All Outputs (152)

A study of the interaction between cucurbit[8]uril and alkyl substituted 4-pyrrolidinopyridinium salts (2018)
Journal Article
Xu, W., Kan, J., Yang, B., Prior, T. J., Bian, B., Xiao, X., Tao, Z., & Redshaw, C. (2019). A study of the interaction between cucurbit[8]uril and alkyl substituted 4-pyrrolidinopyridinium salts. Chemistry - An Asian Journal, 14(1), 235-242. https://doi.org/10.1002/asia.201801498

The interaction between cucuribit[8]uril (Q[8]) and a series of 4-pyrrolidinopyridinium salts bearing aliphatic substituents at the pyridinium nitrogen, namely 4-(C4H8N)C5H5NRBr, where R = Et (g1), n-butyl (g2), n-pentyl (g3), n-hexyl (g4), n-octyl (... Read More about A study of the interaction between cucurbit[8]uril and alkyl substituted 4-pyrrolidinopyridinium salts.

Vanadyl sulfates: molecular structure, magnetism and electrochemical activity (2018)
Journal Article
Ignaszak, A., Patterson, N., Radtke, M., Elsegood, M. R., Frese, J. W., Lipman, J. L., Yamato, T., Sanz, S., Brechin, E. K., Prior, T. J., & Redshaw, C. (2018). Vanadyl sulfates: molecular structure, magnetism and electrochemical activity. Dalton Transactions : an international journal of inorganic chemistry, 47(44), 15983-15993. https://doi.org/10.1039/c8dt03626h

Reaction of differing amounts of vanadyl sulfate with p-tert-butylthiacalix[4]areneH4 and base allows access to the vanadyl-sulfate species [NEt4]4[(VO)4(3-OH)4(SO4)4]∙1/2H2O (1), [HNEt3]5[(VO)5(3-O)4(SO4)4]∙4MeCN (2∙4MeCN) and [NEt4]2[(VO)6(O)2(SO... Read More about Vanadyl sulfates: molecular structure, magnetism and electrochemical activity.

Interstitial nitrides revisited - a simple synthesis of MxMo3N (M = Fe, Co, Ni) (2018)
Journal Article
Conway, J. O., & Prior, T. J. (2019). Interstitial nitrides revisited - a simple synthesis of MxMo3N (M = Fe, Co, Ni). Journal of Alloys and Compounds, 774, 69-74. https://doi.org/10.1016/j.jallcom.2018.09.307

The efficient synthesis of polycrystalline filled beta-Mn structured Ni2Mo3N, and the eta-carbides Fe3Mo3N and Co3Mo3N, by a single heating of metal powders at 975 ºC under a hydrogen-nitrogen mixture is reported. Rietveld analysis of high-resolution... Read More about Interstitial nitrides revisited - a simple synthesis of MxMo3N (M = Fe, Co, Ni).

Increase of Direct C-C Coupling Reaction Yield by Identifying Structural and Electronic Properties of High-Spin Iron Tetra-azamacrocyclic Complexes (2018)
Journal Article
Brewer, S. M., Wilson, K. R., Jones, D. G., Reinheimer, E. W., Archibald, S. J., Prior, T. J., Ayala, M. A., Foster, A. L., Hubin, T. J., & Green, K. N. (2018). Increase of Direct C-C Coupling Reaction Yield by Identifying Structural and Electronic Properties of High-Spin Iron Tetra-azamacrocyclic Complexes. Inorganic chemistry, 57(15), 8890-8902. https://doi.org/10.1021/acs.inorgchem.8b00777

Macrocyclic ligands have been explored extensively as scaffolds for transition metal catalysts for oxygen and hydrogen atom transfer reactions. C–C reactions facilitated using earth abundant metals bound to macrocyclic ligands have not been well-unde... Read More about Increase of Direct C-C Coupling Reaction Yield by Identifying Structural and Electronic Properties of High-Spin Iron Tetra-azamacrocyclic Complexes.

