University of Hull logo

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

Efremova, O. A.; Shestopalov, M. A.; Chirtsova, N. A.; Smolentsev, A. I.; Mironov, Y. V.; Kitamura, N.; Brylev, K. A.; Sutherland, A. J.

Authors

M. A. Shestopalov

N. A. Chirtsova

A. I. Smolentsev

Y. V. Mironov

N. Kitamura

K. A. Brylev

A. J. Sutherland

Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu₄N)₂[Mo₆I₈(NO₃)₆], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as “polymeric ligands” to immobilise the molybdenum cluster complex.

Journal Article Type Article
Publication Date Apr 28, 2014
Journal Dalton transactions
Print ISSN 1477-9226
Electronic ISSN 1477-9234
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 43
Issue 16
Pages 6021-6025
Institution Citation Efremova, O. A., Shestopalov, M. A., Chirtsova, N. A., Smolentsev, A. I., Mironov, Y. V., Kitamura, N., …Sutherland, A. J. (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton transactions : an international journal of inorganic chemistry / RSoC, 43(16), 6021-6025. doi:10.1039/c3dt53126k
DOI https://doi.org/10.1039/c3dt53126k
Keywords Chemistry, Inorganic hexamolybdenum cluster complex
Publisher URL http://pubs.rsc.org/en/content/articlelanding/2014/dt/c3dt53126k#!divAbstract
Copyright Statement ©2015 University of Hull
Additional Information Author's accepted manuscript of article published in: Dalton transactions, 2014, v.43, issue 16

Files



You might also like


Downloadable Citations