2018)
Journal Article
Cheng, F., Verrelli, E., Alharthi, F. A., Kelly, S. M., O'Neill, M., Kemp, N. T., …Anthopoulos, T. (2019). Lyotropic ‘hairy’ TiO2 nanorods. Nanoscale advances, 1, 254-264. doi:10.1039/c8na00054a

We report the synthesis of the first stable, solution-processable and photocrosslinkable hybrid organic/inorganic titanium dioxide nanorods as ‘hairy rods’ coated with phosphonate ligands with photoreactive coumarin groups located in a terminal posit... Read More

Supramolecular organization of liquid-crystal dimers-bis-cyanobiphenyl alkanes on HOPG by scanning tunneling microscopy (2018)
Journal Article
Krzyzewska, K., Jaroch, T., Maranda-Niedbała, A., Pociecha, D., Górecka, E., Ahmed, Z., …Nowakowski, R. (2018). Supramolecular organization of liquid-crystal dimers-bis-cyanobiphenyl alkanes on HOPG by scanning tunneling microscopy. Nanoscale, 10(34), 16201-16210. doi:10.1039/c8nr02069h

2D supramolecular organization of a series of six cyanobiphenyl bimesogens deposited on highly oriented pyrolytic graphite (HOPG) is studied by scanning tunneling microscopy (STM). The adsorbates are 1,ω-bis(4-cyanobiphenyl-4’-yl)alkanes (CBnCB) with... Read More

EPR study of the polydomain structure of the twist-bend nematic phase of CB9CB in the bulk (2018)
Journal Article
Bacchiocchi, C., Tamba, M., Mehl, G. H., Arcioni, A., Miglioli, I., & Zannoni, C. (2018). EPR study of the polydomain structure of the twist-bend nematic phase of CB9CB in the bulk. Liquid crystals, 45(13-15), 2109-2120. doi:10.1080/02678292.2018.1501110

EPR spin probe spectra of the liquid crystal phases exhibited, in the bulk, by the 1″,9″-bis(4- cyanobiphenyl-4’-yl)nonane (CB9CB) bent-shape dimer showed that, on cooling from the isotropic phase, this material forms a uniaxial nematic phase with a... Read More

Characterization of large tilt-angle flexoelectro-optic switching in chiral nematic liquid crystal devices (2018)
Journal Article
Wang, X., Fells, J. A. J., Welch, C., Tamba, M., Mehl, G. H., Morris, S. M., & Elston, S. J. (2018). Characterization of large tilt-angle flexoelectro-optic switching in chiral nematic liquid crystal devices. Liquid crystals, 1-7. doi:10.1080/02678292.2018.1502822

The “flexoelastic ratio”, which is the ratio of the effective flexoelectric coefficient to the elastic coefficients, is commonly used to characterize the electro-optic behavior of chiral nematic liquid crystal (LC) devices that exhibit flexoelectro-o... Read More

Tuning selective reflection of light by surface anchoring in cholesteric cells with oblique helicoidal structures (2018)
Journal Article
Iadlovska, O. S., Maxwell, G. R., Babakhanova, G., Mehl, G. H., Welch, C., Shiyanovskii, S. V., & Lavrentovich, O. D. (2018). Tuning selective reflection of light by surface anchoring in cholesteric cells with oblique helicoidal structures. Optics letters, 43(8), (1850-1853). doi:10.1364/ol.43.001850. ISSN 0146-9592

Selective reflection of light by oblique helicoidal cholesteric (ChOH) can be tuned in a very broad spectral range by an applied electric field. In this work, we demonstrate that the peak wavelength of the selective reflection can be controlled by su... Read More

Characterization of the Submicrometer Hierarchy Levels in the Twist-Bend Nematic Phase with Nanometric Helices via Photopolymerization. Explanation for the Sign Reversal in the Polar Response (2017)
Journal Article
Panov, V. P., Sreenilayam, S. P., Panarin, Y. P., Vij, J. K., Welch, C. J., & Mehl, G. H. (2017). Characterization of the Submicrometer Hierarchy Levels in the Twist-Bend Nematic Phase with Nanometric Helices via Photopolymerization. Explanation for the Sign Reversal in the Polar Response. Nano Letters, 17(12), (7515-7519). doi:10.1021/acs.nanolett.7b03441. ISSN 1530-6984

Photopolymerization of a reactive mesogen mixed with a mesogenic dimer, shown to exhibit the twist-bend nematic phase (NTB), reveals the complex structure of the self-deformation patterns observed in planar cells. The polymerized reactive mesogen ret... Read More

Characterization of the sub-micrometer hierarchy levels in the twist-bend nematic phase with nanometric helices via photopolymerization. Explanation for the sign reversal in the polar response (2017)
Journal Article
Panov, V. P., Sreenilayam, S. P., Panarin, Y. P., Vij, J. K., Welch, C. J., & Mehl, G. H. (2017). Characterization of the sub-micrometer hierarchy levels in the twist-bend nematic phase with nanometric helices via photopolymerization. Explanation for the sign reversal in the polar response. Nano Letters, 17(12), 7515–7519. doi:10.1021/acs.nanolett.7b03441

Photopolymerization of a reactive mesogen mixed with a mesogenic dimer, shown to exhibit the twist-bend nematic phase (NTB), reveals the complex structure of the self-deformation patterns observed in planar cells. The polymerized reactive mesogen ret... Read More

