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pH-dependent modulation of reactivity in Ruthenium(II) organometallics

Prior, Timothy J.; Savoie, Huguette; Boyle, Ross W.; Murray, Benjamin S.

Authors

Huguette Savoie



Abstract

The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiologically relevant pH region.

Journal Article Type Article
Publication Date Jan 31, 2018
Journal Organometallics
Print ISSN 0276-7333
Electronic ISSN 1520-6041
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 37
Issue 3
Pages 294-297
APA6 Citation Prior, T. J., Savoie, H., Boyle, R. W., & Murray, B. S. (2018). pH-dependent modulation of reactivity in Ruthenium(II) organometallics. Organometallics, 37(3), 294-297. https://doi.org/10.1021/acs.organomet.7b00868
DOI https://doi.org/10.1021/acs.organomet.7b00868
Keywords Physical and Theoretical Chemistry; Inorganic Chemistry; Organic Chemistry
Publisher URL http://pubs.acs.org/doi/10.1021/acs.organomet.7b00868
Copyright Statement © 2018 University of Hull

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