Mikhail M. Syrokvashin
23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –
Syrokvashin, Mikhail M.; Vorotnikova, Natalya A; Vorotnikov, Yuri A.; Novozhilov, Igor N.; Syrokvashin, Mikhail ?; Nadolinny, Vladimir A.; Kuratieva, Natalia V.; Benoit, David M.; Mironov, Yuri V.; Walton, Richard I.; Clarkson, Guy J.; Kitamura, Noboru; Sutherland, Andrew J.; Shestopalov, Michael A.; Efremova, Olga A.
Authors
Natalya A Vorotnikova
Yuri A. Vorotnikov
Igor N. Novozhilov
Mikhail ? Syrokvashin
Vladimir A. Nadolinny
Natalia V. Kuratieva
Dr David Benoit D.Benoit@hull.ac.uk
Senior Lecturer in Molecular Physics and Astrochemistry
Yuri V. Mironov
Richard I. Walton
Guy J. Clarkson
Noboru Kitamura
Andrew J. Sutherland
Michael A. Shestopalov
Olga A. Efremova
Contributors
Dr David Benoit D.Benoit@hull.ac.uk
Other
Olga Efremova
Other
Abstract
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics and sensing. This article describes chemical and electro-chemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rear example of 23ē cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures, electronic structure and the magnetic, optical and electrochemical properties of this complex are described.
Citation
Syrokvashin, M. M., Vorotnikova, N. A., Vorotnikov, Y. A., Novozhilov, I. N., Syrokvashin, M. М., Nadolinny, V. A., …Efremova, O. A. (2018). 23-electron octahedral molybdenum cluster complex [{Mo 6 I 8 }Cl 6 ] –. Inorganic chemistry, 57(2), https://doi.org/10.1021/acs.inorgchem.7b02760
Journal Article Type | Article |
---|---|
Acceptance Date | Dec 11, 2017 |
Online Publication Date | Dec 22, 2017 |
Publication Date | Jan 16, 2018 |
Deposit Date | Dec 13, 2017 |
Publicly Available Date | Oct 27, 2022 |
Print ISSN | 0020-1669 |
Electronic ISSN | 1520-510X |
Publisher | American Chemical Society |
Peer Reviewed | Peer Reviewed |
Volume | 57 |
Issue | 2 |
DOI | https://doi.org/10.1021/acs.inorgchem.7b02760 |
Keywords | Physical and Theoretical Chemistry; Inorganic Chemistry |
Public URL | https://hull-repository.worktribe.com/output/501965 |
Publisher URL | http://pubs.acs.org/doi/10.1021/acs.inorgchem.7b02760 |
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Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher.
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