Molecular organization in the twist–bend nematic phase by resonant X-ray scattering at the Se K-edge and by SAXS, WAXS and GIXRD (2017)
Journal Article
Stevenson, W. D., Ahmed, Z., Zeng, X. B., Welch, C., Ungar, G., & Mehl, G. H. (2017). Molecular organization in the twist–bend nematic phase by resonant X-ray scattering at the Se K-edge and by SAXS, WAXS and GIXRD. Physical chemistry chemical physics : PCCP, 19(21), (13449-13454). doi:10.1039/c7cp01404j. ISSN 1463-9076

© the Owner Societies 2017. Using a magnetically aligned liquid crystal mixture containing a novel Se-labelled dimer and the difluoroterphenyl dimer DTC5C7, the twist-bend nematic phase (N tb ) was studied by the resonant scattering of hard X-rays an... Read More

Twist-bend nematic phase in cyanobiphenyls and difluoroterphenyls bimesogens (2016)
Journal Article
Panov, V. P., Vij, J. K., & Mehl, G. H. (2017). Twist-bend nematic phase in cyanobiphenyls and difluoroterphenyls bimesogens. Liquid crystals, 44(1), (147-159). doi:10.1080/02678292.2016.1254289. ISSN 0267-8292

The paper reviews assignment of the low-temperature nematic phase observed in simple bimesogenic or dimeric systems based on cyanobiphenyls and difluoroterphenyls to the twist-bend nematic phase, NTB, using a range of experimental techniques. These i... Read More

Light scattering study of the “pseudo-layer” compression elastic constant in a twist-bend nematic liquid crystal (2016)
Journal Article
Parsouzi, Z., Pardaev, S. A., Ahmed, Z., Mehl, G. H., Gleeson, J. T., Lavrentovich, O. D., …Sprunt, S. (2016). Light scattering study of the “pseudo-layer” compression elastic constant in a twist-bend nematic liquid crystal. Physical chemistry chemical physics : PCCP, 18(46), 31645-31652. doi:10.1039/C6CP06292J

The nematic twist-bend (TB) phase, exhibited by certain achiral thermotropic liquid crystalline (LC) dimers, features a nanometer-scale, heliconical rotation of the average molecular long axis (director) with equally probable left- and right-handed d... Read More

Comparative analysis of anisotropic material properties of uniaxial nematics formed by flexible dimers and rod-like monomers (2016)
Journal Article
Ahmed, Z., Mehl, G. H., Welch, C., Cukrov, G., Lavrentovich, O. D., Mosaddeghian Golestani, Y., …Xiang, J. (2017). Comparative analysis of anisotropic material properties of uniaxial nematics formed by flexible dimers and rod-like monomers. Liquid crystals, 44(1), (219-231). doi:10.1080/02678292.2016.1240248. ISSN 0267-8292

We report temperature dependencies of material properties such as dielectric anisotropy, birefringence, splay (K₁₁), twist (K₂₂), and bend (K₃₃) elastic constants of the uniaxial nematic (N) phase formed by flexible dimers of DTC5C9 and compare their... Read More

Director configuration in the twist-bend nematic phase of CB11CB (2016)
Journal Article
Miglioli, I., Bacchiocchi, C., Arcioni, A., Kohlmeier, A., Mehl, G. H., & Zannoni, C. (2016). Director configuration in the twist-bend nematic phase of CB11CB. Journal of materials chemistry. publ. by The Royal Society of Chemistry. C, Materials for optical and electronic devices /, 4(41), 9887-9896. doi:10.1039/c6tc03246j

The director distribution in the nematic phases exhibited by the 100,1100-bis(4-cyanobiphenyl-40-yl)undecane (CB11CB) liquid crystal has been studied in the bulk with the EPR spin probe technique. EPR spectra confirmed the presence of an higher tempe... Read More

Deuteron and proton NMR study of D₂, p-dichlorobenzene and 1,3,5-trichlorobenzene in bimesogenic liquid crystals with two nematic phases (2016)
Journal Article
Ahmed, Z., Burnell, E. E., Welch, C., Mehl, G. H., & Dong, R. Y. (2016). Deuteron and proton NMR study of D₂, p-dichlorobenzene and 1,3,5-trichlorobenzene in bimesogenic liquid crystals with two nematic phases. Chemical Physics Letters, 659, 48-54. doi:10.1016/j.cplett.2016.07.005

The solutes dideuterium, 1,3,5-trichlorobenzene and p-dichlorobenzene (pdcb) are co-dissolved in a 61/39 wt% mixture of CBC9CB/5CB, a bimesogenic liquid crystal with two nematic phases. NMR spectra are collected for each solute. The local electric fi... Read More

Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition (2016)
Journal Article
Sebastián, N., Tamba, M. G., Stannarius, R., de la Fuente, M. R., Salamonczyk, M., Cukrov, G., …Eremin, A. (2016). Mesophase structure and behaviour in bulk and restricted geometry of a dimeric compound exhibiting a nematic-nematic transition. Physical chemistry chemical physics : PCCP, 18(28), 19299-19308. doi:10.1039/c6cp03899a

We present structural studies of a dimeric compound composed of a central heptyl spacer linking two mesogens consisiting of terphenyl units at which two adjacent fluoro groups are attached to each central ring. The terminal rings are linked to pentyl... Read More