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Synthesis, Crystal Structure, and Cytotoxicity Studies of titanacalix[4 and 8]arene Complexes (2018)
Journal Article
Miller-Shakesby, D. M., Nigam, S., Hughes, D. L., Lopez-Estelles, E., Elsegood, M. R., Cawthorne, C. J., Archibald, S. J., & Redshaw, C. (2018). Synthesis, Crystal Structure, and Cytotoxicity Studies of titanacalix[4 and 8]arene Complexes. Dalton Transactions : an international journal of inorganic chemistry, 47(27), 8992-8999. https://doi.org/10.1039/c8dt01992d

© 2018 The Royal Society of Chemistry. Reaction of 5,11,17,23-tetra-tert-butyl-dihydroxy-26,28-bis(2-pentoxy)calix[4]arene (L(OH)2(Opentyl)2) with [TiCl4] afforded the dichlorotitanoacalix[4]arene complex [TiCl2L(O)2(Opentyl)2] (1) in good yield. Hyd... Read More about Synthesis, Crystal Structure, and Cytotoxicity Studies of titanacalix[4 and 8]arene Complexes.

A microbial role in the construction of Mono Lake carbonate chimneys? (2018)
Journal Article
Brasier, A., Wacey, D., Rogerson, M., Guagliardo, P., Saunders, M., Kellner, S., Mercedes-Martin, R., Prior, T., Taylor, C., Matthews, A., & Reijmer, J. (2018). A microbial role in the construction of Mono Lake carbonate chimneys?. Geobiology, 16(5), 540-555. https://doi.org/10.1111/gbi.12292

Lacustrine carbonate chimneys are striking, metre‐scale constructions. If these were bioinfluenced constructions, they could be priority targets in the search for early and extraterrestrial microbial life. However, there are questions over whether su... Read More about A microbial role in the construction of Mono Lake carbonate chimneys?.

X-ray absorption study of platinum and palladium atoms in argon matrices: Evidence for platinum in a substitutional site and a short Pd–Ar interaction (2018)
Journal Article
Harris, N., Sakr, A. K., Snelling, H. V., & Young, N. A. (2018). X-ray absorption study of platinum and palladium atoms in argon matrices: Evidence for platinum in a substitutional site and a short Pd–Ar interaction. Journal of molecular structure, 1172, 80-88. https://doi.org/10.1016/j.molstruc.2018.06.024

The Pt L3-edge X-ray absorption spectrum of Pt atoms generated in a hollow cathode sputtering device and trapped in an Ar matrix yielded a PtAr distance of 3.78(4) Å with a coordination number of ca. 12 which confirms the evidence from electronic abs... Read More about X-ray absorption study of platinum and palladium atoms in argon matrices: Evidence for platinum in a substitutional site and a short Pd–Ar interaction.

A study of the interaction between inverted cucurbit[6]uril and symmetric viologens (2018)
Journal Article
Bai, D., Gao, Z., Tao, Z., Xiao, X., Prior, T. J., Wei, G., Liu, Q., & Redshaw, C. (2018). A study of the interaction between inverted cucurbit[6]uril and symmetric viologens. New journal of chemistry = Nouveau journal de chimie, 42(13), 11085-11092. https://doi.org/10.1039/c8nj01589a

The interaction between inverted cucuribit[6]uril (iQ[6]) and a series of symmetric viologens bearing aliphatic substituents, namely dicationic dialkyl-4,4′-bipyridinium guests where the alkyl substituent is CH3(CH2)n (n = 1, 3 and 5) or benzyl, has... Read More about A study of the interaction between inverted cucurbit[6]uril and symmetric viologens.

Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations (2018)
Journal Article
Xu, M., Jiang, J., Pei, X., Song, B., Cui, Z., & Binks, B. P. (2018). Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations. Angewandte Chemie, 57(26), 7738-7742. https://doi.org/10.1002/anie.201802266

Novel oil-in-water (O/W) emulsions are prepared which are stabilised by a cationic surfactant in combination with similarly charged alumina nanoparticles at concentrations as low as 10-5 M and 10-4 wt.%, respectively. The surfactant molecules adsorb... Read More about Novel oil-in-water emulsions stabilised by ionic surfactant and similarly charged nanoparticles at very low concentrations.

Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments (2018)
Journal Article
Gomes, H. I., Funari, V., Mayes, W. M., Rogerson, M., & Prior, T. J. (2018). Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments. Journal of environmental management, 222, 30-36. https://doi.org/10.1016/j.jenvman.2018.05.056

Steel slag is a major by-product of the steel industry and a potential resource of technology critical elements. For this study, a basic oxygen furnace (BOF) steel slag was tested for bacterial leaching and recovery of aluminium (Al), chromium (Cr),... Read More about Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments.

A review on the recent advances in the reductions of carbon–carbon/oxygen multiple bonds including aromatic rings using Raney Ni–Al Alloy or Al powder in the presence of noble metal catalysts in water (2018)
Journal Article
Rayhan, U., Kowser, Z., Islam, M. N., Redshaw, C., & Yamato, T. (2018). A review on the recent advances in the reductions of carbon–carbon/oxygen multiple bonds including aromatic rings using Raney Ni–Al Alloy or Al powder in the presence of noble metal catalysts in water. Topics in catalysis, 61(7-8), 560-574. https://doi.org/10.1007/s11244-018-0994-2

Over the past few years, heterogeneous catalysts have attracted much attention with a view to lowering reaction temperatures and improving the selectivity of many organic syntheses. When it comes to designing or optimizing a catalyst, a lot of attent... Read More about A review on the recent advances in the reductions of carbon–carbon/oxygen multiple bonds including aromatic rings using Raney Ni–Al Alloy or Al powder in the presence of noble metal catalysts in water.

CFD analysis and experimental validation of magnetic droplet generation and deflection across multilaminar flow streams (2018)
Presentation / Conference Contribution
Gómez-Pastora, J., Karampelas, I. H., Alorabi, A. Q., Tarn, M. D., Bringas, E., Iles, A., Paunov, V. N., Pamme, N., Furlani, E. P., & Ortiz, I. (2018, June). CFD analysis and experimental validation of magnetic droplet generation and deflection across multilaminar flow streams. Presented at TechConnect Briefs 2018 - Advanced Materials

© 2018 OOSV. All rights reserved. The use of droplet-based microfluidic systems has increased in the last decade due to the advantages these systems present such as compatibility with many chemical and biological reagents, capability of performing a... Read More about CFD analysis and experimental validation of magnetic droplet generation and deflection across multilaminar flow streams.

Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures (2018)
Journal Article
Binks, B. P., & Olusanya, S. O. (2018). Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures. Langmuir : the ACS journal of surfaces and colloids, 34(17), 5040-5051. https://doi.org/10.1021/acs.langmuir.8b00715

Pickering emulsions stabilized by a mixture of coloured organic pigment particles of different hydrophobicity have been investigated at equal oil:water ratio and a fixed overall particle concentration by several complementary methods. Transitional ph... Read More about Phase inversion of colored Pickering emulsions stabilized by organic pigment particle mixtures.

Two-photon-absorption properties of pyrene-based dipolar D-π-A fluorophores (2018)
Journal Article
Wang, C. Z., Zhang, R., Sakaguchi, K., Feng, X., Yu, X., Elsegood, M. R. J., Teat, S. J., Redshaw, C., & Yamato, T. (2018). Two-photon-absorption properties of pyrene-based dipolar D-π-A fluorophores. Chemphotochem, 2(8), 749-756. https://doi.org/10.1002/cptc.201800053

Two-photon absorption (TPA) properties of pyrene-based derivatives are rare as a result of the limited number of controllable synthetic methods to prepare them. However, these materials are in great demand given their potential practical application... Read More about Two-photon-absorption properties of pyrene-based dipolar D-π-A fluorophores.

Photo-induced anticancer activity and singlet oxygen production of prodigiosenes (2018)
Journal Article
Savoie, H., Figliola, C., Marchal, E., Crabbe, B. W., Hallett-Tapley, G. L., Boyle, R. W., & Thompson, A. (2018). Photo-induced anticancer activity and singlet oxygen production of prodigiosenes. Photochemical & photobiological sciences : an international journal, 17(5), 599-606. https://doi.org/10.1039/c8pp00060c

© 2018 The Royal Society of Chemistry and Owner Societies. The photo-induced cytotoxicity of prodigiosenes is reported. One prodigiosene represents a synthetic analogue of the natural product prodigiosin, and two are conjugated to molecules that targ... Read More about Photo-induced anticancer activity and singlet oxygen production of prodigiosenes.

