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Pulses of enhanced continental weathering associated with multiple Late Devonian climate perturbations: Evidence from osmium-isotope compositions

Percival, L. M.E.; Selby, D.; Bond, D. P.G.; Rakoci?ski, M.; Racki, G.; Marynowski, L.; Adatte, T.; Spangenberg, J. E.; Föllmi, K. B.


L. M.E. Percival

D. Selby

M. Rakoci?ski

G. Racki

L. Marynowski

T. Adatte

J. E. Spangenberg

K. B. Föllmi



Anomalously high rates of continental weathering have frequently been proposed as a key stimulus for the development of widespread marine anoxia during a number of Late Devonian environmental and biospheric crises, which included a major mass extinction during the Frasnian–Famennian transition (marked by the Upper and Lower Kellwasser horizons). Here, this model is investigated by presenting the first stratigraphic record of osmium-isotope trends ( 187 Os/ 188 Os) in upper Devonian strata from the Kowala Quarry (Holy Cross Mountains, Poland). Changes in reconstructed 187 Os/ 188 Os seawater values to more radiogenic compositions are documented at the base of both the Lower (~0.42 to ~0.83) and Upper (~0.31 to ~0.81) Kellwasser horizons characteristic of the Frasnian–Famennian transition, and additionally within upper Famennian shales that record a more minor environmental perturbation known as the Annulata Event (~0.20 to ~0.53). These shifts indicate the occurrence of extremely enhanced continental weathering rates at the onsets of the Kellwasser crises and during the later Annulata Event. The similarity of 187 Os/ 188 Os values in this study from Frasnian–Famennian boundary and lower Famennian strata (between 0.4 and 0.5) to those from North American stratigraphic equivalents suggests that the 187 Os/ 188 Os values record global trends. These findings support a causal relationship between increased continental weathering (and thus, nutrient supply to the marine shelf) and the environmental perturbations that occurred during numerous Late Devonian events, including both of the biospherically catastrophic Kellwasser crises as well as other, less severe, oceanic anoxic events.


Percival, L. M., Selby, D., Bond, D. P., RakociƄski, M., Racki, G., Marynowski, L., …Föllmi, K. B. (2019). Pulses of enhanced continental weathering associated with multiple Late Devonian climate perturbations: Evidence from osmium-isotope compositions. Palaeogeography, palaeoclimatology, palaeoecology, 524, 240-249.

Journal Article Type Article
Acceptance Date Mar 22, 2019
Online Publication Date Mar 26, 2019
Publication Date Jun 15, 2019
Deposit Date Mar 27, 2019
Publicly Available Date Oct 27, 2022
Journal Palaeogeography, Palaeoclimatology, Palaeoecology
Print ISSN 0031-0182
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 524
Pages 240-249
Keywords Earth-Surface Processes; Palaeontology; Ecology, Evolution, Behavior and Systematics; Oceanography
Public URL
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