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A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine (2023)
Journal Article
Shan, P. H., Pan, D. W., Chen, L. X., Prior, T. J., Redshaw, C., Tao, Z., & Xiao, X. (2023). A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine. Journal of molecular structure, 1294(2), Article 136418. https://doi.org/10.1016/j.molstruc.2023.136418

Herein, we report a simple fluorescence-enhanced system for the selective recognition and determination of the insecticide pymetrozine. 1H NMR spectroscopic data indicate that 1,2-bis(4-pyridyl)ethylene (BPE) is partially encapsulated in the cavity o... Read More about A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine.

Real life test of a novel super performance dew point cooling system in operational live data centre (2023)
Journal Article
Ma, X., Zeng, C., Zhu, Z., Zhao, X., Xiao, X., Akhlaghi, Y. G., & Shittu, S. (2023). Real life test of a novel super performance dew point cooling system in operational live data centre. Applied energy, 348, Article 121483. https://doi.org/10.1016/j.apenergy.2023.121483

This paper presents the development and application of a super performance dew point cooling technology for data centres. The novel super performance dew point cooler showed considerably improved energy saving and carbon reduction for data centre coo... Read More about Real life test of a novel super performance dew point cooling system in operational live data centre.

The Energy-Saving Potential of Air-Side Economisers in Modular Data Centres: Analysis of Opportunities and Risks in Different Climates (2023)
Journal Article
Badiei, A., Jadowski, E., Sadati, S., Beizaee, A., Li, J., Khajenoori, L., …Xiao, X. (2023). The Energy-Saving Potential of Air-Side Economisers in Modular Data Centres: Analysis of Opportunities and Risks in Different Climates. Sustainability, 15(14), Article 10777. https://doi.org/10.3390/su151410777

This study examines the feasibility of utilising outside air for ‘free cooling’ in modular data centres through the implementation of an air-side economiser, as an alternative to traditional mechanical cooling systems. The objective is to offset the... Read More about The Energy-Saving Potential of Air-Side Economisers in Modular Data Centres: Analysis of Opportunities and Risks in Different Climates.

Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine (2023)
Journal Article
Liu, Z. N., Hu, J. H., Xiong, Y., Zhang, J. Y., Hou, R. X., Li, C. R., …Xiao, X. (2023). Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine. Inorganica Chimica Acta, 556, Article 121632. https://doi.org/10.1016/j.ica.2023.121632

In this study, single crystal X-ray diffraction and 1H NMR spectroscopy were used to examine the interaction of the guest 1,5-pentanediamine with inverted cucurbit[6]uril (iQ[6]) in the presence of [ZnCl4]2− anion. The results show that [ZnCl4]2− and... Read More about Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine.

Cucurbit[n]uril-based supramolecular hydrogels: Synthesis, properties and applications (2023)
Journal Article
Hu, J. H., Huang, Y., Redshaw, C., Tao, Z., & Xiao, X. (2023). Cucurbit[n]uril-based supramolecular hydrogels: Synthesis, properties and applications. Coordination chemistry reviews, 489, Article 215194. https://doi.org/10.1016/j.ccr.2023.215194

Due to their dynamic qualities and potential uses in fields such as biomedicine, tissue engineering, drug delivery, soft materials, and sensing, hydrogels have gained increased attention in recent years. Concurrently, the application of cucurbit[n]ur... Read More about Cucurbit[n]uril-based supramolecular hydrogels: Synthesis, properties and applications.

Novel fluorescent probe for sequential recognition of Zn2+ and pyrophosphate in aqueous based on aggregation-induced emission (2023)
Journal Article
Bai, Q., Xia, Y., Liang, G., Wang, C., Redshaw, C., & Xiao, X. (2023). Novel fluorescent probe for sequential recognition of Zn2+ and pyrophosphate in aqueous based on aggregation-induced emission. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 295, Article 122585. https://doi.org/10.1016/j.saa.2023.122585

A new fluorescent probe (E)-4-(4-([2,2':6',2''-terpyridin]-4'-yl)styryl)-1-dodecylpyridin-1-ium (TPy-SD), with the aggregation-induced emission (AIE) property in aqueous solution, has been synthesized and characterized. The new probe, TPy-SD exhibite... Read More about Novel fluorescent probe for sequential recognition of Zn2+ and pyrophosphate in aqueous based on aggregation-induced emission.

