Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles

Vilela, G. D.; Fernandes, T. H. M.; Kelly, S. M.; Merlo, A. A.

Abstract

© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k.

Citation

Vilela, G. D., Fernandes, T. H. M., Kelly, S. M., & Merlo, A. A. (2015). Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles. Molecular crystals and liquid crystals, 612(1), 169-182. https://doi.org/10.1080/15421406.2015.1030982

• Journal Article Type: Article
• Acceptance Date: Feb 1, 2015
• Online Publication Date: Jul 6, 2015
• Publication Date: May 3, 2015
• Deposit Date: Apr 5, 2016
• Publicly Available Date: Apr 5, 2016
• Journal: Molecular crystals and liquid crystals
• Print ISSN: 1542-1406
• Electronic ISSN: 1563-5287
• Publisher: Taylor and Francis
• Peer Reviewed: Peer Reviewed
• Volume: 612
• Issue: 1
• Pages: 169-182
• DOI: https://doi.org/10.1080/15421406.2015.1030982
• Keywords: Isoxazoles; [3+2] 1, 3-dipolar cycloaddition; Büchwald-Hartwig reaction; Fluorescence; Liquid crystals
• Public URL: https://hull-repository.worktribe.com/output/434939
• Publisher URL: http://www.tandfonline.com/doi/full/10.1080/15421406.2015.1030982
• Additional Information: This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular crystals and liquid crystals on 6th July 2015, available online: http://wwww.tandfonline.com/10.1080/15421406.2015.1030982