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Octahedral chalcogenide rhenium cluster complexes with imidazole

Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Smolentsev, Anton I.; Eltsov, Ilia V.; Efremova, Olga A.; Kitamura, Noboru; Mironov, Yuri V.; Shestopalov, Michael A.


Dmitry I. Konovalov

Anton A. Ivanov

Yuri A. Vorotnikov

Anton I. Smolentsev

Ilia V. Eltsov

Olga A. Efremova

Noboru Kitamura

Yuri V. Mironov

Michael A. Shestopalov


Olga Efremova
Project Member


Reactions of [{Re6Q8}Br6]4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re6Q8}(imzH)4(imz)2] (imzH = imidazole). The interaction of [{Re6Q8}(imzH)4(imz)2] with hydrohalic acids resulted in cationic complexes [{Re6Q8}(imzH)6]X2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re6Q8}(imzH)4(imz)2] was also studied.


Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Smolentsev, A. I., Eltsov, I. V., Efremova, O. A., Kitamura, N., Mironov, Y. V., & Shestopalov, M. A. (2019). Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron, 165, 79-85.

Journal Article Type Article
Acceptance Date Mar 8, 2019
Online Publication Date Mar 16, 2019
Publication Date Jun 1, 2019
Deposit Date Apr 25, 2019
Publicly Available Date Mar 17, 2020
Journal Polyhedron
Print ISSN 0277-5387
Publisher Elsevier
Peer Reviewed Not Peer Reviewed
Volume 165
Pages 79-85
Keywords Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry
Public URL
Additional Information This article is maintained by: Elsevier; Article Title: Octahedral chalcogenide rhenium cluster complexes with imidazole; Journal Title: Polyhedron; CrossRef DOI link to publisher maintained version:; Content Type: article; Copyright: © 2019 Elsevier Ltd. All rights reserved.
Contract Date Sep 3, 2019


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