Supramolecular Assembly of Tetramethylcucurbit[6]uril and 2-Picolylamine (2023)
Journal Article
Fan, Y., Cen, R., Shan, P., Redshaw, C., Cong, H., Xiao, X., & Ge, Q. (2023). Supramolecular Assembly of Tetramethylcucurbit[6]uril and 2-Picolylamine. ACS Omega, 8(11), 9919–9924. https://doi.org/10.1021/acsomega.2c06989

The supramolecular assembly of symmetrical tetramethylcucurbit[6]uril (TMeQ[6]) and 2-picolylamine (AMPy) has been investigated via various techniques, including ultraviolet-visible (UV-vis) and nuclear magnetic resonance spectroscopy, isothermal tit... Read More about Supramolecular Assembly of Tetramethylcucurbit[6]uril and 2-Picolylamine.

Supramolecular Room-Temperature Phosphorescent Hydrogel Based on Hexamethyl Cucurbit[5]uril for Cell Imaging (2023)
Journal Article
Sun, X. R., Yang, H. P., Zhang, W., Zhang, S., Hu, J. H., Liu, M., …Xiao, X. (2023). Supramolecular Room-Temperature Phosphorescent Hydrogel Based on Hexamethyl Cucurbit[5]uril for Cell Imaging. ACS Applied Materials & Interfaces, https://doi.org/10.1021/acsami.2c17891

The host-guest interaction between hexamethyl cucurbit[5]uril (HmeQ[5]) and 1,4-diaminobenzene (DB) was investigated, and a new low-molecular-weight supramolecular gel was prepared by a simple heating/mixing cooling method. The structure and properti... Read More about Supramolecular Room-Temperature Phosphorescent Hydrogel Based on Hexamethyl Cucurbit[5]uril for Cell Imaging.

A study of the supramolecular assembly formed by cucurbit[7]uril and 4-cyanophenol (2023)
Journal Article
Yu, Z. C., Lu, Y., Zhao, J., Dai, J. J., Chen, G. R., Shan, P. H., …Xiao, X. (2023). A study of the supramolecular assembly formed by cucurbit[7]uril and 4-cyanophenol. Journal of molecular structure, 1278, Article 134969. https://doi.org/10.1016/j.molstruc.2023.134969

The binding interaction between 4-cyanophenol (4-CY) and cucurbit[7]uril has been studied using 1H NMR spectroscopy, UV–vis absorption spectroscopy, fluorescence spectroscopy and X-ray crystallography. The corresponding absorption and emission spectr... Read More about A study of the supramolecular assembly formed by cucurbit[7]uril and 4-cyanophenol.

Supramolecular structural control: photochemical reactions between styrylpyridine derivative and cucurbit[7,8]urils (2023)
Journal Article
Yuan, S. W., Wu, H., Yang, X. N., Yang, M. X., Luo, Y., Min, W., …Xiao, X. (2023). Supramolecular structural control: photochemical reactions between styrylpyridine derivative and cucurbit[7,8]urils. New journal of chemistry = Nouveau journal de chimie, https://doi.org/10.1039/d2nj03718a

The use of cucurbit[n]urils to control the photochemical reactions of styrylpyridine salts has become a new strategy in supramolecular chemistry. In an aqueous solution, styrylpyridine derivatives (CHP) can form supramolecular complexes of the 1:2 an... Read More about Supramolecular structural control: photochemical reactions between styrylpyridine derivative and cucurbit[7,8]urils.

Supramolecular Self-assembly Formed from Cucurbit[8]uril and p-Hydroxybenzoic Acid (2023)
Journal Article
Wang, C., Yu, Z., Bai, Q., Pan, D., Prior, T. J., Tao, Z., …Xiao, X. (2023). Supramolecular Self-assembly Formed from Cucurbit[8]uril and p-Hydroxybenzoic Acid. Chemical Research in Chinese Universities, https://doi.org/10.1007/s40242-023-3119-9

The binding behavior of cucurbit[8]uril(Q[8]) and p-hydroxybenzoic acid(p-HBA) has been investigated using 1H NMR titration experiments, UV-Vis absorption, isothermal titration calorimetry(ITC), and X-ray crystallography. Results revealed that the Q[... Read More about Supramolecular Self-assembly Formed from Cucurbit[8]uril and p-Hydroxybenzoic Acid.