pH-dependent modulation of reactivity in Ruthenium(II) organometallics

Prior, Timothy J.; Savoie, Huguette; Boyle, Ross W.; Murray, Benjamin S.

Abstract

The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiologically relevant pH region.

Citation

Prior, T. J., Savoie, H., Boyle, R. W., & Murray, B. S. (2018). pH-dependent modulation of reactivity in Ruthenium(II) organometallics. Organometallics, 37(3), 294-297. https://doi.org/10.1021/acs.organomet.7b00868

• Journal Article Type: Article
• Acceptance Date: Jan 29, 2018
• Online Publication Date: Jan 31, 2018
• Publication Date: Jan 31, 2018
• Deposit Date: Feb 1, 2018
• Publicly Available Date: Feb 1, 2018
• Journal: Organometallics
• Print ISSN: 0276-7333
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 37
• Issue: 3
• Pages: 294-297
• DOI: https://doi.org/10.1021/acs.organomet.7b00868
• Keywords: Physical and Theoretical Chemistry; Inorganic Chemistry; Organic Chemistry
• Public URL: https://hull-repository.worktribe.com/output/566565
• Publisher URL: http://pubs.acs.org/doi/10.1021/acs.organomet.7b00868
• Contract Date: Feb 1, 2018