All Outputs (12)

In Situ Photogenerated Radicals of Hydroxyl Substituted Pyrene-Based Triphenylamines with Enhanced Transport and Free Doping/Post-Oxidation for Efficient Perovskite Solar Cells (2024)
Journal Article
Wang, X., Xie, Z., Wang, R., Xiao, Y., Yan, K., Zhao, Y., …Feng, X. (in press). In Situ Photogenerated Radicals of Hydroxyl Substituted Pyrene-Based Triphenylamines with Enhanced Transport and Free Doping/Post-Oxidation for Efficient Perovskite Solar Cells. Small, https://doi.org/10.1002/smll.202311914

The high-performance hole transporting material (HTM) is one of the most important components for the perovskite solar cells (PSCs) in promoting power conversion efficiency (PCE). However, the low conductivity of HTMs and their additional requirement... Read More about In Situ Photogenerated Radicals of Hydroxyl Substituted Pyrene-Based Triphenylamines with Enhanced Transport and Free Doping/Post-Oxidation for Efficient Perovskite Solar Cells.

Molecular Engineering toward Broad Color-Tunable Emission of Pyrene-Based Aggregation-Induced Emission Luminogens (2024)
Journal Article
Liu, W., Li, S., Xie, Z., Huang, K., Yan, K., Zhao, Y., …Tang, B. Z. (in press). Molecular Engineering toward Broad Color-Tunable Emission of Pyrene-Based Aggregation-Induced Emission Luminogens. Advanced Optical Materials, https://doi.org/10.1002/adom.202400301

A molecular design strategy for the precise regulation of full-color-tunable emission organic luminescence materials is not yet systematically established for pyrene chemistry. To fabricate color-tunable and highly-efficiency pyrene-based emitters, t... Read More about Molecular Engineering toward Broad Color-Tunable Emission of Pyrene-Based Aggregation-Induced Emission Luminogens.

Phenanthrothiophene-Triazine Star-Shaped Discotic Liquid Crystals: Synthesis, Self-Assembly, and Stimuli-Responsive Fluorescence Properties (2024)
Journal Article
Zeng, C. Y., Deng, W. J., Zhao, K. Q., Redshaw, C., & Donnio, B. (in press). Phenanthrothiophene-Triazine Star-Shaped Discotic Liquid Crystals: Synthesis, Self-Assembly, and Stimuli-Responsive Fluorescence Properties. Chemistry: a European journal, Article e202400296. https://doi.org/10.1002/chem.202400296

Lipophilic biphenylthiophene- and phenanthrothiophene-triazine compounds, BPTTn and CPTTn, respectively, were prepared by a tandem procedure involving successive Suzuki-Miyaura coupling and Scholl cyclodehydrogenation reactions. These compounds displ... Read More about Phenanthrothiophene-Triazine Star-Shaped Discotic Liquid Crystals: Synthesis, Self-Assembly, and Stimuli-Responsive Fluorescence Properties.

Position-dependent hexaarylbenzene AIEgens: synthesis, characterization and optical properties (2024)
Journal Article
Zhao, W. X., Yang, L. F., Yu, D., Chen, F. Y., Liang, L., Cao, J. Y., …Wang, C. Z. (in press). Position-dependent hexaarylbenzene AIEgens: synthesis, characterization and optical properties. New journal of chemistry = Nouveau journal de chimie, https://doi.org/10.1039/d3nj05914f

With the development and exploration of photoelectric materials, the design of tunable and high luminescence efficiency materials remains a challenge. As a promising candidate, aggregation-induced emission (AIE) luminogens have shown significant adva... Read More about Position-dependent hexaarylbenzene AIEgens: synthesis, characterization and optical properties.

Regulable high-contrast mechanofluorochromic enhancement behaviour based on substituent effects (2024)
Journal Article
Yang, G., Zhao, W. X., Cao, J. Y., Xue, Z. M., Lin, H. T., Chen, S. H., …Wang, C. Z. (in press). Regulable high-contrast mechanofluorochromic enhancement behaviour based on substituent effects. Chemical communications : Chem comm / the Royal Society of Chemistry, https://doi.org/10.1039/d4cc00476k

Herein, a facile strategy was established to build mechanoresponsive luminogens with high sensitivity to substituents and positional effects. Even in slightly different structures, distinct optical phenomena, including fluorescence efficiency and mec... Read More about Regulable high-contrast mechanofluorochromic enhancement behaviour based on substituent effects.

Extended Hydrogen-Bonded Molybdenum Arrays Derived from Carboxylic Acids and Dianilines: ROP Capability of the Complexes and Parent Acids and Dianilines (2024)
Journal Article
Clegg, W., Elsegood, M. R., & Redshaw, C. (2024). Extended Hydrogen-Bonded Molybdenum Arrays Derived from Carboxylic Acids and Dianilines: ROP Capability of the Complexes and Parent Acids and Dianilines. Catalysts, 14(3), Article 214. https://doi.org/10.3390/catal14030214

From reactions involving sodium molybdate and dianilines [2,2′-(NH2)C6H4]2(CH2)n (n = 0, 1, 2) and amino-functionalized carboxylic acids 1,2-(NH2)(CO2H)C6H4 or 2-H2NC6H3-1,4-(CO2H)2, in the presence of Et3N and Me3SiCl, products adopting H-bonded net... Read More about Extended Hydrogen-Bonded Molybdenum Arrays Derived from Carboxylic Acids and Dianilines: ROP Capability of the Complexes and Parent Acids and Dianilines.

