Crystal structure of 4-carbamoylpyridinium chloride

Fellows, Simon M.; Prior, Timothy J.

Abstract

The hydro­chloride salt of isonicotinamide, C6H7N2O+·Cl-, has been synthesized from a dilute solution of hydro­chloric acid in aceto­nitrile. The compound displays monoclinic symmetry (space group C2/c) at 150 K, similar to the related hydro­chloride salt of nicotinamide. The asymmetric unit contains one protonated isonicotinamide mol­ecule and a chloride anion. An array of hydrogen-bonding inter­actions, including a peculiar bifurcated pyridinium-chloride inter­action, results in linear chains running almost perpendicularly in the [150] and [1-50] directions within the structure. A description of the hydrogen-bonding network and comparison with similar compounds are presented.

Citation

Fellows, S. M., & Prior, T. J. (2016). Crystal structure of 4-carbamoylpyridinium chloride. Acta Crystallographica Section E: Crystallographic Communications, 72(4), 436-439. https://doi.org/10.1107/S2056989016003340

• Journal Article Type: Article
• Acceptance Date: Feb 26, 2016
• Online Publication Date: Mar 4, 2016
• Publication Date: 2016-04
• Deposit Date: Jul 8, 2021
• Publicly Available Date: Jul 9, 2021
• Journal: Acta Crystallographica Section E: Crystallographic Communications
• Print ISSN: 2056-9890
• Electronic ISSN: 2056-9890
• Publisher: International Union of Crystallography
• Peer Reviewed: Peer Reviewed
• Volume: 72
• Issue: 4
• Pages: 436-439
• DOI: https://doi.org/10.1107/S2056989016003340
• Keywords: Crystal structure; Isonicotinamide; Hydro­chloride; Hydrogen bonding
• Public URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84964034496&doi=10.1107%2fS2056989016003340&partnerID=40&md5=74f292187b1e56d7151eda0416ed801c