Tuning selective reflection of light by surface anchoring in cholesteric cells with oblique helicoidal structures (2018)
Journal Article
Iadlovska, O. S., Maxwell, G. R., Babakhanova, G., Mehl, G. H., Welch, C., Shiyanovskii, S. V., & Lavrentovich, O. D. (2018). Tuning selective reflection of light by surface anchoring in cholesteric cells with oblique helicoidal structures. Optics letters, 43(8), 1850-1853. https://doi.org/10.1364/ol.43.001850

Selective reflection of light by oblique helicoidal cholesteric (ChOH) can be tuned in a very broad spectral range by an applied electric field. In this work, we demonstrate that the peak wavelength of the selective reflection can be controlled by su... Read More about Tuning selective reflection of light by surface anchoring in cholesteric cells with oblique helicoidal structures.

Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity (2018)
Journal Article
Chen, L., Vivier, E., Eling, C. J., Babra, T. S., Bouillard, J. S. G., Adawi, A. M., Benoit, D. M., Hartl, F., Colquhoun, H. M., Efremova, O. A., & Greenland, B. W. (2018). Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity. Synthetic Metals, 241, 31-38. https://doi.org/10.1016/j.synthmet.2018.03.019

© 2018 An iterative synthesis has been used to produce conjugated, monodisperse, viologen-based aromatic oligomers containing up to 12 aromatic/heterocyclic rings. The methoxy-substituted oligomers were soluble in common organic solvents and could be... Read More about Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity.

Synthesis and Characterization of Temperature-Sensitive and Chemically Cross-Linked Poly(N-isopropylacrylamide)/Photosensitizer Hydrogels for Applications in Photodynamic Therapy (2018)
Journal Article
Belali, S., Savoie, H., O’Brien, J. M., Cafolla, A. A., O’Connell, B., Karimi, A. R., Boyle, R. W., & Senge, M. O. (2018). Synthesis and Characterization of Temperature-Sensitive and Chemically Cross-Linked Poly(N-isopropylacrylamide)/Photosensitizer Hydrogels for Applications in Photodynamic Therapy. Biomacromolecules, 19(5), 1592-1601. https://doi.org/10.1021/acs.biomac.8b00293

Copyright © 2018 American Chemical Society. A novel poly(N-isopropylacrylamide) (PNIPAM) hydrogel containing different photosensitizers (protoporphyrin IX (PpIX), pheophorbide a (Pba), and protoporphyrin IX dimethyl ester (PpIX-DME)) has been synthes... Read More about Synthesis and Characterization of Temperature-Sensitive and Chemically Cross-Linked Poly(N-isopropylacrylamide)/Photosensitizer Hydrogels for Applications in Photodynamic Therapy.

Fluoride doped γ-Fe2O3 nanoparticles with increased MRI relaxivity (2018)
Journal Article
Jones, N. E., Burnett, C. A., Salamon, S., Landers, J., Wende, H., Lazzarini, L., Gibbs, P., Pickles, M., Johnson, B. R., Evans, D. J., Archibald, S. J., & Francesconi, M. G. (2018). Fluoride doped γ-Fe2O3 nanoparticles with increased MRI relaxivity. Journal of Materials Chemistry B, 6(22), 3665-3673. https://doi.org/10.1039/c8tb00360b

Iron oxide nanoparticles (IONs) are being actively researched and experimented with as contrast agents for Magnetic Resonance Imaging (MRI), as well as image-directed delivery of therapeutics. The efficiency of an MRI contrast agent can be described... Read More about Fluoride doped γ-Fe2O3 nanoparticles with increased MRI relaxivity.