Double-cavity cucurbiturils: synthesis, structures, properties, and applications (2024)
Journal Article
Li, Q., Yu, Z., Redshaw, C., Xiao, X., & Tao, Z. (2024). Double-cavity cucurbiturils: synthesis, structures, properties, and applications. Chemical Society Reviews, https://doi.org/10.1039/d3cs00961k

Double-cavity Q[n]s are relatively new members of the Q[n] family and have garnered significant interest due to their distinctive structures and novel properties. While they incorporate n glycoluril units, akin to their single-cavity counterparts, th... Read More about Double-cavity cucurbiturils: synthesis, structures, properties, and applications.

Reaction of Ph2C(X)(CO2H) (X = OH, NH2) with [VO(OR)3] (R = Et, nPr): Structure, magnetic susceptibility and ROP capability (2024)
Journal Article
Glenister, M. A., Frese, J. W., Elsegood, M. R., Canaj, A. B., Brechin, E. K., & Redshaw, C. (2024). Reaction of Ph2C(X)(CO2H) (X = OH, NH2) with [VO(OR)3] (R = Et, nPr): Structure, magnetic susceptibility and ROP capability. Dalton Transactions : an international journal of inorganic chemistry, 53(12), 5351-5355. https://doi.org/10.1039/d4dt00078a

Reaction of [VO(OR)3] (R = Et, nPr) with 2,2′-diphenylglycine afforded the alkoxide-bridged dimers {[VO(OR)(μ-OR)][Ph2C(NH2)(CO2)]}2, whereas use of benzilic acid, in the presence of alkali metals, afforded 16-membered metallocycles {V8(O)4M(OR)8[Ph2... Read More about Reaction of Ph2C(X)(CO2H) (X = OH, NH2) with [VO(OR)3] (R = Et, nPr): Structure, magnetic susceptibility and ROP capability.

Pyrene-Based Deep-Blue Fluorophores with Narrow-Band Emission (2024)
Journal Article
Liu, Y., Zhang, J., Wang, X., Xie, Z., Zheng, H., Zhang, S., …Feng, X. (2024). Pyrene-Based Deep-Blue Fluorophores with Narrow-Band Emission. Journal of Organic Chemistry, 89(5), 3319–3330. https://doi.org/10.1021/acs.joc.3c02775

High-efficiency narrow-band luminescent materials have attracted intense interest, resulting in their great colorimetric purity. This has led to a variety of high-tech applications in high-definition displays, spectral analysis, and biomedicine. In t... Read More about Pyrene-Based Deep-Blue Fluorophores with Narrow-Band Emission.

A Coumarin–Hemicyanine Deep Red Dye with a Large Stokes Shift for the Fluorescence Detection and Naked-Eye Recognition of Cyanide (2024)
Journal Article
Li, D., Peng, S., Zhou, X., Shen, L., Yang, X., Xu, H., …Zhang, Q. (2024). A Coumarin–Hemicyanine Deep Red Dye with a Large Stokes Shift for the Fluorescence Detection and Naked-Eye Recognition of Cyanide. Molecules, 29(3), Article 618. https://doi.org/10.3390/molecules29030618

In this study, we synthesized a coumarin–hemicyanine-based deep red fluorescent dye that exhibits an intramolecular charge transfer (ICT). The probe had a large Stokes shift of 287 nm and a large molar absorption coefficient (ε = 7.5 × 105 L·mol−1·cm... Read More about A Coumarin–Hemicyanine Deep Red Dye with a Large Stokes Shift for the Fluorescence Detection and Naked-Eye Recognition of Cyanide.

Influence of Steric Effects on the Emission Behavior of Pyrene-Based Blue Luminogens (2024)
Journal Article
Xie, Z., Liu, W., Liu, Y., Song, X., Zheng, H., Su, X., …Feng, X. (2024). Influence of Steric Effects on the Emission Behavior of Pyrene-Based Blue Luminogens. Journal of Organic Chemistry, 89(3), 1681-1691. https://doi.org/10.1021/acs.joc.3c02372

Pyrene-based derivatives have been widely deployed in organic luminescent materials because of their bright fluorescence, high charge carrier mobility, and facile modification. Nevertheless, the fluorescence output of conventional pyrenes is prone to... Read More about Influence of Steric Effects on the Emission Behavior of Pyrene-Based Blue Luminogens.

Detection of basic amino acids under highly alkaline conditions using a perylene amine-derived probe (2024)
Journal Article
Zhang, T. T., Lu, Y., Lu, J. H., Zhao, A. T., Redshaw, C., & Xiao, X. (2024). Detection of basic amino acids under highly alkaline conditions using a perylene amine-derived probe. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 309, Article 123835. https://doi.org/10.1016/j.saa.2024.123835

pH plays a crucial part in numerous chemical and physiological processes. In this work, a new perylene diimide derivative that acts as a pH-sensitive dye with Bay Area Carboxylic Acid functionality. The derivative utilizes the outstanding thermal, ch... Read More about Detection of basic amino acids under highly alkaline conditions using a perylene amine-derived probe.