All Outputs (58)

Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics (2014)
Journal Article
Murray, B. S., Menin, L., Scopelliti, R., & Dyson, P. J. (2014). Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics. Chemical science, 5(6), 2536-2545. https://doi.org/10.1039/c4sc00116h

Dinuclear metal complexes have emerged as a promising class of biologically active compounds which possess unique anticancer activity. Here, we describe a novel series of arene-linked dinuclear organometallic Ru(II) complexes, where the relative conf... Read More about Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics.

Biomimetic polyorganosiloxanes: Model compounds for new materials (2014)
Journal Article
Kociok-Köhn, G., Mahon, M. F., Molloy, K. C., Price, G. J., Prior, T. J., & Smith, D. (2014). Biomimetic polyorganosiloxanes: Model compounds for new materials. Dalton Transactions : an international journal of inorganic chemistry, 43(21), 7734-7746. https://doi.org/10.1039/c4dt00554f

The chemistry of N-organosilylalkyl-substituted heterocyclic bases (thymine, adenine and cytosine) is described, covering the structures of model compounds, the synthesis of substituted oligo-siloxanes and a preliminary report of the synthesis of a p... Read More about Biomimetic polyorganosiloxanes: Model compounds for new materials.

Chromium complex pre-catalysts in ethylene oligomerization/polymerization (2014)
Journal Article
Katla, V., Du, S., Redshaw, C., & Sun, W. (2014). Chromium complex pre-catalysts in ethylene oligomerization/polymerization. Review of catalysts, 1(1), 1-14. https://doi.org/10.18488/journal.96.2014.11.1.14

Recent progress of chromium complex pre-catalysts in ethylene oligomerization and polymerization is reviewed herein. As well as the well-established trimerization of ethylene by chromium catalytic systems, such pre-catalysts have more generally been... Read More about Chromium complex pre-catalysts in ethylene oligomerization/polymerization.

Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles (2014)
Journal Article
Cheng, F., Betts, J. W., Kelly, S. M., Wareham, D. W., Kornherr, A., Dumestre, F., …Heinze, T. (2014). Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles. Journal of Materials Chemistry B, 2(20), 3057-3064. https://doi.org/10.1039/c3tb21734e

Small, carboxymethyl-starch-stabilised zinc oxide nanoparticles with a defined shape, size and morphology were prepared in situ in water at relatively low reaction temperatures using soluble carboxymethyl starch (CMS) as a combined crystallising, sta... Read More about Whiter, brighter, and more stable cellulose paper coated with antibacterial carboxymethyl starch stabilized ZnO nanoparticles.

Synthesis, characterization and ethylene polymerization behaviour of binuclear nickel halides bearing 4,5,9,10-tetra(arylimino)pyrenylidenes (2014)
Journal Article
Xing, Q., Song, K., Liang, T., Liu, Q., Sun, W., & Redshaw, C. (2014). Synthesis, characterization and ethylene polymerization behaviour of binuclear nickel halides bearing 4,5,9,10-tetra(arylimino)pyrenylidenes. Dalton Transactions : an international journal of inorganic chemistry, 43(21), 7830-7837. https://doi.org/10.1039/c4dt00503a

Pyrene-4,5,9,10-tetraone was prepared via the oxidation of pyrene, and reacted with various anilines to afford a series of 4,5,9,10-tetra(arylimino)pyrenylidene derivatives (L1–L4). The tetraimino-pyrene compounds L1 and L2 were reacted with two equi... Read More about Synthesis, characterization and ethylene polymerization behaviour of binuclear nickel halides bearing 4,5,9,10-tetra(arylimino)pyrenylidenes.

Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions (2014)
Journal Article
Destribats, M., Rouvet, M., Gehin-Delval, C., Schmitt, C., & Binks, B. P. (2014). Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions. Soft matter, 10(36), 6941-6954. https://doi.org/10.1039/c4sm00179f

We have investigated a new class of food-grade particles, whey protein microgels, as stabilisers of triglyceride-water emulsions. The sub-micron particles stabilized oil-in-water emulsions at all pH with and without salt. All emulsions creamed but ex... Read More about Emulsions stabilised by whey protein microgel particles: Towards food-grade Pickering emulsions.

