Octahedral chalcogenide rhenium cluster complexes with imidazole

Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Smolentsev, Anton I.; Eltsov, Ilia V.; Efremova, Olga A.; Kitamura, Noboru; Mironov, Yuri V.; Shestopalov, Michael A.

Abstract

Reactions of [{Re6Q8}Br6]4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re6Q8}(imzH)4(imz)2] (imzH = imidazole). The interaction of [{Re6Q8}(imzH)4(imz)2] with hydrohalic acids resulted in cationic complexes [{Re6Q8}(imzH)6]X2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re6Q8}(imzH)4(imz)2] was also studied.

Citation

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Smolentsev, A. I., Eltsov, I. V., Efremova, O. A., Kitamura, N., Mironov, Y. V., & Shestopalov, M. A. (2019). Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron, 165, 79-85. https://doi.org/10.1016/j.poly.2019.03.007

• Journal Article Type: Article
• Acceptance Date: Mar 8, 2019
• Online Publication Date: Mar 16, 2019
• Publication Date: Jun 1, 2019
• Deposit Date: Apr 25, 2019
• Publicly Available Date: Mar 17, 2020
• Journal: Polyhedron
• Print ISSN: 0277-5387
• Publisher: Elsevier
• Peer Reviewed: Not Peer Reviewed
• Volume: 165
• Pages: 79-85
• DOI: https://doi.org/10.1016/j.poly.2019.03.007
• Keywords: Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry
• Public URL: https://hull-repository.worktribe.com/output/1647705
• Additional Information: This article is maintained by: Elsevier; Article Title: Octahedral chalcogenide rhenium cluster complexes with imidazole; Journal Title: Polyhedron; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.poly.2019.03.007; Content Type: article; Copyright: © 2019 Elsevier Ltd. All rights reserved.
• Contract Date: Sep 3, 2019