Design of surface-active artificial enzyme particles to stabilize Pickering emulsions for high-performance biphasic biocatalysis

Binks, Bernard P.; Chen, Zhaowei; Ji, Haiwei; Ju, Enguo; Qu, Xiaogang; Ren, Jinsong; Zhao, Chuanqi

Abstract

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Surface-active artificial enzymes (SAEs) are designed and constructed by a general and novel strategy. These SAEs can simultaneously stabilize Pickering emulsions and catalyze biphasic biotransformation with superior enzymatic stability and good re-usability; for example, for the interfacial conversion of hydrophobic p-nitrophenyl butyrate into yellow water-soluble p-nitrophenolate catalyzed by esterase-mimic SAE.

Citation

Binks, B. P., Chen, Z., Ji, H., Ju, E., Qu, X., Ren, J., & Zhao, C. (2016). Design of surface-active artificial enzyme particles to stabilize Pickering emulsions for high-performance biphasic biocatalysis. Advanced materials, 28(8), 1682-1688. https://doi.org/10.1002/adma.201504557

• Journal Article Type: Article
• Acceptance Date: Oct 29, 2015
• Online Publication Date: Dec 18, 2015
• Publication Date: Feb 24, 2016
• Deposit Date: Mar 10, 2016
• Publicly Available Date: Mar 10, 2016
• Journal: Advanced materials
• Print ISSN: 0935-9648
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 28
• Issue: 8
• Pages: 1682-1688
• DOI: https://doi.org/10.1002/adma.201504557
• Keywords: Pickering emulsions, Artificial enzyme, Biphasic biocatalysis, Stability, Re-usability
• Public URL: https://hull-repository.worktribe.com/output/412696
• Publisher URL: http://onlinelibrary.wiley.com/doi/10.1002/adma.201504557/abstract
• Additional Information: Authors' accepted manuscript of article : Chen, Z., Zhao, C., Ju, E., Ji, H., Ren, J., Binks, B. P. and Qu, X. (2016), Design of Surface-Active Artificial Enzyme Particles to Stabilize Pickering Emulsions for High-Performance Biphasic Biocatalysis. Adv. Mater., 28: 1682–1688. doi:10.1002/adma.201504557
• Contract Date: Mar 10, 2016