Vanadyl complexes bearing bi-dentate phenoxyimine ligands: Synthesis, structural studies and ethylene polymerization capability (2014)
Journal Article
Ma, J., Zhao, K., Walton, M. J., Wright, J. A., Frese, J. W. A., Elsegood, M. R. J., …Redshaw, C. (2014). Vanadyl complexes bearing bi-dentate phenoxyimine ligands: Synthesis, structural studies and ethylene polymerization capability. Dalton Transactions : an international journal of inorganic chemistry, 43(22), 8300-8310. https://doi.org/10.1039/c4dt00021h

Reaction of [VO(OnPr)₃] with the Schiff bases 3,5-(tBu)₂-2-OH-C₆H₂CH(N(x-OR-C₆H₄)) (R = Me; x = 2, L¹H; x = 3, L²H; x = 4, L³H; R = Et (L⁴H), CF₃ (L⁵H), Ph (L⁶H)) or 4-methyl-3-(R)-2-(OH)-C₆H₄C=N(2′-(2′′-(OR₁)C₆H₄)C₆H₄) (R = adamantyl, R¹ = Ph (L⁷H)... Read More about Vanadyl complexes bearing bi-dentate phenoxyimine ligands: Synthesis, structural studies and ethylene polymerization capability.

Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates (2014)
Journal Article
Soshnikov, I. E., Semikolenova, N. V., Ma, J., Zhao, K., Zakharov, V. A., Bryliakov, K. P., …Talsi, E. P. (2014). Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates. Organometallics, 33(6), 1431-1439. https://doi.org/10.1021/om500017r

The catalyst systems (FI)TiCl₃/MAO (FI = phenoxyimine ligand with an additional aryl–O–CH₃ donor) display exceptionally high activity in selective ethylene trimerization. By means of NMR and EPR spectroscopy, the nature of the Ti species formed in th... Read More about Selective ethylene trimerization by titanium complexes bearing phenoxy-imine ligands: NMR and EPR Spectroscopic studies of the reaction intermediates.

Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template (2014)
Journal Article
Elaigwu, S. E., Kyriakou, G., Prior, T. J., & Greenway, G. M. (2014). Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template. Materials letters, 123, 198-201. https://doi.org/10.1016/j.matlet.2014.03.003

A new microwave-assisted hydrothermal synthesis of carbon monolith is reported in this work. The process uses microwave heating at 100 °C under acidic condition by employing a triblock copolymer F127 as the template, and resorcinol–formaldehyde as th... Read More about Microwave-assisted hydrothermal synthesis of carbon monolith via a soft-template method using resorcinol and formaldehyde as carbon precursor and pluronic F127 as template.

Biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridyl-cobalt complexes: synthesis, characterization and ethylene polymerization behavior (2014)
Journal Article
Xing, Q., Zhao, T., Du, S., Yang, W., Liang, T., Redshaw, C., & Sun, W. (2014). Biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridyl-cobalt complexes: synthesis, characterization and ethylene polymerization behavior. Organometallics, 33(6), 1382-1388. https://doi.org/10.1021/om4010884

A series of biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridine derivatives reacted with cobalt dichloride in dichloromethane/ethanol to afford the corresponding binuclear cobalt complexes. The cobalt complexes were characterized by FT-IR spectrosc... Read More about Biphenyl-bridged 6-(1-aryliminoethyl)-2-iminopyridyl-cobalt complexes: synthesis, characterization and ethylene polymerization behavior.

Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-) polymerization behavior (2014)
Journal Article
Redshaw, C., Chen, L., Sun, W., Wang, L., Yan, Q., & Yang, W. (2014). Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-) polymerization behavior. Journal of organometallic chemistry, 753(March), 34-41. https://doi.org/10.1016/j.jorganchem.2013.12.021

A series of half-titanocene chloride complexes bearing 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate ligands (L), CpTiLCl₂, has been synthesized in acceptable yields by the stoichiometric reaction of CpTiCl₃ with the respective potassium 5-t-buty... Read More about Half-titanocene 5-t-butyl-2-(1-(arylimino)methyl)quinolin-8-olate chlorides: Synthesis, characterization and ethylene (co-) polymerization behavior.

Regioselective and stoichiometrically controlled conjugation of photodynamic sensitizers to a HER2 targeting antibody fragment (2014)
Journal Article
Bryden, F., Maruani, A., Savoie, H., Chudasama, V., Smith, M. E. B., Caddick, S., & Boyle, R. W. (2014). Regioselective and stoichiometrically controlled conjugation of photodynamic sensitizers to a HER2 targeting antibody fragment. Bioconjugate chemistry, 25(3), 611-617. https://doi.org/10.1021/bc5000324

The rapidly increasing interest in the synthesis of antibody–drug conjugates as powerful targeted anticancer agents demonstrates the growing appreciation of the power of antibodies and antibody fragments as highly selective targeting moieties. This t... Read More about Regioselective and stoichiometrically controlled conjugation of photodynamic sensitizers to a HER2 targeting antibody fragment.

