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One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction

Vorotnikova, Natalya A; Edeleva, Mariya V; Kurskaya, Olga G; Brylev, Konstantin A; Shestopalov, Alexander M; Mironov, Yuri V; Sutherland, Andrew J; Efremova, Olga A; Shestopalov, Michael A

Authors

Natalya A Vorotnikova

Mariya V Edeleva

Olga G Kurskaya

Konstantin A Brylev

Alexander M Shestopalov

Yuri V Mironov

Andrew J Sutherland

Olga A Efremova

Michael A Shestopalov



Abstract

© 2017 Society of Chemical Industry Molybdenum octahedral clusters, when incorporated into an appropriate polymer matrix, are considered as promising agents for a range of biological applications. This work describes the one-pot synthesis, morphology and cellular toxicity of nano-sized polystyrene beads doped with luminescent cluster complexes [{Mo 6 X 8 }(NO 3 ) 6 ] 2− (X = Cl, Br or I). Specifically, the particles were obtained by free radical dispersion copolymerisation of styrene and methacrylic acid or 4-vinylpyridine in the presence of the cluster complexes. The effects of the cluster loading in the reaction mixture on both the content of the final material and number-average molar mass of the copolymers were evaluated. © 2017 Society of Chemical Industry.

Journal Article Type Article
Publication Date 2017-12
Journal Polymer International
Print ISSN 0959-8103
Electronic ISSN 1097-0126
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 66
Issue 12
Pages 1906-1912
APA6 Citation Vorotnikova, N. A., Edeleva, M. V., Kurskaya, O. G., Brylev, K. A., Shestopalov, A. M., Mironov, Y. V., …Shestopalov, M. A. (2017). One-pot synthesis of {Mo6I8}4+-doped polystyrene microspheres via a free radical dispersion copolymerisation reaction. Polymer international, 66(12), 1906-1912. https://doi.org/10.1002/pi.5473
DOI https://doi.org/10.1002/pi.5473
Keywords Polymers and Plastics
Publisher URL http://onlinelibrary.wiley.com/doi/10.1002/pi.5473/abstract
Related Public URLs https://research.aston.ac.uk/portal/en/researchoutput/onepot-synthesis-of-mo6i84doped-polystyrene-microspheres-via-a-free-radical-dispersion-copolymerisation-reaction(54a383b3-be6b-40c9-a927-78ef20450088).html
Copyright Statement ©2018 University of Hull

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