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Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex

Xia, Yu; Wang, Chuan-Zeng; Tian, Mengkui; Tao, Zhu; Ni, Xin-Long; Prior, Timothy J.; Redshaw, Carl

Authors

Yu Xia

Chuan-Zeng Wang

Mengkui Tian

Zhu Tao

Xin-Long Ni

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Professor Carl Redshaw C.Redshaw@hull.ac.uk
Professor of Inorganic Materials Chemistry and REF Lead for Chemistry



Abstract

2018 by the authors. The host-guest interaction of a series of cyclohexyl-appended guests with cucurbit[8]uril (Q[8] ) was studied by 1 H NMR spectroscopy, isothermal titration calorimetry (ITC), and X-ray crystallography. The X-ray structure revealed that two cycloalkane moieties can be simultaneously encapsulated in the hydrophobic cavity of the Q[8] host to form a ternary complex for the first time.

Citation

Xia, Y., Wang, C., Tian, M., Tao, Z., Ni, X., Prior, T. J., & Redshaw, C. (2018). Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex. Molecules, 23(1), 175. https://doi.org/10.3390/molecules23010175

Journal Article Type Article
Acceptance Date Jan 10, 2018
Online Publication Date Jan 15, 2018
Publication Date Jan 15, 2018
Deposit Date Aug 21, 2018
Publicly Available Date Aug 22, 2018
Journal Molecules
Electronic ISSN 1420-3049
Publisher MDPI
Peer Reviewed Peer Reviewed
Volume 23
Issue 1
Pages 175
DOI https://doi.org/10.3390/molecules23010175
Keywords Cucurbit[8]uril; Cycloalkane groups; Host-guest interaction; Ternary complex; X-ray structure
Public URL https://hull-repository.worktribe.com/output/614489
Publisher URL http://www.mdpi.com/1420-3049/23/1/175/htm

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https://creativecommons.org/licenses/by/4.0/

Copyright Statement
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).





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