Octahedral chalcogenide rhenium cluster complexes with imidazole

Konovalov, Dmitry I.; Ivanov, Anton A.; Vorotnikov, Yuri A.; Smolentsev, Anton I.; Eltsov, Ilia V.; Efremova, Olga A.; Kitamura, Noboru; Mironov, Yuri V.; Shestopalov, Michael A.

Abstract

Reactions of [{Re6Q8}Br6]4−/3− (Q = S, Se) with molten imidazole lead to the formation of two new neutral cluster complexes [{Re6Q8}(imzH)4(imz)2] (imzH = imidazole). The interaction of [{Re6Q8}(imzH)4(imz)2] with hydrohalic acids resulted in cationic complexes [{Re6Q8}(imzH)6]X2 (X = Cl, Br). All compounds were characterised by X-ray single-crystal and powder diffraction analyses, elemental analysis, energy dispersive X-ray and IR spectroscopies. The luminescence of the neutral compounds [{Re6Q8}(imzH)4(imz)2] was also studied.

Citation

Konovalov, D. I., Ivanov, A. A., Vorotnikov, Y. A., Smolentsev, A. I., Eltsov, I. V., Efremova, O. A., …Shestopalov, M. A. (2019). Octahedral chalcogenide rhenium cluster complexes with imidazole. Polyhedron, 165, 79-85. https://doi.org/10.1016/j.poly.2019.03.007

• Journal Article Type: Article
• Acceptance Date: Mar 8, 2019
• Online Publication Date: Mar 16, 2019
• Publication Date: Jun 1, 2019
• Deposit Date: Apr 25, 2019
• Publicly Available Date: Mar 17, 2020
• Journal: Polyhedron
• Print ISSN: 0277-5387
• Publisher: Elsevier
• Peer Reviewed: Not Peer Reviewed
• Volume: 165
• Pages: 79-85
• DOI: https://doi.org/10.1016/j.poly.2019.03.007
• Keywords: Physical and Theoretical Chemistry; Inorganic Chemistry; Materials Chemistry
• Public URL: https://hull-repository.worktribe.com/output/1647705
• Additional Information: This article is maintained by: Elsevier; Article Title: Octahedral chalcogenide rhenium cluster complexes with imidazole; Journal Title: Polyhedron; CrossRef DOI link to publisher maintained version: https://doi.org/10.1016/j.poly.2019.03.007; Content Type: article; Copyright: © 2019 Elsevier Ltd. All rights reserved.