A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

Efremova, O. A.; Shestopalov, M. A.; Chirtsova, N. A.; Smolentsev, A. I.; Mironov, Y. V.; Kitamura, N.; Brylev, K. A.; Sutherland, A. J.

Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu₄N)₂[Mo₆I₈(NO₃)₆], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as “polymeric ligands” to immobilise the molybdenum cluster complex.

Citation

Efremova, O. A., Shestopalov, M. A., Chirtsova, N. A., Smolentsev, A. I., Mironov, Y. V., Kitamura, N., …Sutherland, A. J. (2014). A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials. Dalton Transactions : an international journal of inorganic chemistry, 43(16), 6021-6025. https://doi.org/10.1039/c3dt53126k

• Journal Article Type: Article
• Acceptance Date: Jan 16, 2014
• Online Publication Date: Jan 17, 2014
• Publication Date: Apr 28, 2014
• Deposit Date: Aug 26, 2015
• Publicly Available Date: Nov 23, 2017
• Journal: Dalton transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 43
• Issue: 16
• Pages: 6021-6025
• DOI: https://doi.org/10.1039/c3dt53126k
• Keywords: Chemistry, Inorganic hexamolybdenum cluster complex
• Public URL: https://hull-repository.worktribe.com/output/378079
• Publisher URL: http://pubs.rsc.org/en/content/articlelanding/2014/dt/c3dt53126k#!divAbstract
• Additional Information: Author's accepted manuscript of article published in: Dalton transactions, 2014, v.43, issue 16