Qing Li
Double-cavity cucurbiturils: synthesis, structures, properties, and applications
Li, Qing; Yu, Zhengwei; Redshaw, Carl; Xiao, Xin; Tao, Zhu
Authors
Zhengwei Yu
Emeritus Professor Carl Redshaw C.Redshaw@hull.ac.uk
Emeritus Professor
Xin Xiao
Zhu Tao
Abstract
Double-cavity Q[n]s are relatively new members of the Q[n] family and have garnered significant interest due to their distinctive structures and novel properties. While they incorporate n glycoluril units, akin to their single-cavity counterparts, their geometry can best be described as resembling a figure-of-eight or a handcuff, distinguishing them from single-cavity Q[n]s. Despite retaining the core molecular recognition traits of single-cavity Q[n]s, these double-cavity variants introduce fascinating new attributes rooted in their distinct configurations. This overview delves into the synthesis, structural attributes, properties, and intriguing applications of double-cavity Q[n]s. Some of the applications explored include their role in supramolecular polymers, molecular machinery, supra-amphiphiles, sensors, artificial light-harvesting systems, and adsorptive separation materials. Upon concluding this review, we discuss potential challenges and avenues for future development and offer valuable insights for other scholars working in this area with the aim of stimulating further exploration and interest.
Citation
Li, Q., Yu, Z., Redshaw, C., Xiao, X., & Tao, Z. (2024). Double-cavity cucurbiturils: synthesis, structures, properties, and applications. Chemical Society Reviews, https://doi.org/10.1039/d3cs00961k
Journal Article Type | Review |
---|---|
Acceptance Date | Feb 21, 2024 |
Online Publication Date | Feb 28, 2024 |
Publication Date | 2024 |
Deposit Date | Mar 16, 2024 |
Publicly Available Date | Mar 1, 2025 |
Journal | Chemical Society Reviews |
Print ISSN | 0306-0012 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
DOI | https://doi.org/10.1039/d3cs00961k |
Public URL | https://hull-repository.worktribe.com/output/4591069 |
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©2024 The authors. All rights reserved. No part of this publication may be reproduced without the written permission of the copyright holder
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