Development of radiolabeled fatty acid derivatives for imaging cardiac metabolism using PET and SPECT (2018)
Thesis
Al-Ali, Z. S. A. (2018). Development of radiolabeled fatty acid derivatives for imaging cardiac metabolism using PET and SPECT. (Thesis). University of Hull. Retrieved from https://hull-repository.worktribe.com/output/4223957

Cardiac diseases are the leading cause of death worldwide. To address this problem, a better understanding of biochemical reasons underlying heart pathologies is needed. Fatty acid oxidation (FAO) plays a significant role in cardiac energy production... Read More about Development of radiolabeled fatty acid derivatives for imaging cardiac metabolism using PET and SPECT.

Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry (2018)
Journal Article
Hiebler, K., Lichtenegger, G. J., Maier, M. C., Park, E. S., Gonzales-Groom, R., Binks, B. P., & Gruber-Woelfler, H. (2018). Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry. Beilstein Journal of Organic Chemistry, 14, 648-658. https://doi.org/10.3762/bjoc.14.52

Within the “Compartmentalised Smart Factory” approach of the ONE-FLOW project the implementation of different catalysts in “compartments” provided by Pickering emulsions and their application in continuous flow is targeted. We present here the develo... Read More about Heterogeneous Pd catalysts as emulsifiers in Pickering emulsions for integrated multistep synthesis in flow chemistry.

A hexahomotrioxacalix[3]arene-based ditopic receptor for alkylammonium ions controlled by Ag + ions 4 (2018)
Journal Article
Georghiou, P., Elsegood, M., Teat, S., Elsegood, M. R., Jiang, X.-K., Ikejiri, Y., Wu, C., Rahman, S., Georghiou, P. E., Zeng, X., Elsegood, M. R. J., Warwick, T. G., Redshaw, C., Teat, S. J., & Yamato, T. (2018). A hexahomotrioxacalix[3]arene-based ditopic receptor for alkylammonium ions controlled by Ag + ions 4. Molecules, 23(2), 467. https://doi.org/10.3390/molecules23020467

A receptor cone-1 based on a hexahomotrioxacalix[3]arene bearing three pyridyl groups 21 was successfully synthesized, which has a C3-symmetric conformation and is capable of binding 22 alkylammonium and metal ions simultaneously in a cooperative fas... Read More about A hexahomotrioxacalix[3]arene-based ditopic receptor for alkylammonium ions controlled by Ag + ions 4.

How inert, perturbing, or interacting are cryogenic matrices? A combined spectroscopic (infrared, electronic, and x-ray absorption) and DFT investigation of matrix-isolated Iron, Cobalt, Nickel, and Zinc Dibromides (2018)
Journal Article
Wilkin, O. M., Harris, N., Rooms, J. F., Dixon, E. L., Bridgeman, A. J., & Young, N. A. (2018). How inert, perturbing, or interacting are cryogenic matrices? A combined spectroscopic (infrared, electronic, and x-ray absorption) and DFT investigation of matrix-isolated Iron, Cobalt, Nickel, and Zinc Dibromides. The journal of physical chemistry. A, 122(8), 1994-2029. https://doi.org/10.1021/acs.jpca.7b09734

The interactions of FeBr2, CoBr2, NiBr2 and ZnBr2 with Ne, Ar, Kr, Xe, CH4 and N2 matrices have been investigated using IR, electronic absorption and X-ray absorption spectroscopies, as well as DFT calculations. ZnBr2 is linear in all the matrices. N... Read More about How inert, perturbing, or interacting are cryogenic matrices? A combined spectroscopic (infrared, electronic, and x-ray absorption) and DFT investigation of matrix-isolated Iron, Cobalt, Nickel, and Zinc Dibromides.

Cover Picture: Ann. Phys. 2'2018 (2018)
Journal Article
Verrelli, E., Michelakaki, I., Boukos, N., Kyriakou, G., & Tsoukalas, D. (2018). Cover Picture: Ann. Phys. 2'2018. Annalen der Physik, 530(2), https://doi.org/10.1002/andp.201870013

In article number 1700256, Emanuele Verrelli and co‐workers propose that cluster beam deposition of sub‐2nm magic number Au clusters, Au20 and Au55, on flat surfaces reveals a rich evolution of the phenomena taking place at substrate level. New magic... Read More about Cover Picture: Ann. Phys. 2'2018.