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pH-dependent modulation of reactivity in Ruthenium(II) organometallics

Prior, Timothy J.; Savoie, Huguette; Boyle, Ross W.; Murray, Benjamin S.


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Dr Tim Prior
Senior Lecturer in Inorganic Chemistry

Huguette Savoie

Benjamin S. Murray


The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiologically relevant pH region.


Prior, T. J., Savoie, H., Boyle, R. W., & Murray, B. S. (2018). pH-dependent modulation of reactivity in Ruthenium(II) organometallics. Organometallics, 37(3), 294-297.

Journal Article Type Article
Acceptance Date Jan 29, 2018
Online Publication Date Jan 31, 2018
Publication Date Jan 31, 2018
Deposit Date Feb 1, 2018
Publicly Available Date Feb 1, 2019
Journal Organometallics
Print ISSN 0276-7333
Electronic ISSN 1520-6041
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 37
Issue 3
Pages 294-297
Keywords Physical and Theoretical Chemistry; Inorganic Chemistry; Organic Chemistry
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