The effects of GDL anisotropic transport properties on the PEFC performance

Okereke, Isaac Chukwuemezu; Ismail, Mohammed S.; Ingham, Derek; Hughes, Kevin J.; Ma, Lin; Pourkashanian, Mohamed

Abstract

Purpose: This paper aims to numerically investigate the impact of gas diffusion layer (GDL) anisotropic transport properties on the overall and local performance of polymer electrolyte fuel cells (PEFCs). Design/methodology/approach: A three-dimensional numerical model of a polymer electrolyte fuel cell with a single straight channel has been developed to investigate the sensitivity of the fuel cell performance to the GDL anisotropic transport properties – gas permeability, diffusivity, thermal conductivity and electrical conductivity. Realistic experimentally estimated GDL transport properties were incorporated into the developed PEFC model, and a parametric study was performed to show the effect of these properties on fuel cell performance and the distribution of the key variables of current density and oxygen concentration within the cathode GDL. Findings: The results showed that the anisotropy of the GDL must be captured to avoid overestimation/underestimation of the performance of the modelled fuel cell. The results also showed that the fuel cell performance and the distributions of current density and oxygen mass fraction within the cathode GDL are highly sensitive to the through-plane electrical conductivity of the GDL and, to a lesser extent, the through-plane diffusivity, and the thermal conductivity of the GDL. The fuel cell performance is almost insensitive to the gas permeability of the GDL. Practical implications: This study improves the understanding of the importance of the GDL anisotropy in the modelling of fuel cells and provides useful insights on improving the efficiency of the fuel cells. Originality/value: Realistic experimentally estimated GDL transport properties have been incorporated into the PEFC model for the first time, allowing for more accurate prediction of the PEFC performance.

Citation

Okereke, I. C., Ismail, M. S., Ingham, D., Hughes, K. J., Ma, L., & Pourkashanian, M. (2023). The effects of GDL anisotropic transport properties on the PEFC performance. International Journal of Numerical Methods for Heat and Fluid Flow, 33(2), 648-672. https://doi.org/10.1108/HFF-05-2022-0284

• Journal Article Type: Article
• Acceptance Date: Aug 12, 2022
• Online Publication Date: Aug 12, 2022
• Publication Date: Jan 5, 2023
• Deposit Date: Jan 21, 2023
• Journal: International Journal of Numerical Methods for Heat and Fluid Flow
• Print ISSN: 0961-5539
• Publisher: Emerald
• Peer Reviewed: Peer Reviewed
• Volume: 33
• Issue: 2
• Pages: 648-672
• DOI: https://doi.org/10.1108/HFF-05-2022-0284
• Keywords: Polymer electrolyte fuel cells; Numerical model; Anisotropic transport properties; Gas diffusion layers
• Public URL: https://hull-repository.worktribe.com/output/4186501
• Related Public URLs: https://eprints.whiterose.ac.uk/190225/