One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

Vorotnikova, Natalya A; Edeleva, Mariya V; Kurskaya, Olga G; Brylev, Konstantin A; Shestopalov, Alexander M; Mironov, Yuri V; Sutherland, Andrew J; Efremova, Olga A; Shestopalov, Michael A

Abstract

© 2017 Society of Chemical Industry Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [{Mo 6 X 8 }(NO 3 ) 6 ] 2− (X = Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated. © 2017 Society of Chemical Industry.

Citation

Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., Sutherland, A. J., Efremova, O. A., & Shestopalov, M. A. (2017). One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction. Polymer international, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473

• Journal Article Type: Article
• Acceptance Date: Sep 23, 2017
• Online Publication Date: Oct 18, 2017
• Publication Date: 2017-12
• Deposit Date: Feb 13, 2018
• Publicly Available Date: Oct 19, 2018
• Journal: Polymer International
• Print ISSN: 0959-8103
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 66
• Issue: 12
• Pages: 1906-1912
• DOI: https://doi.org/10.1002/pi.5473
• Keywords: Polymers and Plastics
• Public URL: https://hull-repository.worktribe.com/output/591809
• Publisher URL: http://onlinelibrary.wiley.com/doi/10.1002/pi.5473/abstract
• Related Public URLs: https://research.aston.ac.uk/portal/en/researchoutput/onepot-synthesis-of-mo6i84doped-polystyrene-microspheres-via-a-free-radical-dispersion-copolymerisation-reaction(54a383b3-be6b-40c9-a927-78ef20450088).html
• Contract Date: Feb 16, 2018