Long-range magnetic ordering in Ba2CoS3: A neutron diffraction study

Headspith, D. A.; Battle, P. D.; Francesconi, M. G.

Abstract

Neutron powder diffraction has been used to determine the magnetic structure of the quasi-one-dimensional compound Ba2CoS3, which contains linear [001] chains of vertex-sharing CoS4 tetrahedra, spaced apart by Ba2+ cations. At 1.5 K the Co2+ cations in the chains are antiferromagnetically ordered with an ordered magnetic moment of 1.97(4) μB per cation aligned along [100]. Each Co2+ cation is ferromagnetically aligned with four cation in neighbouring chains and antiferromagnetically aligned with two others. © 2007 Elsevier Inc. All rights reserved.

Citation

Headspith, D. A., Battle, P. D., & Francesconi, M. G. (2007). Long-range magnetic ordering in Ba2CoS3: A neutron diffraction study. Journal of Solid State Chemistry, 180(10), 2859-2863. https://doi.org/10.1016/j.jssc.2007.07.029

• Journal Article Type: Article
• Acceptance Date: Jul 30, 2007
• Online Publication Date: Aug 22, 2007
• Publication Date: 2007-10
• Deposit Date: Dec 9, 2020
• Journal: Journal of Solid State Chemistry
• Print ISSN: 0022-4596
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 180
• Issue: 10
• Pages: 2859-2863
• DOI: https://doi.org/10.1016/j.jssc.2007.07.029
• Keywords: One-dimensional sulphides; Neutron diffraction; Magnetic structure
• Public URL: https://hull-repository.worktribe.com/output/3590380
• Publisher URL: https://www.sciencedirect.com/science/article/abs/pii/S0022459607003118?via%3Dihub