Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template

Elaigwu, Sunday E.; Kyriakou, Georgios; Prior, Timothy J.; Greenway, Gillian M.

doi:10.1016/j.matlet.2014.03.003

All Outputs (8)

High-pressure studies of palladium and platinum thioether macrocyclic dihalide complexes (2014)
Journal Article
Allan, D. R., Bailey, D., Bird, N., Blake, A. J., Champness, N. R., Huang, D., Keane, C. P., McMaster, J., Prior, T. J., Tidey, J. P., & Schröder, M. (2014). High-pressure studies of palladium and platinum thioether macrocyclic dihalide complexes. Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 70(3), 469-486. https://doi.org/10.1107/S2052520614008786

The mononuclear macrocyclic PdII complex cis-[PdCl 2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclo- nonane) converts at 44kbar into an intensely coloured chain polymer exhibiting distorted octahedral coordination at the metal centre and an unprecedented... Read More about High-pressure studies of palladium and platinum thioether macrocyclic dihalide complexes.

Stabilization of boron carbide via silicon doping (2014)
Journal Article
Proctor, J. E., Bhakhri, V., Hao, R., Prior, T. J., Scheler, T., Gregoryanz, E., Chhowalla, M., & Giulani, F. (2015). Stabilization of boron carbide via silicon doping. Journal of Physics: Condensed Matter, 27(1), Article 015401. https://doi.org/10.1088/0953-8984/27/1/015401

Boron carbide is one of the lightest and hardest ceramics, but its applications are limited by its poor stability against a partial phase separation into separate boron and carbon. Phase separation is observed under high non-hydrostatic stress (both... Read More about Stabilization of boron carbide via silicon doping.

Ethyleneglycol tungsten complexes of calix[6 and 8]arenes: Synthesis, characterization and ROP of ε-caprolactone (2014)
Journal Article
Li, Y., Zhao, K.-Q., Feng, C., Elsegood, M. R., Prior, T. J., Sun, X., & Redshaw, C. (2014). Ethyleneglycol tungsten complexes of calix[6 and 8]arenes: Synthesis, characterization and ROP of ε-caprolactone. Dalton Transactions : an international journal of inorganic chemistry, 43(36), 13612-13619. https://doi.org/10.1039/c4dt01936a

By varying the reaction conditions, the reaction of [W(eg)₃] (eg = 1,2-ethanediolato) with p-tert-butylcalix[n]areneHn (n = 6 or 8) in refluxing toluene affords, following work-up, a number of products which have been fully characterized. From the re... Read More about Ethyleneglycol tungsten complexes of calix[6 and 8]arenes: Synthesis, characterization and ROP of ε-caprolactone.

A novel fluorescent "turn-on" chemosensor for nanomolar detection of Fe(III) from aqueous solution and its application in living cells imaging (2014)
Journal Article
Nandre, J., Patil, S., Patil, V., Yu, F., Chen, L., Sahoo, S., Prior, T., Redshaw, C., Mahulikar, P., & Patil, U. (2014). A novel fluorescent "turn-on" chemosensor for nanomolar detection of Fe(III) from aqueous solution and its application in living cells imaging. Biosensors & bioelectronics, 61(November), 612-617. https://doi.org/10.1016/j.bios.2014.06.017

An electronically active and spectral sensitive fluorescent “turn-on” chemosensor (BTP-1) based on the benzo-thiazolo-pyrimidine unit was designed and synthesized for the highly selective and sensitive detection of Fe³⁺ from aqueous medium. With Fe³⁺... Read More about A novel fluorescent "turn-on" chemosensor for nanomolar detection of Fe(III) from aqueous solution and its application in living cells imaging.

A series of new microporous lanthanide frameworks [Ln(C8H3NO6)(L)0.5(H2O)]·3H2O (Ln = Pr, Nd, Sm and Gd, and L = C8H4O4or C8H4O4/C8H3NO6): Syntheses, characterization and photoluminescence properties (2014)
Journal Article
Panyarat, K., Prior, T. J., & Rujiwatra, A. (2014). A series of new microporous lanthanide frameworks [Ln(C8H3NO6)(L)0.5(H2O)]·3H2O (Ln = Pr, Nd, Sm and Gd, and L = C8H4O4or C8H4O4/C8H3NO6): Syntheses, characterization and photoluminescence properties. Polyhedron, 81, 74-80. https://doi.org/10.1016/j.poly.2014.05.044

Four new microporous lanthanide coordination polymers of general formula [Ln(C8H3NO6)(L)0.5(H 2O)]·3H2O (Ln = Pr, Nd, Sm and Gd, and L = C 8H4O4 or C8H4O 4/C8H3NO6) were hydrothermally synthesized using in situ ligand synthesis. The complexes are iso... Read More about A series of new microporous lanthanide frameworks [Ln(C8H3NO6)(L)0.5(H2O)]·3H2O (Ln = Pr, Nd, Sm and Gd, and L = C8H4O4or C8H4O4/C8H3NO6): Syntheses, characterization and photoluminescence properties.

Organoaluminium complexes of ortho-, meta-, para-anisidines: synthesis, structural studies and ROP of ε-caprolactone (and rac-lactide) (2014)
Journal Article
Li, Y., Zhao, K.-Q., Elsegood, M. R. J., Prior, T. J., Sun, X., Mo, S., & Redshaw, C. (2014). Organoaluminium complexes of ortho-, meta-, para-anisidines: synthesis, structural studies and ROP of ε-caprolactone (and rac-lactide). Catalysis science & technology, 4(9), 3025-3031. https://doi.org/10.1039/c4cy00624k

Reaction of Me₃Al (two equivalents) with ortho-, meta- or para-anisidine, (OMe)(NH₂)C₆H₄, affords the complexes {[1,2-(OMe),NC₆H₄(μ-Me₂Al)](μ-Me₂Al)}₂ (1), [1,3-(Me₃AlOMe),NHC₆H₄(μ-Me₂Al)]2 (2) or [1,4-(Me₃AlOMe),NHC₆H₄(μ-Me₂Al)]₂ (3), respectively.... Read More about Organoaluminium complexes of ortho-, meta-, para-anisidines: synthesis, structural studies and ROP of ε-caprolactone (and rac-lactide).

Biomimetic polyorganosiloxanes: Model compounds for new materials (2014)
Journal Article
Kociok-Köhn, G., Mahon, M. F., Molloy, K. C., Price, G. J., Prior, T. J., & Smith, D. (2014). Biomimetic polyorganosiloxanes: Model compounds for new materials. Dalton Transactions : an international journal of inorganic chemistry, 43(21), 7734-7746. https://doi.org/10.1039/c4dt00554f

The chemistry of N-organosilylalkyl-substituted heterocyclic bases (thymine, adenine and cytosine) is described, covering the structures of model compounds, the synthesis of substituted oligo-siloxanes and a preliminary report of the synthesis of a p... Read More about Biomimetic polyorganosiloxanes: Model compounds for new materials.

Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template (2014)
Journal Article
Elaigwu, S. E., Kyriakou, G., Prior, T. J., & Greenway, G. M. (2014). Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template. Materials letters, 123, 198-201. https://doi.org/10.1016/j.matlet.2014.03.003

A new microwave-assisted hydrothermal synthesis of carbon monolith is reported in this work. The process uses microwave heating at 100 °C under acidic condition by employing a triblock copolymer F127 as the template, and resorcinol–formaldehyde as th... Read More about Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template.