Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone
(2010)
Journal Article
Shen, M., Huang, W., Zhang, W., Hao, X., Sun, W. H., & Redshaw, C. (2010). Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone. Dalton Transactions : an international journal of inorganic chemistry, 39(41), 9912-9922. https://doi.org/10.1039/c0dt00514b
The stoichiometric reactions of 2-(benzimidazol-2-yl)-6-methylpyridine (L1) or 8-(benzimidazol-2-yl)quinaldine (L2) with trialkylaluminium reagents R 3Al (R = Me, Et and iBu) afforded the corresponding dialkylaluminium benzimidazolate complexes R2AlL... Read More about Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone.