Zhi Nian Liu
Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine
Liu, Zhi Nian; Hu, Jian Hang; Xiong, Yu; Zhang, Jia Yi; Hou, Run Xin; Li, Chun Rong; Meng, Tie Hong; Prior, Timothy J.; Redshaw, Carl; Xiao, Xin
Authors
Jian Hang Hu
Yu Xiong
Jia Yi Zhang
Run Xin Hou
Chun Rong Li
Tie Hong Meng
Dr Tim Prior T.Prior@hull.ac.uk
Senior Lecturer in Inorganic Chemistry
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
Xin Xiao
Abstract
In this study, single crystal X-ray diffraction and 1H NMR spectroscopy were used to examine the interaction of the guest 1,5-pentanediamine with inverted cucurbit[6]uril (iQ[6]) in the presence of [ZnCl4]2− anion. The results show that [ZnCl4]2− and [Zn(H2O)Cl3]− anions form a honeycomb framework structure, and iQ[6] forms a 1:1 complex with 1,5-pentanediamine. Inverted cucurbit[6]uril forms molecular chains via outer surface interactions, which in turn fill in the honeycomb framework structure. The amino groups at both ends of the 1,5-pentanediamine guest are situated at the entrance of the central cavity, while the alkyl chain part resides in the central cavity of the iQ[6].
Citation
Liu, Z. N., Hu, J. H., Xiong, Y., Zhang, J. Y., Hou, R. X., Li, C. R., …Xiao, X. (2023). Supramolecular Self-assemblies of inverted cucurbit[6]uril with 1,5-pentanediamine. Inorganica Chimica Acta, 556, Article 121632. https://doi.org/10.1016/j.ica.2023.121632
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 7, 2023 |
Online Publication Date | Jun 10, 2023 |
Publication Date | Oct 1, 2023 |
Deposit Date | Jun 13, 2023 |
Publicly Available Date | Jun 11, 2024 |
Journal | Inorganica Chimica Acta |
Print ISSN | 0020-1693 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 556 |
Article Number | 121632 |
DOI | https://doi.org/10.1016/j.ica.2023.121632 |
Keywords | Materials Chemistry; Inorganic Chemistry; Physical and Theoretical Chemistry |
Public URL | https://hull-repository.worktribe.com/output/4312298 |
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Copyright Statement
© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
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