23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –

Syrokvashin, Mikhail M.; Vorotnikova, Natalya A; Vorotnikov, Yuri A.; Novozhilov, Igor N.; Syrokvashin, Mikhail ?; Nadolinny, Vladimir A.; Kuratieva, Natalia V.; Benoit, David M.; Mironov, Yuri V.; Walton, Richard I.; Clarkson, Guy J.; Kitamura, Noboru; Sutherland, Andrew J.; Shestopalov, Michael A.; Efremova, Olga A.

Abstract

Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.

Citation

Syrokvashin, M. M., Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. М., Nadolinny, V. A., Kuratieva, N. V., Benoit, D. M., Mironov, Y. V., Walton, R. I., Clarkson, G. J., Kitamura, N., Sutherland, A. J., Shestopalov, M. A., & Efremova, O. A. (2018). 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –. Inorganic chemistry, 57(2), https://doi.org/10.1021/acs.inorgchem.7b02760

• Journal Article Type: Article
• Acceptance Date: Dec 11, 2017
• Online Publication Date: Dec 22, 2017
• Publication Date: Jan 16, 2018
• Deposit Date: Dec 13, 2017
• Publicly Available Date: Dec 23, 2018
• Print ISSN: 0020-1669
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 57
• Issue: 2
• DOI: https://doi.org/10.1021/acs.inorgchem.7b02760
• Keywords: Physical and Theoretical Chemistry; Inorganic Chemistry
• Public URL: https://hull-repository.worktribe.com/output/501965
• Publisher URL: http://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02760
• Contract Date: Dec 13, 2017