Outputs (9)

Niobium and Tantalum complexes derived from the acids Ph<inf>2</inf>C(X)CO<inf>2</inf>H (X = OH, NH<inf>2</inf>): synthesis, structure and ROP capability (2022)
Journal Article
Zhang, X., Prior, T. J., & Redshaw, C. (2022). Niobium and Tantalum complexes derived from the acids Ph2C(X)CO2H (X = OH, NH2): synthesis, structure and ROP capability. New journal of chemistry = Nouveau journal de chimie, https://doi.org/10.1039/d2nj02527b

Reaction of benzilic acid, Ph2C(OH)(CO2H), L1H2, with equimolar amounts of M(OR)5 (M = Nb, Ta) led, following work-up, to the tetranuclear complexes [Nb4(OEt)8(L1)4(μ-O)2] (1) or [Ta4(OEt)8(L1)4(μ-O)2]·0.5MeCN (2·0.5MeCN), respectively. Similar use o... Read More about Niobium and Tantalum complexes derived from the acids Ph<inf>2</inf>C(X)CO<inf>2</inf>H (X = OH, NH<inf>2</inf>): synthesis, structure and ROP capability.

Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters (2021)
Journal Article
Xing, T., Prior, T. J., & Redshaw, C. (2021). Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(42), 15140-15152. https://doi.org/10.1039/d1dt02790e

Reaction of [LiPb(OiPr)3]2 (generated in situ) with either p-tert-butylcalix[4]areneH4 (L4H4) or p-tert-butylcalix[6]areneH6 (L6H6) resulted in the heterometallic lithium/lead complexes [Pb4Li2(L4)4H6(MeCN)3]·4.5MeCN (1·4.5MeCN) and [Pb8Li10Cl2(L6H2)... Read More about Lead calix[n]arenes (n = 4, 6, 8): Structures and ring opening homo-/co-polymerization capability for cyclic esters.

Scandium calix[n]arenes (n= 4, 6, 8): structural, cytotoxicity and ring opening polymerization studies (2021)
Journal Article
Alshamrani, A. F., Santoro, O., Prior, T. J., Alamri, M. A., Stasiuk, G. J., Elsegood, M. R. J., & Redshaw, C. (2021). Scandium calix[n]arenes (n= 4, 6, 8): structural, cytotoxicity and ring opening polymerization studies. Dalton Transactions : an international journal of inorganic chemistry, 50(24), 8302-8306. https://doi.org/10.1039/d1dt01330k

Interaction of [Sc(OR)3] (R = iPr or triflate) with p-tert-butylcalix[n]arenes, where n = 4, 6, or 8, affords a number of intriguing structural motifs, which are relatively non-toxic (cytotoxicity evaluated against cell lines HCT116 and HT-29) and a... Read More about Scandium calix[n]arenes (n= 4, 6, 8): structural, cytotoxicity and ring opening polymerization studies.

Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters (2021)
Journal Article
Wang, K., Prior, T. J., Hughes, D. L., Arbaoui, A., & Redshaw, C. (2021). Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(23), 8057-8069. https://doi.org/10.1039/d1dt00711d

Reaction of the [2 + 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2(R = Me, L1H2;tBu, L2H2) with FeBr2afforded the complexes [FeBr(L1H2)]2[(FeBr3)2O]·2MeCN (1·2MeCN), [FeBr(L2H2)][X] (X = 0.5(FeBr3)2O,2·0.5MeCN, X = Br,... Read More about Coordination chemistry of [2 + 2] Schiff-base macrocycles derived from the dianilines [(2-NH2C6H4)2X] (X = CH2CH2, O): structural studies and ROP capability towards cyclic esters.

Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters. (2021)
Journal Article
Xing, T., Prior, T. J., Chen, K., & Redshaw, C. (2021). Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters. Dalton Transactions : an international journal of inorganic chemistry, 50(12), 4396-4407. https://doi.org/10.1039/d1dt00189b

Reaction of excess [Ti(OiPr)4] with p-tert-butyltetrahomodioxacalix[6]areneH6 (L1H6) afforded, after work-up (MeCN), the complex [Ti2(OiPr)2(MeCN)L1]∙3.5MeCN (1∙3.5MeCN), whilst the oxo complex [Ti4(3-O)2(H2O)(L1)2]∙MeCN (2∙MeCN) was isolated via a... Read More about Titanium complexes bearing oxa- and azacalix[4, 6]arenes: structural studies and use in the ring opening homo-/co-polymerization of cyclic esters..

