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Synthesis and characterisation of the quaternary nitride-fluoride Ce2MnN3F2-δ (2009)
Journal Article
Headspith, D. A., Sullivan, E., Greaves, C., & Francesconi, M. G. (2009). Synthesis and characterisation of the quaternary nitride-fluoride Ce2MnN3F2-δ. Dalton Transactions : an international journal of inorganic chemistry, 9273-9279. https://doi.org/10.1039/b908591b

Ce 2 MnN 3 F 2-δ has been synthesised via low-temperature fluorination of the ternary nitride Ce 2 MnN 3 . To the best of our knowledge, Ce 2 MnN 3 F 2-δ is the first quaternary nitride-fluoride to be reported. The reaction of Ce 2 MnN 3 with 10% F 2... Read More about Synthesis and characterisation of the quaternary nitride-fluoride Ce2MnN3F2-δ.

Mobile magnetic particles as solid-supports for rapid surface-based bioanalysis in continuous flow (2009)
Journal Article
Peyman, S. A., Iles, A., & Pamme, N. (2009). Mobile magnetic particles as solid-supports for rapid surface-based bioanalysis in continuous flow. Lab on a chip, 9(21), 3110-3117. https://doi.org/10.1039/b904724g

An extremely versatile microfluidic device is demonstrated in which multi-step (bio) chemical procedures can be performed in continuous flow. The system operates by generating several co-laminar flow streams, which contain reagents for specific (bio)... Read More about Mobile magnetic particles as solid-supports for rapid surface-based bioanalysis in continuous flow.

Two related lithium calixarene complexes, [p-tert-butyl-calix[4]arene(OMe) (OH)2(OLi)]2·4MeCN and {p-tert-butyl-calix[4] arene(OH)2(OLi)[OLi(NCMe)2]}2·8MeCN, determined using synchrotron radiation (2009)
Journal Article
Lee, D. S., Elsegood, M. R., Redshaw, C., & Zhan, S. (2009). Two related lithium calixarene complexes, [p-tert-butyl-calix[4]arene(OMe) (OH)2(OLi)]2·4MeCN and {p-tert-butyl-calix[4] arene(OH)2(OLi)[OLi(NCMe)2]}2·8MeCN, determined using synchrotron radiation. Acta Crystallographica Section C: Crystal Structure Communications, 65(8), m291-m295. https://doi.org/10.1107/S0108270109025311

The crystal structures of acetonitrile solvates of two related lithium calixarene complexes have been determined by low-temperature single-crystal X-ray diffraction using synchrotron radiation. Bis(μ-5,11,17,23-tetra-tert- butyl-26,28-dihydr-oxy-25-m... Read More about Two related lithium calixarene complexes, [p-tert-butyl-calix[4]arene(OMe) (OH)2(OLi)]2·4MeCN and {p-tert-butyl-calix[4] arene(OH)2(OLi)[OLi(NCMe)2]}2·8MeCN, determined using synchrotron radiation.

Novel multifunctional micro-ampoules for structuring and encapsulation (2009)
Journal Article
Campbell, A. L., Stoyanov, S. D., & Paunov, V. N. (2009). Novel multifunctional micro-ampoules for structuring and encapsulation. Chemphyschem, 10(15), 2599-2602. https://doi.org/10.1002/cphc.200900317

Micro-ampoules: A novel method for the scalable fabrication of micro-rodcapsules made from edible materials is described. The capsules closely resemble ampoules by having multiple compartments loaded with oils (see picture). Such novel micro-ampoules... Read More about Novel multifunctional micro-ampoules for structuring and encapsulation.

Melaminium 2,4,6-trihydroxybenzoate dihydrate (2009)
Journal Article
Prior, T. J., Goch, O., & Kift, R. L. (2009). Melaminium 2,4,6-trihydroxybenzoate dihydrate. Acta Crystallographica Section E: Crystallographic Communications, 65(9), O2133-U1847. https://doi.org/10.1107/S1600536809031055

In the title compound, C 3 H 7 N 6 + ·C 7 H 5 O 5 - ·2H 2 O, the melaminium and benzoate ions are approximately planar (r.m.s. deviation of the non-hydrogen atoms is 0.093 Å) and there is a strong C 2 2 (8) hydrogen-bonding embrace between them. The... Read More about Melaminium 2,4,6-trihydroxybenzoate dihydrate.

Influence of surfactant structure on the double inversion of emulsions in the presence of nanoparticles (2009)
Journal Article
Rodrigues, J. A., & Binks, B. P. (2009). Influence of surfactant structure on the double inversion of emulsions in the presence of nanoparticles. Colloids and surfaces. A, Physicochemical and engineering aspects, 345(1-3), 195-201. https://doi.org/10.1016/j.colsurfa.2009.05.001

The double inversion of emulsions from oil-in-water (o/w) to water-in-oil (w/o) and back to o/w is a novel approach developed using oppositely charged mixtures of solid particles and surfactant molecules [B.P. Binks, J.A. Rodrigues, Angew. Chem. Int.... Read More about Influence of surfactant structure on the double inversion of emulsions in the presence of nanoparticles.

Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations (2009)
Journal Article
Kali, G., Georgiou, T. K., Iván, B., & Patrickios, C. S. (2009). Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations. Journal of Polymer Science Part A: Polymer Chemistry, 47(17), 4289-4301. https://doi.org/10.1002/pola.23481

A series of amphiphilic end-linked conetworks was synthesized by the combination of two "quasiliving" polymerization techniques, quasiliving carbocationic (QLCCP) and group transfer polymerizations (GTP). The hydrophobic monomer was polyisobutylene m... Read More about Anionic amphiphilic end-linked conetworks by the combination of quasiliving carbocationic and group transfer polymerizations.

Ionothermal synthesis, structure and characterization of three-dimensional zinc phosphates (2009)
Journal Article
Liu, L., Wragg, D. S., Zhang, H., Kong, Y., Byrne, P. J., Prior, T. J., …Morris, R. E. (2009). Ionothermal synthesis, structure and characterization of three-dimensional zinc phosphates. Dalton Transactions : an international journal of inorganic chemistry, 6715-6718. https://doi.org/10.1039/b906934h

The first metal phosphate analogue of the zeolite Na-J (framework type JBW) has been synthesized by an ionothermal approach along with zincophosphate thomsonite.

Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation (2009)
Journal Article
Arbaoui, A., Redshaw, C., Homden, D. M., Wright, J. A., & Elsegood, M. R. (2009). Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation. Dalton Transactions : an international journal of inorganic chemistry, 8911-8922. https://doi.org/10.1039/b902402f

The pro-catalysts [V(NAr)(L)(OR)] (Ar = p-tolyl, p-ClC6H 4, p-(OMe)C6H4, p-(CF3)C 6H4; R = t-Bu, i-Pr, n-Pr, Et, C(CH3)(CF 3)2) have been prepared in good yields from the reaction of [V(NAr)(OR)3] and the bisphenol 2,2′-CH3CH[4,6- (t-Bu)2C6H2OH]2 (LH... Read More about Vanadium-based imido-alkoxide pro-catalysts bearing bisphenolate ligands for ethylene and ε-caprolactone polymerisation.

Intercalated brucite-type layered cobalt(II) hydroxysulfate (2009)
Journal Article
Yotnoi, B., Luachan, S., Prior, T. J., & Rujiwatra, A. (2009). Intercalated brucite-type layered cobalt(II) hydroxysulfate. Acta Crystallographica Section E: Crystallographic Communications, 65(7), I52-U139. https://doi.org/10.1107/S160053680902251X

In an attempt to synthesize new cobalt(II) sulfate framework structures using 1,4-diazabicyclo[2.2.2]octane as a template, crystals of poly[0.35-[hexaaquacobalt(II)] [tri-μ-hydroxido-μ-sulfato-dicobalt(II)]], {[Co(H 2 O) 6 ] 0.35 [Co 2 (OH) 3 (SO 4... Read More about Intercalated brucite-type layered cobalt(II) hydroxysulfate.

Diamagnetic repulsion—A versatile tool for label-free particle handling in microfluidic devices (2009)
Journal Article
Peyman, S. A., Kwan, E. Y., Margarson, O., Iles, A., & Pamme, N. (2009). Diamagnetic repulsion—A versatile tool for label-free particle handling in microfluidic devices. Journal of Chromatography A, 1216(52), 9055-9062. https://doi.org/10.1016/j.chroma.2009.06.039

We report the exploration of diamagnetic repulsion forces for the selective manipulation of microparticles inside microfluidic devices. Diamagnetic materials such as polymers are repelled from magnetic fields, an effect greatly enhanced by suspending... Read More about Diamagnetic repulsion—A versatile tool for label-free particle handling in microfluidic devices.

2-Benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (II) chlorides: A temperature switch catalyst in oligomerization and polymerization of ethylene (2009)
Journal Article
Gao, R., Wang, K., Li, Y., Wang, F., Sun, W. H., Redshaw, C., & Bochmann, M. (2009). 2-Benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (II) chlorides: A temperature switch catalyst in oligomerization and polymerization of ethylene. Journal of Molecular Catalysis A: Chemical, 309(1-2), 166-171. https://doi.org/10.1016/j.molcata.2009.05.021

A series of cobalt (II) complexes ligated by 2-(2-benzoxazolyl)-6-(1-(arylimino)ethyl)pyridines was synthesized and characterized by FT-IR spectroscopic and elemental analysis. The molecular structures of Co1 (Ar = 2,6-Me2C6H3), Co2 (Ar = 2,6-Et2C6H3... Read More about 2-Benzoxazolyl-6-(1-(arylimino)ethyl)pyridyl cobalt (II) chlorides: A temperature switch catalyst in oligomerization and polymerization of ethylene.

