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A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

Efremova, O. A.; Shestopalov, M. A.; Chirtsova, N. A.; Smolentsev, A. I.; Mironov, Y. V.; Kitamura, N.; Brylev, K. A.; Sutherland, A. J.

Authors

O. A. Efremova

M. A. Shestopalov

N. A. Chirtsova

A. I. Smolentsev

Y. V. Mironov

N. Kitamura

K. A. Brylev

A. J. Sutherland



Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu₄N)₂[Mo₆I₈(NO₃)₆], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as “polymeric ligands” to immobilise the molybdenum cluster complex.

Citation

Efremova, O. A., Shestopalov, M. A., Chirtsova, N. A., Smolentsev, A. I., Mironov, Y. V., Kitamura, N., …Sutherland, A. J. (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton transactions : an international journal of inorganic chemistry / RSoC, 43(16), 6021-6025. doi:10.1039/c3dt53126k

Journal Article Type Article
Acceptance Date Jan 16, 2014
Online Publication Date Jan 17, 2014
Publication Date Apr 28, 2014
Deposit Date Aug 26, 2015
Publicly Available Date Nov 23, 2017
Journal Dalton transactions
Print ISSN 1477-9226
Electronic ISSN 1477-9234
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 43
Issue 16
Pages 6021-6025
DOI https://doi.org/10.1039/c3dt53126k
Keywords Chemistry, Inorganic hexamolybdenum cluster complex
Public URL https://hull-repository.worktribe.com/output/378079
Publisher URL http://pubs.rsc.org/en/content/articlelanding/2014/dt/c3dt53126k#!divAbstract
Copyright Statement ©2015 University of Hull
Additional Information Author's accepted manuscript of article published in: Dalton transactions, 2014, v.43, issue 16

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