How does iron interact with sporopollenin exine capsules? An X-ray absorption study including microfocus XANES and XRF imaging (2014)
Journal Article
Archibald, S. J., Atkin, S. L., Bras, W., Diego-Taboada, A., Mackenzie, G., Mosselmans, J. F. W., …Young, N. A. (2014). How does iron interact with sporopollenin exine capsules? An X-ray absorption study including microfocus XANES and XRF imaging. Journal of Materials Chemistry B, 2(8), 945-959. https://doi.org/10.1039/c3tb21523g

Sporopollenin exine capsules (SECs) derived from plant spores and pollen grains have been proposed as adsorption, remediation and drug delivery agents. Despite many studies there is scant structural data available. This X-ray absorption investigation... Read More about How does iron interact with sporopollenin exine capsules? An X-ray absorption study including microfocus XANES and XRF imaging.

Direct amine-functionalisation of γ-Fe2O3nanoparticles (2014)
Journal Article
Rocher, V., Manerova, J., Kinnear, M., Evans, D. J., & Francesconi, M. G. (2014). Direct amine-functionalisation of γ-Fe2O3nanoparticles. Dalton Transactions : an international journal of inorganic chemistry, 43(7), 2948-2952. https://doi.org/10.1039/c3dt52386a

A novel and simple preparation of amine-modified γ-Fe2O3 nanoparticles is described. The presence of amine groups on the surface, instead of hydroxyl groups, will allow conjugation of biologically active molecules to the iron oxide nanoparticles with... Read More about Direct amine-functionalisation of γ-Fe2O3nanoparticles.

Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study (2014)
Journal Article
Salama, I. E., Binks, B. P., Fletcher, P. D. I., & Horsup, D. I. (2014). Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study. Colloids and surfaces. A, Physicochemical and engineering aspects, 447, 155-165. https://doi.org/10.1016/j.colsurfa.2014.01.034

The adsorption behaviour of benzyldimethyldodecylammonium chloride (C12BDMAC) corrosion inhibitor from aqueous solutions onto a stainless steel surface has been investigated using the quartz crystal microbalance (QCM) technique and the depletion-HPLC... Read More about Adsorption of benzyldimethyldodecylammonium chloride onto stainless steel using the quartz crystal microbalance and the depletion methods: An optimisation study.

2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino} -3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior (2014)
Journal Article
Liu, Q., Zhang, W., Jia, D., Hao, X., Redshaw, C., & Sun, W. (2014). 2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino} -3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior. Applied catalysis. A, General, 475(April), 195-202. https://doi.org/10.1016/j.apcata.2014.01.034

The series of 2-{2,6-bis[di(4-fluorophenyl)methyl]-4-chlorophenylimino}-3- aryliminobutane derivatives (L1-L5) and their nickel(II) dibromide complexes (Ni1-Ni5) were synthesized, and all organic compounds were fully characterized by the Fourier tran... Read More about 2-{2,6-Bis[bis(4-fluorophenyl)methyl]-4-chlorophenylimino} -3-aryliminobutylnickel(II) bromide complexes: Synthesis, characterization, and investigation of their catalytic behavior.

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials (2014)
Journal Article
Efremova, O. A., Shestopalov, M. A., Chirtsova, N. A., Smolentsev, A. I., Mironov, Y. V., Kitamura, N., …Sutherland, A. J. (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton Transactions : an international journal of inorganic chemistry, 43(16), 6021-6025. https://doi.org/10.1039/c3dt53126k

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu₄N)₂[Mo₆I₈(NO₃)₆], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materia... Read More about A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials.

Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: Towards mild strategies for the labelling of glycans (2014)
Journal Article
Giuntini, F., Bryden, F., Daly, R., Scanlan, E. M., & Boyle, R. W. (2014). Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: Towards mild strategies for the labelling of glycans. Organic & biomolecular chemistry, 12(8), 1203-1206. https://doi.org/10.1039/c3ob42306a

Fully deprotected alkynyl-functionalised mono- and oligosaccharides undergo CuAAC-based conjugation with water-soluble porphyrin azides in aqueous environments. The mild reaction conditions are fully compatible with the presence of labile glycosidic... Read More about Huisgen-based conjugation of water-soluble porphyrins to deprotected sugars: Towards mild strategies for the labelling of glycans.