Supramolecular Assemblies Controlled by Cucurbit[n]uril Size (n = 6, 7, 8 and 10)
Xu, Weitao; Deng, Xinyu; Xiao, Xin; Bian, Bing; Chen, Qing; Dalgarno, Scott; Tao, Zhu; Redshaw, Carl
Dr Xin Xiao X.Xiao@hull.ac.uk
Senior Research Fellow
Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry
A benzyl substituted 4-pyrrolidinopyridinium salt (G) with multiple active sites including benzyl, pyridinium and pyrrole groups has been synthesized. The interaction between G and a series of cucurbit[n]urils (TMeQ, Q, Q, Q), has been studied both in aqueous solution and in the solid state. The binding interaction site between G and the Q[n] can be controlled by the different size of the cavity of the Q[n]s. In the case of TMeQ, the benzyl is accommodated within the cavity, whilst for Q and Q, the pyrrole ring and the benzyl are accommodated within the cavity of the Q[7/8], and the latter can shuttle on the guest G in a state of dynamic equilibrium. For the larger cavity of Q, the entire G molecule is located within the cavity of the Q.
Xu, W., Deng, X., Xiao, X., Bian, B., Chen, Q., Dalgarno, S., …Redshaw, C. (2020). Supramolecular Assemblies Controlled by Cucurbit[n]uril Size (n = 6, 7, 8 and 10). New journal of chemistry = Nouveau journal de chimie, https://doi.org/10.1039/d0nj00087f
|Journal Article Type||Article|
|Acceptance Date||Feb 19, 2020|
|Online Publication Date||Feb 20, 2020|
|Publication Date||Feb 20, 2020|
|Deposit Date||Feb 20, 2020|
|Publicly Available Date||Nov 30, -0001|
|Journal||New Journal of Chemistry|
|Publisher||Royal Society of Chemistry|
|Peer Reviewed||Peer Reviewed|
|Keywords||Materials Chemistry; General Chemistry; Catalysis|
This file is under embargo due to copyright reasons.
Contact C.Redshaw@hull.ac.uk to request a copy for personal use.
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