Transition metal pnictide-halides: A class of under-explored compounds (2009)
Journal Article
Headspith, D. A., & Francesconi, M. G. (2009). Transition metal pnictide-halides: A class of under-explored compounds. Topics in catalysis, 52(11), 1611-1627. https://doi.org/10.1007/s11244-009-9282-5

In terms of application, mixed anion compounds have attracted far less attention than mixed cation systems. Interest in the catalytic properties of nitrides has been driven, in part, by their accessibility through new, improved synthesis routes. Alth... Read More about Transition metal pnictide-halides: A class of under-explored compounds.

Identification, release and olfactory detection of bile salts in the intestinal fluid of the Senegalese sole (Solea senegalensis) (2009)
Journal Article
Velez, Z., Hubbard, P. C., Welham, K., Hardege, J., Barata, E. N., & Canário, A. V. M. (2009). Identification, release and olfactory detection of bile salts in the intestinal fluid of the Senegalese sole (Solea senegalensis). Journal of comparative physiology. A, Sensory, neural, and behavioral physiology, 195(7), 691-698. https://doi.org/10.1007/s00359-009-0444-5

Olfactory sensitivity to bile salts is wide-spread in teleosts; however, which bile salts are released in sufficient quantities to be detected is unclear. The current study identified bile salts in the intestinal and bile fluids of Solea senegalensis... Read More about Identification, release and olfactory detection of bile salts in the intestinal fluid of the Senegalese sole (Solea senegalensis).

CXCR4 antagonists: a new generation of configurationally restricted bis-azamacrocyclic compounds (2009)
Journal Article
Khan, A., Nicholson, G., McRobbie, G., Greenman, J., Pannecouque, C., Daelemans, D., …Archibald, S. J. (2009). CXCR4 antagonists: a new generation of configurationally restricted bis-azamacrocyclic compounds. Antiviral research, 82(2), A59-A60. https://doi.org/10.1016/j.antiviral.2009.02.141

AMD3100 is a bis-azamacrocyclic compound that has been demonstrated to be a highly effective antagonist of the CXCR4 chemokine receptor. The two azamacrocyclic rings have been shown to interact with aspartate residues on the receptor via hydrogen bon... Read More about CXCR4 antagonists: a new generation of configurationally restricted bis-azamacrocyclic compounds.

Particle-stabilised foams: an interfacial study (2009)
Journal Article
Stocco, A., Drenckhan, W., Rio, E., Langevin, D., & Binks, B. P. (2009). Particle-stabilised foams: an interfacial study. Soft matter, 5(11), 2215-2222. https://doi.org/10.1039/b901180c

In an attempt to elucidate the remarkable stability of foams generated from dispersions of partially hydrophobic nanoparticles (fumed silica), we present investigations into the static and dilational properties of the gas-liquid interfaces of such di... Read More about Particle-stabilised foams: an interfacial study.

Fabrication of novel anisotropic magnetic microparticles (2009)
Journal Article
Dyab, A. K. F., Ozmen, M., Ersoz, M., & Paunov, V. N. (2009). Fabrication of novel anisotropic magnetic microparticles. Journal of Materials Chemistry, 19(21), 3475-3481. https://doi.org/10.1039/b814971m

We report a novel technique for fabrication of magnetically anisotropic microparticles based on “arresting” of the alignment of oleic acid coated magnetite nanoparticles (OCMNs) dispersed within the oil drops of a polymerisable oil-in-water emulsion.... Read More about Fabrication of novel anisotropic magnetic microparticles.

Microwave assisted crystal growth of a new organic-decavanadate assembly: [V10O27(OH)] · 2(C6N2H14) · (C6N2H13) · (C6N2H12) · 2H2O (2009)
Journal Article
Yotnoi, B., Yimklan, S., Prior, T. J., & Rujiwatra, A. (2009). Microwave assisted crystal growth of a new organic-decavanadate assembly: [V10O27(OH)] · 2(C6N2H14) · (C6N2H13) · (C6N2H12) · 2H2O. Journal of inorganic and organometallic polymers and materials, 19(3), 306-313. https://doi.org/10.1007/s10904-009-9271-y

Microwave synthesis was used to grow single crystals of a new organic-inorganic supramolecular assembly, [V10O27(OH)]·2(C6N2H14)·(C6N2H13)·(C6N2H12)·2H2O, in a very short time compared to the conventional solution technique. In order to generate crys... Read More about Microwave assisted crystal growth of a new organic-decavanadate assembly: [V10O27(OH)] · 2(C6N2H14) · (C6N2H13) · (C6N2H12) · 2H2O.

Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles (2009)
Journal Article
Binks, B. P., & Rocher, A. (2009). Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles. Journal of colloid and interface science, 335(1), 94-104. https://doi.org/10.1016/j.jcis.2009.03.089

The possibility of stabilising oil-water mixtures using wax particles alone is reported. As judged from contact angle measurements, wax particles are hydrophobic and act as effective emulsifiers of water-in-squalane emulsions. Specific differences ex... Read More about Effects of temperature on water-in-oil emulsions stabilised solely by wax microparticles.