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Octahedral chalcogenide rhenium cluster complexes with imidazole

Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Smolentsev, Anton I.; Eltsov, Ilia V.; Efremova, Olga A.; Kitamura, Noboru; Mironov, Yuri V.; Shestopalov, Michael A.

Authors

Dmitry I. Konovalov

Anton A. Ivanov

Yuri A. Vorotnikov

Anton I. Smolentsev

Ilia V. Eltsov

Olga A. Efremova

Noboru Kitamura

Yuri V. Mironov

Michael A. Shestopalov



Contributors

Olga Efremova
Project Member

Abstract

Reactions of [{Re6Q8}Br6]4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re6Q8}(imzH)4(imz)2] (imzH = imidazole). The interaction of [{Re6Q8}(imzH)4(imz)2] with hydrohalic acids resulted in cationic complexes [{Re6Q8}(imzH)6]X2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re6Q8}(imzH)4(imz)2] was also studied.

Journal Article Type Article
Publication Date Jun 1, 2019
Journal Polyhedron
Print ISSN 0277-5387
Publisher Elsevier
Peer Reviewed Not Peer Reviewed
Volume 165
Pages 79-85
APA6 Citation Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Smolentsev, A. I., Eltsov, I. V., Efremova, O. A., …Shestopalov, M. A. (2019). Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron, 165, 79-85. https://doi.org/10.1016/j.poly.2019.03.007
DOI https://doi.org/10.1016/j.poly.2019.03.007
Keywords Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry
Additional Information This article is maintained by: Elsevier; Article Title: Octahedral chalcogenide rhenium cluster complexes with imidazole; Journal Title: Polyhedron; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.poly.2019.03.007; Content Type: article; Copyright: © 2019 Elsevier Ltd. All rights reserved.

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