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Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes (2020)
Journal Article
Konovalov, D. I., Ivanov, A. A., Frolova, T. S., Eltsov, I. V., Gayfulin, Y. M., Plunkett, L., Bazzar, M., Adawi, A. M., Bouillard, J. S. G., Baiborodin, S. I., Sinitsyna, O. I., Kuratieva, N. V., Yanshole, V. V., Efremova, O. A., & Shestopalov, M. A. (2020). Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes. Chemistry: a European journal, 26(61), 13904-13914. https://doi.org/10.1002/chem.202001680

Here we explore the effect of the nature of organic ligands in rhenium cluster complexes [Re6Q8L6]4− (where Q=S or Se, and L=benzotriazole, 1,2,3-triazole or 1,2,4-triazole) on the biological properties of the complexes, in particular on the cellular... Read More about Water‐soluble rhenium clusters with triazoles: the effect of chemical structure on cellular internalization and the DNA binding of the complexes.

From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis (2018)
Journal Article
Svezhentseva, E. V., Vorotnikov, Y. A., Solovieva, A. O., Pozmogova, T. N., Eltsov, I. V., Ivanov, A. A., Evtushok, D. V., Miroshnichenko, S. M., Yanshole, V. V., Eling, C. J., Adawi, A. M., Bouillard, J. S. G., Kuratieva, N. V., Fufaeva, M. S., Shestopalova, L. V., Mironov, Y. V., Efremova, O. A., & Shestopalov, M. A. (2018). From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis. Chemistry: a European journal, 24(68), 17915-17920. https://doi.org/10.1002/chem.201804663

Octahedral molybdenum and tungsten clusters have potential biological applications in photodynamic therapy and bioimaging. However, poor solubility and hydrolysis stability of these compounds hinder their application. The first water-soluble photolum... Read More about From photoinduced to dark cytotoxicity via an octahedral cluster hydrolysis.

Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity (2018)
Journal Article
Chen, L., Vivier, E., Eling, C. J., Babra, T. S., Bouillard, J. S. G., Adawi, A. M., Benoit, D. M., Hartl, F., Colquhoun, H. M., Efremova, O. A., & Greenland, B. W. (2018). Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity. Synthetic Metals, 241, 31-38. https://doi.org/10.1016/j.synthmet.2018.03.019

© 2018 An iterative synthesis has been used to produce conjugated, monodisperse, viologen-based aromatic oligomers containing up to 12 aromatic/heterocyclic rings. The methoxy-substituted oligomers were soluble in common organic solvents and could be... Read More about Conjugated, rod-like viologen oligomers: Correlation of oligomer length with conductivity and photoconductivity.