Synthesis, characterisation and ROP catalytic evaluation of Cu(II) complexes bearing 2,2ʹ-diphenylglycine-derived moieties (2020)
Journal Article
Alshamrani, A. F. A., Santoro, O., Ounsworth, S., Prior, T. J., Stasiuk, G. J., & Redshaw, C. (2021). Synthesis, characterisation and ROP catalytic evaluation of Cu(II) complexes bearing 2,2ʹ-diphenylglycine-derived moieties. Polyhedron, 195, Article 114977. https://doi.org/10.1016/j.poly.2020.114977

The treatment of CuX2 (X = Cl, Br) with an equimolar amount of 2-2ʹ-diphenylglycine (DpgH) in EtOH at reflux afforded, after work up, the complexes [CuCl(Dpg)(EtOH)]2 (1) and [(CuBr2)2(Dpg)2Cu(EtOH)4] (2), respectively. The compounds were obtained mi... Read More about Synthesis, characterisation and ROP catalytic evaluation of Cu(II) complexes bearing 2,2ʹ-diphenylglycine-derived moieties.

Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization (2020)
Journal Article
Xing, T., Prior, T. J., Elsegood, M. R. J., Semikolenova, N. V., Soshnikov, I. E., Bryliakov, K. P., Chen, K., & Redshaw, C. (2021). Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization. Catalysis science & technology, 11(2), 624-636. https://doi.org/10.1039/d0cy01979h

Reaction of Na[VO(tBuO)4] (generated in-situ from VOCl3 and NaOtBu) with p-tert-butyltetrahomodioxacalix[6]areneH6 (L1H6) afforded, after work-up (in MeCN), the mixed-metal complex [(VO)2(μ-O)Na2(L1)(MeCN)4]·5(MeCN) (1·5MeCN), whilst the oxo complex... Read More about Vanadium complexes derived from oxacalix[6]arenes: structural studies and use in the ring opening homo-/co-polymerization of ε-caprolactone/δ-valerolactone and ethylene polymerization.

Rare-earth metal complexes derived from the acids Ph2C(X)CO2H (X= OH, NH2): Structural and ring opening polymerization (ROP) studies. (2020)
Journal Article
Collins, J., Santoro, O., Prior, T. J., Chen, K., & Redshaw, C. (2021). Rare-earth metal complexes derived from the acids Ph2C(X)CO2H (X= OH, NH2): Structural and ring opening polymerization (ROP) studies. Journal of molecular structure, 1224, Article 129083. https://doi.org/10.1016/j.molstruc.2020.129083

Treatment of Ln(NO3)3.6H2O (Ln = La, Ce) with an equimolar amount of 2,2’-diphenylglycine (DpgH) in ethanol afforded the corresponding hexacoordinated complexes (DpgH±)3Ln(NO3)3.H2O (DpgH± = zwitterionic 2,2’-diphenylglycine, Ln = La (1), Ce (2)). Th... Read More about Rare-earth metal complexes derived from the acids Ph2C(X)CO2H (X= OH, NH2): Structural and ring opening polymerization (ROP) studies..

Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle (2019)
Journal Article
Wang, K., Prior, T. J., & Redshaw, C. (2019). Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle. Chemical communications : Chem comm / the Royal Society of Chemistry, 55(75), 11279-11282. https://doi.org/10.1039/c9cc04494a

Homo-dinuclear Co and Zn complexes derived from the macrocycle LH2, {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2 (R = Me, tBu), revealed near inactivity for the ring opening polymerization (ROP) of the cyclic esters δ-valerolactone (δ-VL) and ϵ... Read More about Turning on ROP activity in a bimetallic Co/Zn complex supported by a [2+2] Schiff-base macrocycle.