A microbial role in the construction of Mono Lake carbonate chimneys? (2018)
Journal Article
Brasier, A., Wacey, D., Rogerson, M., Guagliardo, P., Saunders, M., Kellner, S., Mercedes-Martin, R., Prior, T., Taylor, C., Matthews, A., & Reijmer, J. (2018). A microbial role in the construction of Mono Lake carbonate chimneys?. Geobiology, 16(5), 540-555. https://doi.org/10.1111/gbi.12292

Lacustrine carbonate chimneys are striking, metre‐scale constructions. If these were bioinfluenced constructions, they could be priority targets in the search for early and extraterrestrial microbial life. However, there are questions over whether su... Read More about A microbial role in the construction of Mono Lake carbonate chimneys?.

A study of the interaction between inverted cucurbit[6]uril and symmetric viologens (2018)
Journal Article
Bai, D., Gao, Z., Tao, Z., Xiao, X., Prior, T. J., Wei, G., Liu, Q., & Redshaw, C. (2018). A study of the interaction between inverted cucurbit[6]uril and symmetric viologens. New journal of chemistry = Nouveau journal de chimie, 42(13), 11085-11092. https://doi.org/10.1039/c8nj01589a

The interaction between inverted cucuribit[6]uril (iQ[6]) and a series of symmetric viologens bearing aliphatic substituents, namely dicationic dialkyl-4,4′-bipyridinium guests where the alkyl substituent is CH3(CH2)n (n = 1, 3 and 5) or benzyl, has... Read More about A study of the interaction between inverted cucurbit[6]uril and symmetric viologens.

Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments (2018)
Journal Article
Gomes, H. I., Funari, V., Mayes, W. M., Rogerson, M., & Prior, T. J. (2018). Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments. Journal of environmental management, 222, 30-36. https://doi.org/10.1016/j.jenvman.2018.05.056

Steel slag is a major by-product of the steel industry and a potential resource of technology critical elements. For this study, a basic oxygen furnace (BOF) steel slag was tested for bacterial leaching and recovery of aluminium (Al), chromium (Cr),... Read More about Recovery of Al, Cr and V from steel slag by bioleaching: batch and column experiments.

pH-dependent modulation of reactivity in Ruthenium(II) organometallics (2018)
Journal Article
Prior, T. J., Savoie, H., Boyle, R. W., & Murray, B. S. (2018). pH-dependent modulation of reactivity in Ruthenium(II) organometallics. Organometallics, 37(3), 294-297. https://doi.org/10.1021/acs.organomet.7b00868

The pH-dependent intramolecular chelation of a tethered sulfonamide ligand in ruthenium(II) arene complexes is demonstrated, a process shown to modulate metal-centered reactivity toward the model ligand guanosine 5′-monophosphate within the physiolog... Read More about pH-dependent modulation of reactivity in Ruthenium(II) organometallics.

Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex (2018)
Journal Article
Xia, Y., Wang, C.-Z., Tian, M., Tao, Z., Ni, X.-L., Prior, T. J., & Redshaw, C. (2018). Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex. Molecules, 23(1), 175. https://doi.org/10.3390/molecules23010175

2018 by the authors. The host-guest interaction of a series of cyclohexyl-appended guests with cucurbit[8]uril (Q[8] ) was studied by 1 H NMR spectroscopy, isothermal titration calorimetry (ITC), and X-ray crystallography. The X-ray structure reveale... Read More about Host-guest interaction of cucurbit[8]uril with n-(3-aminopropyl)cyclohexylamine: Cyclohexyl encapsulation triggered ternary complex.

Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH (2017)
Journal Article
Kubicek, V., Bohmova, Z., Price, T. W., Gallo, J., Kubíček, V., Böhmová, Z., Prior, T. J., Greenman, J., Hermann, P., & Stasiuk, G. J. (2017). Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH. Dalton Transactions : an international journal of inorganic chemistry, 46(48), 16973-16982. https://doi.org/10.1039/c7dt03398b

Gallium-68 ( 68 Ga) has been the subject of increasing interest for its potential in the production of radiotracers for diagnosis of diseases. In this work we report the complexation of 68 Ga by the amino acid based tripodal chelate H 3 Dpaa, and two... Read More about Amino acid based gallium-68 chelators capable of radiolabeling at neutral pH.

