Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds

Kitney, Stuart P.; Sajedin, Seyed M.; Rocher, Vincent; Cheng, Fei; Kelly, Stephen M.

Abstract

We report the use of mesoporous silicon diimide gel as a basic stationary phase in thin layer chromatography for the characterisation and purification of acid-sensitive compounds. The gel is prepared by a simple sol-gel process and exhibits a large specific surface area, almost monodisperse pores and basic properties due to free-hanging amine groups.

Citation

Kitney, S. P., Sajedin, S. M., Rocher, V., Cheng, F., & Kelly, S. M. (2017). Silicon diimide gel as an efficient stationary phase in thin layer chromatography for acid-sensitive organic compounds. Chemical communications : Chem comm / the Royal Society of Chemistry, 53(80), 11080-11082. https://doi.org/10.1039/c7cc04952h

• Journal Article Type: Article
• Acceptance Date: Sep 19, 2017
• Online Publication Date: Sep 19, 2017
• Publication Date: Sep 19, 2017
• Deposit Date: Sep 21, 2017
• Publicly Available Date: Sep 19, 2018
• Journal: Chemical communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 53
• Issue: 80
• Pages: 11080-11082
• DOI: https://doi.org/10.1039/c7cc04952h
• Keywords: Silicon diimide gel; Thin layer chromatography; Basic stationary phase
• Public URL: https://hull-repository.worktribe.com/output/454896
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC04952H#!divAbstract
• Additional Information: : This document is CrossCheck deposited; : Stuart P. Kitney (ORCID); : Stephen M. Kelly (ORCID); : The Royal Society of Chemistry has an exclusive publication licence for this journal; : Received 26 June 2017; Accepted 19 September 2017; Accepted Manuscript published 19 September 2017; Advance Article published 26 September 2017; Version of Record published 5 October 2017