Mono-oxo molybdenum(VI) and tungsten(VI) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters

Sun, Ziyue; Zhao, Yanxia; Prior, Timothy J.; Elsegood, Mark R.J.; Wang, Kuiyuan; Xing, Tian; Redshaw, Carl

doi:10.1039/c8dt04566f

All Outputs (8)

Silver Nanoparticle-Immobilized Schiff-Base Macrocycles as Nanozymes with Peroxidase Mimic Activity for Antibacterial Films (2024)
Journal Article
Wang, K., Redshaw, C., Zhao, X., Wang, A., Chen, K., & Qiao, Y. (2024). Silver Nanoparticle-Immobilized Schiff-Base Macrocycles as Nanozymes with Peroxidase Mimic Activity for Antibacterial Films. ACS Applied Nano Materials, 7(14), 16274–16282. https://doi.org/10.1021/acsanm.4c02258

The development of nanozymes has emerged as a promising pathway for combating bacterial infections. In this work, Ag/Schiff base nanozymes are obtained through the in situ reduction method on [2 + 3] Schiff base macrocycles using eco-friendly reducta... Read More about Silver Nanoparticle-Immobilized Schiff-Base Macrocycles as Nanozymes with Peroxidase Mimic Activity for Antibacterial Films.

Corrigendum to “Iron complexes of [2 + 2] and [6 + 6] Schiff-base macrocycles derived from 2,2′-oxydianiline and their applications” [Inorg. Chem. Commun. 139 (2022) 109376] (Inorganic Chemistry Communications (2022) 139, (S1387700322001848), (10.1016/j.inoche.2022.109376)) (2023)
Journal Article
Wang, K., Chen, K., Cai, J., & Redshaw, C. (2023). Corrigendum to “Iron complexes of [2 + 2] and [6 + 6] Schiff-base macrocycles derived from 2,2′-oxydianiline and their applications” [Inorg. Chem. Commun. 139 (2022) 109376] (Inorganic Chemistry Communications (2022) 139, (S1387700322001848), (10.1016/j.inoche.2022.109376)). Inorganic Chemistry Communications, 153, Article 110740. https://doi.org/10.1016/j.inoche.2023.110740

The correct formula of 3 is [Fe2(L2H4)][FeBr3OFeBr3]2‧8MeCN.
The revised CIF has been deposited with the CSD
An updated version of the supplementary information file is provided.

Iron complexes of [2+2] and [6+6] Schiff-base macrocycles derived from 2,2′-oxydianiline and their applications (2022)
Journal Article
Wang, K., Chen, K., Cai, J., & Redshaw, C. (2022). Iron complexes of [2+2] and [6+6] Schiff-base macrocycles derived from 2,2′-oxydianiline and their applications. Inorganic Chemistry Communications, 139, Article 109376. https://doi.org/10.1016/j.inoche.2022.109376

Reaction of [2+2] and [6+6] Schiff-base macrocycles with FeBr2 are reported, together with preliminary studies of the applications of the iron-containing products. In particular, we have investigated peroxidase-like activity and determination of H2O2... Read More about Iron complexes of [2+2] and [6+6] Schiff-base macrocycles derived from 2,2′-oxydianiline and their applications.

Pd-Immobilized Schiff Base Double-Layer Macrocycle: Synthesis, Structures, Peroxidase Mimic Activity, and Antibacterial Performance (2021)
Journal Article
Wang, K., Chen, K., Prior, T. J., Feng, X., & Redshaw, C. (2022). Pd-Immobilized Schiff Base Double-Layer Macrocycle: Synthesis, Structures, Peroxidase Mimic Activity, and Antibacterial Performance. ACS Applied Materials & Interfaces, 14(1), 1423–1433. https://doi.org/10.1021/acsami.1c19795

Di-, tri-, and tetra-aldehydes have been employed to access new [2 + 2] [2 + 3] and [2 + 4] double-layer Schiff base macrocycles. The [2 + 3] compound has been used for the immobilization of Pd and the resulting composite has been employed as a perox... Read More about Pd-Immobilized Schiff Base Double-Layer Macrocycle: Synthesis, Structures, Peroxidase Mimic Activity, and Antibacterial Performance.

Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters (2021)
Journal Article
Wang, K., Prior, T. J., Hughes, D. L., Arbaoui, A., & Redshaw, C. (2021). Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(23), 8057-8069. https://doi.org/10.1039/d1dt00711d

Reaction of the [2 + 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2(R = Me, L1H2;tBu, L2H2) with FeBr2afforded the complexes [FeBr(L1H2)]2[(FeBr3)2O]·2MeCN (1·2MeCN), [FeBr(L2H2)][X] (X = 0.5(FeBr3)2O,2·0.5MeCN, X = Br,... Read More about Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters.

Emission and theoretical studies of Schiff-base [2+2] macrocycles derived from 2,2′-oxydianiline and zinc complexes thereof (2021)
Journal Article
Wang, K., Chen, K., Bian, T., Chao, Y., Yamato, T., Xing, F., Prior, T. J., & Redshaw, C. (2021). Emission and theoretical studies of Schiff-base [2+2] macrocycles derived from 2,2′-oxydianiline and zinc complexes thereof. Dyes and pigments : an international journal, 190, Article 109300. https://doi.org/10.1016/j.dyepig.2021.109300

The emission properties of a number of solvates of the [2+2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][O(2-C6H4N)2]}2 (R = Me L1H2, tBu L2H2, Cl L3H2), formed by reacting 2,6-dicarboxy-4-R-phenol with 2,2′-oxydianiline (2-aminophenylethe... Read More about Emission and theoretical studies of Schiff-base [2+2] macrocycles derived from 2,2′-oxydianiline and zinc complexes thereof.

Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle (2019)
Journal Article
Wang, K., Prior, T. J., & Redshaw, C. (2019). Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle. Chemical communications : Chem comm / the Royal Society of Chemistry, 55(75), 11279-11282. https://doi.org/10.1039/c9cc04494a

Homo-dinuclear Co and Zn complexes derived from the macrocycle LH2, {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2 (R = Me, tBu), revealed near inactivity for the ring opening polymerization (ROP) of the cyclic esters δ-valerolactone (δ-VL) and ϵ... Read More about Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle.

Mono-oxo molybdenum(VI) and tungsten(VI) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters (2018)
Journal Article
Sun, Z., Zhao, Y., Prior, T. J., Elsegood, M. R., Wang, K., Xing, T., & Redshaw, C. (2019). Mono-oxo molybdenum(VI) and tungsten(VI) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 48(4), 1454-1466. https://doi.org/10.1039/c8dt04566f

The mono-oxo aryloxide complexes [M(O)(L1)2] (M = Mo (1·hexane), W(2·2MeCN)) have been prepared from [Mo(O)(Cl)4] or [W(O)(Ot-Bu)4] and two equivalents of the di-phenol 2,2/-ethylidenebis(4,6-di-tert-butylphenol) L1H2, respectively. Use of in-situ ge... Read More about Mono-oxo molybdenum(VI) and tungsten(VI) complexes bearing chelating aryloxides: synthesis, structure and ring opening polymerization of cyclic esters.