Novel copper coordination compounds of amino acids and pyridines : synthesis, characterisation, physical properties, and future prospects for gas adsorption (2017)
Thesis
Fellows, S. M. (2017). Novel copper coordination compounds of amino acids and pyridines : synthesis, characterisation, physical properties, and future prospects for gas adsorption. (Thesis). University of Hull. Retrieved from https://hull-repository.worktribe.com/output/4221246

The primary goal of the work discussed in this thesis was to assess the capability of cheap, readily available ligands, e.g. pyridines and amines, to produce new coordination compounds, primarily with copper, that could lead to the development of nov... Read More about Novel copper coordination compounds of amino acids and pyridines : synthesis, characterisation, physical properties, and future prospects for gas adsorption.

Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O (2017)
Journal Article
Chen, L. X., Kan, J. L., Cong, H., Prior, T. J., Tao, Z., Xiao, X., & Redshaw, C. (2017). Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O. Molecules, 22(7), 1147. https://doi.org/10.3390/molecules22071147

Heating a mixture of Nd(NO₃)₃·6H₂O, KCl, Q[10] and Q[5] in HCl for 10 min affords the inclusion complex {NdQ[5]K@Q[10](H₂O)₄}·4NO₃·20H₂O. The structure of the inclusion complex has been investigated by single crystal X-ray diffraction and by X-ray Ph... Read More about Synthesis and structure of the inclusion complex {NdQ[5]K@Q[10](H₂O)4}·4NO₃·20H₂O.

Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes (2017)
Journal Article
McConkey, G. A., Bedingfield, P. T., Burrell, D. R., Chambers, N. C., Cunningham, F., Prior, T. J., Fishwick, C. W., & Boa, A. N. (2017). Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes. Bioorganic and Medicinal Chemistry Letters, 27(16), 3878-3882. https://doi.org/10.1016/j.bmcl.2017.06.052

Two new tricyclic β-aminoacrylate derivatives (2e and 3e) have been found to be inhibitors of Plasmodium falciparum dihydroorotate dehydrogenase (PfDHODH) with Ki 0.037 and 0.15 μM respectively. 1H and 13C NMR spectroscopic data show that these compo... Read More about Interconvertible geometric isomers of Plasmodium falciparum dihydroorotate dehydrogenase inhibitors exhibit multiple binding modes.

Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide (2017)
Journal Article
Meva, F. E., Prior, T. J., Evans, D. J., & Mang, E. R. (2017). Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide. Acta Crystallographica Section E: Crystallographic Communications, 73(7), 1021-1025. https://doi.org/10.1107/s2056989017008416

© Eya'ane Meva et al. 2017. The crystal structures of N,-Aminopyridine-2-carboximidamide (C 6 H 8 N 4 ), 1, and N,-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide (C 13 H 13 N 5 ), 2, are described. The non-H atoms in compound 1 are nea... Read More about Crystal structures of N ′-Aminopyridine-2-carboximidamide and N ′-{[1-(pyridin-2-yl)ethylidene]amino}pyridine-2-carboximidamide.

Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks (2017)
Journal Article
Panyarat, K., Surinwong, S., Prior, T. J., Konno, T., & Rujiwatra, A. (2017). Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks. Microporous and Mesoporous Materials, 251, 155-164. https://doi.org/10.1016/j.micromeso.2017.06.003

Six new lanthanide metal organic complexes, i.e. [La2(NO2-BDC)3(H2O)4] (1) [Ln(L)0.5(NO2-BDC) (H2O)]·3H2O (Ln = Eu (2), Tb (3), Dy (4) and Ho (5); L = BDC2− or BDC2−/NO2-BDC2-) and [Tm(NO2-BDC)1.5(H2O)]·H2O (6), have been synthesized using mixed liga... Read More about Crystal structures and gas adsorption behavior of new lanthanide-benzene-1,4-dicarboxylate frameworks.

Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland (2017)
Journal Article
Rogerson, M., Mercedes Martín, R., Brasier, A. T., McGill, R. A. R., Prior, T. J., Vonhof, H., Fellows, S. M., Reijmer, J. J. G., McClymont, E., Billing, I., Matthews, A., & Pedley, H. M. (2017). Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland. Gondwana Research, 48, 101-109. https://doi.org/10.1016/j.gr.2017.04.007

Lacustrine carbonate deposits with spherulitic facies are poorly understood, but are key to understanding the economically important “Pre-Salt” Mesozoic strata of the South Atlantic. A major barrier to research into these unique and spectacular facie... Read More about Are spherulitic lacustrine carbonates an expression of large-scale mineral carbonation? A case study from the East Kirkton Limestone, Scotland.

Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites (2017)
Journal Article
Kelly, S., Kornherr, A., Alahmadi, N. S., Betts, J. W., Francesconi, M. G., Prior, T. J., Wadhawan, J. D., Cheng, F., Francesconi, M. G., Kelly, S. M., Prior, T., Wadhawan, J., & Kornherr, A. (2017). Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites. RSC advances, 7(32), 20020-20026. https://doi.org/10.1039/c7ra00920h

© The Royal Society of Chemistry. Green synthesis is employed to prepare cobalt/cellulose nanocomposites with cubic (α-cobalt) cobalt as a main component with antibacterial and magnetic properties. An in situ reduction of aqueous solutions of cobalt... Read More about Synthesis and antibacterial effects of cobalt–cellulose magnetic nanocomposites.

Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide (2017)
Journal Article
Mo, S., Prior, T. J., Al-Khafaj, Y., Zhao, K.-Q., Wang, X., Elsegood, M. R., Elsegood, M. R. J., Wang, X., Zhao, K.-Q., Al-Khafaji, Y., Mo, S., Prior, T., Elsegood, M., & Redshaw, C. (2017). Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide. European Journal of Inorganic Chemistry, 2017(13), 1951-1965. https://doi.org/10.1002/ejic.201601415

Reaction of R¹R²CHN=CH(3,5-tBu₂C₆H₂-OH-2) (R¹ = R² = Me L¹H; R¹ = Me, R² = Ph L²H; R¹ = R2 = Ph L³H) with one equivalent of R³3Al (R³ = Me, Et) afforded [(L¹-³)AlR³₂] (L¹, R³ = Me 1, R³ = Et 2; L², R³ = Me 3, R³ = Et 4; L³ R³ = Me 5, R³ = Et 6); comp... Read More about Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide.

Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine (2017)
Journal Article
Hou, H.-B., Gao, Z.-Z., Bai, D., Tao, Z., Prior, T. J., Redshaw, C., & Xiao, X. (2017). Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine. Supramolecular chemistry, 29(9), 680-685. https://doi.org/10.1080/10610278.2017.1304549

The nature of the supramolecular host-guest complex involving 4-pyrrolidinopyridine (BuPC4) and cucurbit[6]uril (Q[6]) has been investigated by NMR and UV spectroscopy, MALDI-TOF mass spectrometry, X-ray crystallography and isothermal titration calor... Read More about Supramolecular assembly of cucurbit[6]uril and N-butyl-4-pyrrolidinopyridine.

On the high-pressure phase stability and elastic properties of β-titanium alloys (2017)
Journal Article
Smith, D., Joris, O. P. J., Sankaran, A., Weekes, H. E., Bull, D. J., Dye, D., Errandonea, D., Smith, D., Joris, O. P. J., Sankaran, A., Weekes, H. E., Bull, D. J., Prior, T. J., Dye, D., Errandonea, D., & Proctor, J. E. (2017). On the high-pressure phase stability and elastic properties of β-titanium alloys. Journal of Physics: Condensed Matter, 29(15), 155401. https://doi.org/10.1088/1361-648x/aa60b6

We have studied the compressibility and stability of different β-titanium alloys at high pressure, including binary Ti-Mo, Ti-24Nb-4Zr-8Sn (Ti2448) and Ti-36Nb-2Ta-0.3O (gum metal). We observed stability of the β phase in these alloys to 40 GPa, well... Read More about On the high-pressure phase stability and elastic properties of β-titanium alloys.